Dynamic Simulation of the Boron Isotopes Separation by Chemical Exchange Method

2012 ◽  
Vol 442 ◽  
pp. 62-66 ◽  
Author(s):  
Jin Cui ◽  
Wei Jiang Zhang ◽  
Feng Hai Miao
Keyword(s):  
Flow Rate ◽  
Chemical Exchange ◽  
Dynamic Change ◽  
Abundance Ratio ◽  
Enrichment Ratio ◽  
Boron Isotopes ◽  
Rate Variation ◽  
Feed Flow Rate ◽  
Exchange Method ◽  
Isotopes Separation

Abstract The enrichment ratio of 10B in the top and bottom component with the dynamic change of feed fluctuation and periodic wave on the separation process of the boron isotopes separation by chemical exchange method had been studied and a dynamic model was set up. The results indicate that when the feed amount is in the column load limit, the dynamic responses of top and bottom separation plate match well with the condition when feed flow rate is invariable. While when the exchange column is overloaded, the feed flow rate variation influences 10B abundance ratio greatly. With the increasing of the fluctuation period, the longer the wave period, the bigger the amplitude around the average line in top product. However, big increase of feed fluctuation will reduce the 10B abundance ratio of bottom product.

Operational policy of the boron isotopes separation by chemical exchange reaction and distillation

2008 ◽  
Vol 47 (1) ◽  
pp. 17-21 ◽  
Author(s):  
Feng Wei ◽  
Weijiang Zhang ◽  
Meng Han ◽  
Liguo Han ◽  
Xuemei Zhang ◽  
...  
Keyword(s):  
Exchange Reaction ◽  
Chemical Exchange ◽  
Boron Isotopes ◽  
Isotopes Separation

Recovery of Molybdenum (VI) from Aqueous Solution with Packed Foam Column by Steady-State

2013 ◽  
Vol 641-642 ◽  
pp. 270-276
Author(s):  
Yong Qiang Zhang ◽  
Jing Wang ◽  
Mei Ling Shi ◽  
Xiao Xian Zhao
Keyword(s):  
Aqueous Solution ◽  
Steady State ◽  
Flow Rate ◽  
Recovery Rate ◽  
Surfactant Concentration ◽  
Separation Efficiency ◽  
Enrichment Ratio ◽  
Feed Flow Rate ◽  
Experimental Conditions ◽  
Distribution Density Function

The purpose of this study is to recover molybdenum (VI) from aqueous solution with packed foam column by steady-state operation using hexadecyl trimethyl ammonium chloride as the surfactant. The parameters include air and feed flow rate, packing layer heights, surfactant concentration and pH etc, then the macroscopical dynamics is studied. The experimental results show that there are little effects of liquor pH, air flowrate and surfactant concentration on recovery rate and enrichment ratio of molybdenum within experimental conditions, but with increase of feed flow rate, recovery rate and enrichment ratio all decline clearly, with increase of packing height, recovery rate enhances evidently, and enrichment ratio decreases slowly. The macroscopical dynamics show that the process can be regarded as first order reaction. The fluid flow pattern is close to piston, indicating that there is little liquid backmixing and in favor of advancing separation efficiency by analyzing variance and distribution density function.

scholarly journals Process Intensification of Chemical Exchange Method for Boron Isotope Separation Using Micro-Channel Distillation Technology

Micromachines ◽  
2021 ◽  
Vol 12 (10) ◽  
pp. 1222
Author(s):  
Yin Tang ◽  
Yongjie Zheng ◽  
Jingzhi Tian ◽  
Jing Sun
Keyword(s):  
Separation Efficiency ◽  
Chemical Exchange ◽  
Isotope Separation ◽  
Three Dimensional ◽  
Theoretical Plate ◽  
Process Intensification ◽  
Boron Isotopes ◽  
Micro Channel ◽  
Exchange Method ◽  
In Series

A micro-channel distillation device was used for the process intensification method to separate boron isotopes, 10B and 11B. Three-dimensional (3D) printing technology was introduced to manufacture the micro-channel device, which used the chemical exchange method with anisole as the donor to separate the boron isotopes. This device was tested in total reflux mode, and the height of an equivalent theoretical plate of the micro-channel distillation equipment was reduced to 1.56 cm. The accurate control of pressure and temperature, as well as the flow rate of the complex, were factors that affected separation ability. Thus, for process intensification, this micro-channel distillation device can be operated horizontally and connected in series into similar modules to effectively improve separation efficiency and reduce the size of the equipment.

