Thermodynamic Modeling of the Mg-Ni-La-Cu System

2011 ◽  
Vol 314-316 ◽  
pp. 1262-1267 ◽  
Author(s):  
Xue Hui An ◽  
Qian Li ◽  
Jie Yu Zhang
Keyword(s):  
Experimental Data ◽  
Isothermal Section ◽  
Ternary System ◽  
Hydrogen Storage ◽  
Vertical Section ◽  
Solidification Path ◽  
Hydrogen Storage Alloys ◽  
Equilibrium Solidification ◽  
Good Agreement ◽  
Phase Relationships

The isothermal section at 573 K of the Ni-Cu-La system was experimentally validated as well as the Mg-La-Cu system was thermodynamically evaluated. Four sample alloys in the Ni-Cu-La system were prepared and analyzed by ICP, XRD and BSE/EDS. All the experimental results were compared favorably with the calculated phase relationships. For the Mg-La-Cu ternary system, the isothermal section at 673 K was assessed on the basis of the available results in literatures, which showed a good agreement with the experimental data. Based on the thermodynamic models and parameters of the six binaries and four ternaries, the Mg-Ni-La-Cu system was finally modeled. The non-equilibrium solidification path La0.7Mg0.3Ni2.8-xCux (x=0-0.4) and the vertical section of LaNi5-Mg2Cu were calculated and analyzed from the viewpoint of hydrogen storage alloys design.

Diffusion Paths in the Ternarysystem Fe-Co-Ni: An Empirical Approach

2011 ◽  
Vol 312-315 ◽  
pp. 411-416
Author(s):  
J. Priimets ◽  
Ü. Ugaste
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Diffusion Path ◽  
Universal Function ◽  
Empirical Approach ◽  
Diffusion Couples ◽  
Diffusion Paths ◽  
Two Parameters ◽  
Good Agreement

An empirical approach to the description of diffusion paths in the ternary system Fe-Co-Ni is developed. It is shown that the experimentally determined diffusion path in this system can be described by the universal function, which contains two parameters, extracted from experimental data. The values of these parameters and their possible dependence on initial compositions of diffusion couples are discussed. Using the universal function, typical diffusion paths for the system Fe-Co-Ni have been calculated. It is shown that the calculated diffusion paths are in a qualitatively good agreement with the available experimental data.

Microstructure Evolution in Undercooled Ni-Si Melt

2013 ◽  
Vol 749 ◽  
pp. 349-355
Author(s):  
Kai Fan ◽  
Feng Liu ◽  
Bao Quan Fu ◽  
Wen Zhong Luo ◽  
Yao He Zhou
Keyword(s):  
Experimental Data ◽  
Grain Size ◽  
Grain Refinement ◽  
Microstructure Evolution ◽  
Solid Solubility ◽  
Molten Glass ◽  
Dendrite Fragmentation ◽  
Equilibrium Solidification ◽  
Good Agreement ◽  
Non Equilibrium

Upon non-equilibrium solidification, the intrinsic parameters, such as moving velocity, temperature, solute partition coefficient, and liquid and solid concentrations at the interface, deviate from their equilibrium characteristics, and the morphology of the as-solidified structure and the grain size are influenced by the non-equilibrium liqulid/solid transformation, which further influences the subquent solidstate transformation. Adopting molten glass purification technology combined with cycle superheating method, the microstructure evolution of Ni-11at.%Si alloy in different undercooling was investigated. It was found that, with the increase of the initial undercooling, grain refinement occurred in microstructures of undercooled Ni-11at.%Si alloy. Meanwhile, the NL model was used to discuss the two different dendrite morphologies. According to Karmas model for dendrite fragmentation, the grain refinement of undercooled Ni-11at.%Si alloy was in good agreement with the experimental data, and the grain size was reduced with the increasing ΔT. The energy-dispersive spectroscopy (EDS) measurement was applied to analyze the solid solubility of Si atom in α-Ni matrix. It was found that the solid solubility of Si atom in α-Ni matrix increased with undercooling. At the undercooling of T>220K , a complete solute trapping occurred.

