Research on Durability Performance of Novel Double Solution Grouting Material with Metakaolin

2011 ◽  
Vol 250-253 ◽  
pp. 722-727 ◽  
Author(s):  
Chao Yan ◽  
Qing Jun Ding ◽  
Jian Ping Xu ◽  
Hong Xi Wang

At the present, Portland cement-water glass double solution grouting materials have many problems, such as the instability of gelation time and of products, and poor groundwater-corrosion resistance performance, etc. A way to improve the performances of double solution grouting materials was studied by adding metakaolin into the systems. Based on the rapid gelation performance of Portland cement-water glass and the durability of alkali-activated salic cementitious materials, an ideal structural model of the novel anti-aqueous dispersion and anti-aqueous dissolution grouting material (AAGM) was established. Series of experiments were prepared to verify the Na+ solidification and water-corrosion resistance performance of the metakaolin-water glass double solution grouting materials which combined with cement. The results indicated that the compact structure of AAGM was composed of a dominant ingredient of (Na,Ca)-Si-Al-H zeolite gel and a minor part of C-S-H. Moreover, it was shown that the AAGM had hydrated product of low solubility and compact microstructure tested by Fourier transform infrared spectra (FTIR) and transmission electron microscopy (SEM), which proved the well anti-aqueous dispersion and anti-aqueous dissolution performance.

2013 ◽  
Vol 838-841 ◽  
pp. 1457-1462
Author(s):  
Chun Lei Xia ◽  
Ying Ye ◽  
Guan Ming Wang ◽  
Li Cui

Silty fine sand is the second smallest sand with a particle diameter ranging from 0.0625 to 0.120 mm.This kind of sand exists in a large amount in Beijing subway excavation project. Due to the poor self-stabilization of this stratum,seeping , sand flow and collapse take place frequently. Grouting materials such as Portland cement and soluble glass (also called sodium silicate) are employed in most of excavation projects to reinforce this sand stratum. However, the reinforcement is not effective, leading to a large amount of accidents in the process of construction. The reason may be attributed to the fact that Portland cement is unable to penetrate into the stratum and the strength of soluble glass (0.6MPa) is too weak to resist the stratum pressure. To solve this problem, a modified microfine cement grouting material able to penetrate into silty fine sand stratum is developed in this paper. A combination of suspension and diluent is used to increase the penetration extension of the grouts,and the experimental results reveal that the addition of the mixture of suspension and diluent in microfine cement grouting materials improves the penetration property substantially.


Author(s):  
Morimasa Naito ◽  
Hirokazu Kishi ◽  
Naomi Fukuoka ◽  
Tsutomu Yamada ◽  
Hideaki Ishida

As an alternative grouting material for the geological repository of long-lived radioactive waste, the “Superfine Spherical silica Grout” (SFSG) material is developed using a fine spherical silica and a fine calcium hydroxide. The developed SFSG material takes an advantage of its smaller particle size distribution (max. ∼1 micron or less) than those of the cementitious materials, and also provides a low alkaline environment so as to reduce unfavorable effects on the long-term performance of geological disposal system. The SFSG is a mixture of the “super fine silica powder”, the superfine calcium hydroxide and additives such as superplasticizer. Presently, the mixture being investigated for grouting materials is focused on water/binder ratio (W/B) of 1.2. Some preliminary laboratory experiments were carried out to characterize its fundamental properties from the viewpoint of practical use for geological disposal, which is required to be equivalent with the conventional cementitious materials in terms of penetrability, strength, pH performance and workability. From a series of experiments, it was concluded that SFSG is expected to become an alternative grouting material for a geological repository.


2012 ◽  
Vol 450-451 ◽  
pp. 94-101
Author(s):  
Kun Peng Gu ◽  
Cheng Qi Wang

Corrosion resistance coefficient and expansion ratio of different cementitious materials are tested under the sulphate corrosion experimental condition, sulphate resistance of often-used cementitious material of high performance concrete for marine is studied and evaluated. The results show that sulphate resistance of portland cement is better than ordinary portland cement, and both of them are low, often-used cementitious material of high performance concrete for marine have certain sulphate resistance, which are better than ordinary portland cement and portland cement, and some of them have strong or very strong sulphate resistance. The evaluation results of the sulphate resistance of often-used cementitious material of high performance concrete for marine are not unanimous completely by corrosion resistance coefficient method and expansion rate method. Sulphate corrosion mechanism of different kinds of cementitious material is analyzed.


2020 ◽  
Vol 13 ◽  
Author(s):  
Sri Ram Krishna Mishra ◽  
Pradeep Kumar Ghosh ◽  
Manoj Kulshreshtha

Background: The previous studies have focused curing effect of mainly on high strength concrete, where strict supervision is maintained. This study is based upon general purpose concreting work for commercial and residential construction in absence of skilled manpower and supervision. Objective: The objective of this study is to establish a thumb rule to provide 7 days initial curing for maintaining quality for unsupervised concreting irrelevant to type of cement and grading. Methods: In this study concrete samples made with locally available commercial cements were cured for various initial exposure. Results: The results shows that concrete cured after a gap of 4 days from the time of de-moulding have given lowest strength as compared to concrete cured in standard practices i.e. where proper curing protocol had been followed. Conclusion: Initial curing is most important aspect of gaining desired strength. The findings after this study shows that curing affects the strength of concrete in variable grading. Initial curing has great importance for concrete with all types of Portland cement. Concrete with supplementary cementitious materials gives lowest strength initially but results higher strength after 28 days as compared to Portland cement.