Experimental and Modelling of Aqueous Radioactive Waste Treatment by Ultrafiltration

2018 ◽  
Vol 69 (5) ◽  
pp. 1149-1151
Author(s):  
Laura Ruxandra Zicman ◽  
Elena Neacsu ◽  
Felicia Nicoleta Dragolici ◽  
Catalin Ciobanu ◽  
Gheorghe Dogaru ◽  
...  
Keyword(s):  
Flow Rate ◽  
Suspended Solids ◽  
Waste Treatment ◽  
Operating Pressure ◽  
Feed Flow Rate ◽  
Permeate Flux ◽  
Independent Variables ◽  
Opposite Trend ◽  
Process Factors ◽  
Volumetric Flux

Ultrafiltration of untreated and pretreated aqueous radioactive wastes was conducted using a spiral-wound polysulphonamide membrane. The influence of process factors on its performances was experimental studied and predicted. Permeate volumetric flux and permeate total suspended solids (TSS) were measured at different values of feed flow rate (7 and 10 m3/h), operating pressure (0.1-0.4 MPa), and feed TSS (15 and 60 mg/L). Permeate flux (42-200 L/(m2�h)) increased with feed flow rate and operating pressure as well as it decreased with an increase in feed TSS, whereas permeate TSS (0.1-33.2 mg/L) exhibited an opposite trend. A 23 factorial plan was used to establish correlations between dependent and independent variables of ultrafiltration process.

scholarly journals Effects of Fe-Doped Electrolyte and Feed Flow Rate Evaluation in Home Made Solid Oxide Fuel Cell

2021 ◽  
Vol 1143 (1) ◽  
pp. 012007
Author(s):  
Hary Devianto ◽  
Isdiriyani Nurdin ◽  
Pramujo Widiatmoko ◽  
Kafi Adi Prasetya ◽  
Basil Pradipta
Keyword(s):  
Fuel Cell ◽  
Solid Oxide Fuel Cell ◽  
Flow Rate ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Feed Flow Rate ◽  
Rate Evaluation

Column Study for Adsorption of Methylene Blue Dye using Azadirachta indica Adsorbent

2020 ◽  
Vol 17 (4) ◽  
pp. 47-52
Author(s):  
Vibha Goswami ◽  
Renu Upadhyaya ◽  
Sumanta Kumar Meher
Keyword(s):  
Methylene Blue ◽  
Flow Rate ◽  
Azadirachta Indica ◽  
Packed Bed ◽  
Blue Dye ◽  
Feed Flow Rate ◽  
Methylene Blue Dye ◽  
Packed Bed Column ◽  
Bed Height ◽  
Percentage Removal

In this study, synthesised Azadirachta indica adsorbent was used for the removal of methylene blue dye using a packed bed column. The effect of feed flow rate, feed methylene blue dye concentration, and bed height of column on percentage removal of dye was studied. It was observed that the column bed exhausted rapidly at a higher flow rate and therefore, a breakthrough occurred faster. However, it was observed that bed exhaustion time increases on increasing the bed height from 2 to 10 inch at 10 mg/L feed dye concentration and feed flow rate of 40 ml/min. It was also found that the breakthrough curve is more dispersed and the percentage removal of dye increases on decreasing the feed methylene dye concentration from 150 to 10 mg/L. The percentage removal was found to be 96.89% at 20 ml/min of feed flow rate under 10 inch of bed height and 10 mg/L of feed dye concentration. The atomic absorption spectrophotometer and scanning electron microscope were used for estimating the effluent dye concentration from the column and morphological study, respectively.

scholarly journals Dynamic Modelling and Simulation of a Multistage Flash Desalination System

Processes ◽  
2021 ◽  
Vol 9 (3) ◽  
pp. 522
Author(s):  
Qiu-Yun Huang ◽  
Ai-Peng Jiang ◽  
Han-Yu Zhang ◽  
Jian Wang ◽  
Yu-Dong Xia ◽  
...  
Keyword(s):  
Real Time ◽  
Mass Flow Rate ◽  
Mass Flow ◽  
Flow Rate ◽  
Dynamic Change ◽  
Seawater Temperature ◽  
Dynamic Modelling ◽  
Optimal Operation ◽  
Simultaneous Solution ◽  
Time Optimal

As the leading thermal desalination method, multistage flash (MSF) desalination plays an important role in obtaining freshwater. Its dynamic modeling and dynamic performance prediction are quite important for the optimal control, real-time optimal operation, maintenance, and fault diagnosis of MSF plants. In this study, a detailed mathematical model of the MSF system, based on the first principle and its treatment strategy, was established to obtain transient performance change quickly. Firstly, the whole MSF system was divided into four parts, which are brine heat exchanger, flashing stage room, mixed and split modulate, and physical parameter modulate. Secondly, based on mass, energy, and momentum conservation laws, the dynamic correlation equations were formulated and then put together for a simultaneous solution. Next, with the established model, the performance of a brine-recirculation (BR)-MSF plant with 16-stage flash chambers was simulated and compared for validation. Finally, with the validated model and the simultaneous solution method, dynamic simulation and analysis were carried out to respond to the dynamic change of feed seawater temperature, feed seawater concentration, recycle stream mass flow rate, and steam temperature. The dynamic response curves of TBT (top brine temperature), BBT (bottom brine temperature), the temperature of flashing brine at previous stages, and distillate mass flow rate at previous stages were obtained, which specifically reflect the dynamic characteristics of the system. The presented dynamic model and its treatment can provide better analysis for the real-time optimal operation and control of the MSF system to achieve lower operational cost and more stable freshwater quality.

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