Study of Electrical Conductivity in WO3-doped Nonstoichiometric LiTaO3

2012 ◽  
Vol 57 (8) ◽  
pp. 834
Author(s):  
M. Tahiri ◽  
N. Masaif ◽  
A. Jennane ◽  
E.M. Lotfi
Keyword(s):  
Experimental Data ◽  
Electrical Conductivity ◽  
Ternary System ◽  
Curie Temperature ◽  
Solid Solutions ◽  
Theoretical Approach ◽  
Defect Structure ◽  
Experimental Conductivity ◽  
Theoretical Results ◽  
Good Agreement

The results of experimental and analytical studies of the electrical conductivity for different solid solutions synthesized in a vicinity of LiTaO3 in the ternary system Li2O–Ta2O5–(WO3)2 are presented. It is shown that the electrical conductivity increases linearly with the Curie temperature. The experimental conductivity between 200 and 700 ºC was measured using an LCR bridge HP4192A on ceramics sintered at 1250 ºC. Within the theoretical approach to the defect structure analysis combined with our proposed vacancy models, the theoretical results are in a good agreement with the experimental data.

Assessment of the Phase Equilibria among γ-Fe/ Fe2Nb/ Ni3Nb Phases in Fe-Ni-Nb Ternary System at Elevated Temperatures

2011 ◽  
Vol 1295 ◽  
Author(s):  
Y. Hasebe ◽  
K. Hashimoto ◽  
T. Matsuo ◽  
M. Takeyama
Keyword(s):  
Isothermal Section ◽  
Ternary System ◽  
Phase Equilibria ◽  
Ternary Compound ◽  
Elevated Temperatures ◽  
Composition Range ◽  
Interaction Parameters ◽  
Three Phase ◽  
Good Agreement

ABSTRACTPhase equilibria among γ-Fe, ε-Fe2Nb Laves and δ-Ni3Nb phases in Fe-Ni-Nb ternary system at 1473 K and 1373 K were experimentally examined, and also assessed by calculation in order to calculate the phase equilibria among these phases at 973 K. A ternary compound with hP24 structure with its limited composition range of Fe-21.5Nb- (56.8-59.8) Ni exists between Fe2Nb and Ni3Nb phase regions at both temperatures. Including the hP24 phase, the calculated isotherms at both temperatures are in good agreement with experimental ones. By using the optimized interaction parameters among the three elements in each phase, the isothermal section calculated at 973 K revealed a γ-Fe+ Fe2Nb + Ni3Nb three-phase coexisting region extended to Fe-rich composition of 80 at. % Fe. This suggests a possibility to develop austenitic heatresistant steels strengthened by both intermetallics phases.

New La–Fe–B ternary system hydrogen storage alloys

2010 ◽  
Vol 35 (11) ◽  
pp. 5687-5692 ◽  
Author(s):  
H.Z. Yan ◽  
F.Q. Kong ◽  
W. Xiong ◽  
B.Q. Li ◽  
J. Li ◽  
...  
Keyword(s):  
Ternary System ◽  
Hydrogen Storage ◽  
Hydrogen Storage Alloys

RECONSTRUCTION OF PRESSURE–COMPOSITION–TEMPERATURE CURVES OFRNi5(R = La, Pr, Nd, and Sm) HYDROGEN STORAGE MATERIALS BY COMPUTER SIMULATION

2009 ◽  
Vol 08 (04n05) ◽  
pp. 409-413
Author(s):  
VASILEIOS TSEROLAS ◽  
MASAHIKO KATAGIRI ◽  
HIDEHIRO ONODERA ◽  
HIROSHI OGAWA
Keyword(s):  
Experimental Data ◽  
Computer Simulation ◽  
Simple Model ◽  
Hydrogen Storage ◽  
Electrochemical Performance ◽  
Plateau Pressure ◽  
Hydrogen Storage Materials ◽  
Hydrogen Atoms ◽  
Storage Materials ◽  
Good Agreement

RNi5-type metal hydride materials have been simulated by using a simple model. These materials have been thoroughly studied with respect to their physical and electrochemical performance. Examples of simulated P–C–T curves are drawn. The simulations demonstrate good agreement with the experimental data reported for various RNi5-type hydrogen storage materials. As expected, the plateau pressure increases with increasing temperatures. It also becomes more difficult to insert hydrogen atoms at higher temperatures, which is generally accepted to occur. Finally, limitations of the model are discussed and possible solutions to overcome these limitations are proposed.

scholarly journals Thermodynamic re-assessment of the Al-Sn-Zn ternary system

2019 ◽  
Vol 55 (3) ◽  
pp. 439-449 ◽  
Author(s):  
T. Cheng ◽  
L.-J. Zhang
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Phase Equilibria ◽  
Experimental Phase Equilibria ◽  
Calphad Approach ◽  
Experimental Phase ◽  
Ternary Interaction ◽  
Self Consistent ◽  
Comprehensive Comparison ◽  
Good Agreement