2021 ◽  
Vol 11 (12) ◽  
pp. 5322
Author(s):  
Yang Ding ◽  
Tong-Lin Yang ◽  
Hui Liu ◽  
Zhen Han ◽  
Shuang-Xi Zhou ◽  
...  

Cement is widely used in marine concrete, and its resistance to chloride ion corrosion has been widely considered. In this paper, based on a laboratory test, the influence of different hydrostatic pressures, coarse aggregate contents and w/c ratios on the chloride resistance performance is analyzed. Based on COMSOL finite element software, a two-dimensional cementitious materials model is established, and the simulation results are compared with the experimental results. The results show that the penetration depth of chloride ions in cement increases with the increase of the w/c ratio. Under the hydrostatic pressure of 0 MPa, when the w/c ratio is 0.35, the penetration depth of chloride ions is 7.4 mm, and the simulation result is 8.0 mm. When the w/c ratio is 0.45, the penetration depth of chloride ions is 9.3 mm, and the simulation result is 9.9 mm. When the w/c ratio is 0.55, the penetration depth of chloride ions is 12.9 mm, and the simulation result is 12.1 mm. Under different hydrostatic pressures, the penetration depth of chloride ions obviously changes, and with the increase in hydrostatic pressure, the penetration depth of chloride ions deepens. Under the w/c ratio of 0.35, when the hydrostatic pressure is 0.5 MPa, the penetration depth of chloride ions is 11.3 mm, and the simulation result is 12.1 mm. When the hydrostatic pressure is 1.0 MPa, the penetration depth of chloride ions is 16.2 mm, and the simulation result is 17.5 mm.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2291
Author(s):  
Alessandro P. Fantilli ◽  
Daria Jóźwiak-Niedźwiedzka

The environmental impact of the Portland cement production and the large use of cement-based building materials is a growing problem [...]


Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3467
Author(s):  
Ankit Kothari ◽  
Karin Habermehl-Cwirzen ◽  
Hans Hedlund ◽  
Andrzej Cwirzen

Most of the currently used concretes are based on ordinary Portland cement (OPC) which results in a high carbon dioxide footprint and thus has a negative environmental impact. Replacing OPCs, partially or fully by ecological binders, i.e., supplementary cementitious materials (SCMs) or alternative binders, aims to decrease the carbon dioxide footprint. Both solutions introduced a number of technological problems, including their performance, when exposed to low, subfreezing temperatures during casting operations and the hardening stage. This review indicates that the present knowledge enables the production of OPC-based concretes at temperatures as low as −10 °C, without the need of any additional measures such as, e.g., heating. Conversely, composite cements containing SCMs or alkali-activated binders (AACs) showed mixed performances, ranging from inferior to superior in comparison with OPC. Most concretes based on composite cements require pre/post heat curing or only a short exposure to sub-zero temperatures. At the same time, certain alkali-activated systems performed very well even at −20 °C without the need for additional curing. Chemical admixtures developed for OPC do not always perform well in other binder systems. This review showed that there is only a limited knowledge on how chemical admixtures work in ecological concretes at low temperatures and how to accelerate the hydration rate of composite cements containing high amounts of SCMs or AACs, when these are cured at subfreezing temperatures.


Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 3071
Author(s):  
Andri Isak Thorhallsson ◽  
Francesco Fanicchia ◽  
Emily Davison ◽  
Shiladitya Paul ◽  
Svava Davidsdottir ◽  
...  

Geothermal process equipment and accessories are usually manufactured from low-alloy steels which offer affordability but increase the susceptibility of the materials to corrosion. Applying erosion-corrosion-resistant coatings to these components could represent an economical solution to the problem. In this work, testing of two newly developed laser metal deposited high-entropy alloy (LMD-HEA) coatings—CoCrFeNiMo0.85 and Al0.5CoCrFeNi, applied to carbon and stainless steels—was carried out at the Hellisheidi geothermal power plant. Tests in three different geothermal environments were performed at the Hellisheidi site: wellhead test at 194 °C and 14 bar, erosion test at 198 °C and 15 bar, and aerated test at 90 °C and 1 bar. Post-test microstructural characterization was performed via Scanning Eletron Microscope (SEM), Back-Scattered Electrons analysis (BSE), Energy Dispersive X-ray Spectroscopy (EDS), optical microscopy, and optical profilometry while erosion assessment was carried out using an image and chemical analysis. Both the CoCrFeNiMo0.85 and Al0.5CoCrFeNi coatings showed manufacturing defects (cracks) and were prone to corrosion damage. Results show that damage in the CoCrFeNiMo0.85-coated carbon steel can be induced by manufacturing defects in the coating. This was further confirmed by the excellent corrosion resistance performance of the CoCrFeNiMo0.85 coating deposited onto stainless steel, where no manufacturing cracks were observed.


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