In this paper, a thermodynamic re-assessment of the Al-Sn-Zn ternary system was performed by means of the CALculation of PHAse Diagram (CALPHAD) approach. The thermodynamic descriptions of the binary Al-Sn, Al-Zn, and Sn-Zn systems from the literature were directly adopted, and the newly reported experimental phase equilibria, enthalpies of mixing, and activities of Al in the ternary liquid phase were taken into account. A set of self-consistent thermodynamic parameters for the ternary Al-Sn-Zn system were finally obtained. A comprehensive comparison between the presently calculated phase equilibria/thermodynamic properties and the experimental data indicates that the present thermodynamic descriptions of the ternary Al-Sn-Zn system show very good agreement with most of the experimental data. The further direct comparison with the calculated results due to the previous assessment demonstrates that a significant improvement was achieved by the present assessment though fewer ternary interaction parameters were utilized.

Energy Levels and Electromagnetic Transition of 90-94mo Nuclei Using Ibm-1

2020 ◽  
pp. 149-152
Keyword(s):  
Experimental Data ◽  
Transition Probability ◽  
Energy Levels ◽  
Dynamical Symmetry ◽  
Interacting Boson Model ◽  
Excitation Energies ◽  
Electromagnetic Transition ◽  
Boson Model ◽  
Energy States ◽  
Good Agreement

The energy states for the J , b , ɤ bands and electromagnetic transitions B (E2) values for even – even molybdenum 90 – 94 Mo nuclei are calculated in the present work of "the interacting boson model (IBM-1)" . The parameters of the equation of IBM-1 Hamiltonian are determined which yield the best excellent suit the experimental energy states . The positive parity of energy states are obtained by using IBS1. for program for even 90 – 94 Mo isotopes with bosons number 5 , 4 and 5 respectively. The" reduced transition probability B(E2)" of these neuclei are calculated and compared with the experimental data . The ratio of the excitation energies of the 41+ to 21+ states ( R4/2) are also calculated . The calculated and experimental (R4/2) values showed that the 90 – 94 Mo nuclei have the vibrational dynamical symmetry U(5). Good agreement was found from comparison between the calculated energy states and electric quadruple probabilities B(E2) transition of the 90–94Mo isotopes with the experimental data .

Predicting the Effect of Tire Tread Pattern Design on Thick Film Wet Traction

1977 ◽  
Vol 5 (1) ◽  
pp. 6-28 ◽  
Author(s):  
A. L. Browne
Keyword(s):  
Experimental Data ◽  
Network Design ◽  
Thick Film ◽  
Digital Computer ◽  
Analytical Tool ◽  
Design Practice ◽  
Pattern Design ◽  
Performance Results ◽  
Good Agreement

Abstract An analytical tool is presented for the prediction of the effects of changes in tread pattern design on thick film wet traction performance. Results are reported for studies in which the analysis, implemented on a digital computer, was used to determine the effect of different tread geometry features, among these being the number, width, and lateral spacing of longitudinal grooves and the angle of zigzags in longitudinal grooves, on thick film wet traction. These results are shown to be in good agreement with experimental data appearing in the literature and are used to formulate guidelines for tread groove network design practice.

A New Condition of Formation and Stablity of All Crystalline Systems in a Good Agreement with Experimental Data

2015 ◽  
Vol 11 (3) ◽  
pp. 3224-3228
Author(s):  
Tarek El-Ashram
Keyword(s):  
Experimental Data ◽  
Brillouin Zone ◽  
Electron Concentration ◽  
Free Electron ◽  
Lattice Point ◽  
Valence Electron ◽  
Fermi Gas ◽  
Valence Electron Concentration ◽  
Fermi Sphere ◽  
Good Agreement

In this paper we derived a new condition of formation and stability of all crystalline systems and we checked its validity andit is found to be in a good agreement with experimental data. This condition is derived directly from the quantum conditionson the free electron Fermi gas inside the crystal. The new condition relates both the volume of Fermi sphere VF andvolume of Brillouin zone VB by the valence electron concentration VEC as ;𝑽𝑭𝑽𝑩= 𝒏𝑽𝑬𝑪𝟐for all crystalline systems (wheren is the number of atoms per lattice point).

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