Production of High Calorific Biogas from Organic Wastewater and Enhancement of Anaerobic Digestion

2012 ◽  
Vol 550-553 ◽  
pp. 522-528 ◽  
Author(s):  
Yan Qiu Nie ◽  
Yu Xiu Li ◽  
Hui He ◽  
Wen Jing Zhou ◽  
Zhao Hui Pang ◽  
...  

Anaerobic digestion is a widely applied technology to produce biogas from organic wastewater. The biogas calorific value depends on the methane-content. For biogas flows >100 m3/h, the two-step process is usually used for production of high calorific biogas from organic wastewater: the first step, anaerobic digestion; the second step, biogas purification. However, for biogas flows 3/h, biogas purification is not economical, and one-step process according to the big gap between methane and non-methane-gas in solubility at higher pressure or lower temperature, should be condidered. New anaerobic digestion processes, such as micro-aerobic process, electrolysis enhancing methane production process, process of internal circulation anaerobic digester (ICAD) with sewage source heat pump, may all enhance biogas producton or lower biogas production cost. In addition, suitable environmental conditions, such as organic loading rate (OLR), solid retention time (SRT), hydraulic retention time (HRT) and surface area, are all beneficial to enhance methane fermentation. Furthermore, new operation modes and optimal dose of trace metals might be selected.

2013 ◽  
Author(s):  
Kevin N. Nwaigwe ◽  
Nnamdi V. Ogueke ◽  
Chibuike Ononogbo ◽  
Emmanuel E. Anyanwu

A performance study of anaerobic digestion of organic municipal waste in upflow bioreactor with central substrate dispenser is presented. The experimental rig is based on an integrated system of bioreactors consisting of Upflow Bioreactor (UB), Upflow Bioreactor with Central Subtrate Dispenser (UBCSD), and Continous Stirred Tank Reactor (CSTR) each having internal volume of 76 litres, 64.8 litres, and 76 litres respectively. The scheme is used for minimizing the mixing and fouling problems associated with some conventional bioreactors during digestion reaction. Organic municipal waste (OMW) was used to prepare the slurry for the reactors. Microbial reaction was enhanced during operation using a measured quantity (2kg) of substances from the rumen of a newly slaughtered cow. The experimentation from feeder tank to Bioreactors was carried out for a period of 10-days Hydraulic Retention Time (HRT) at 37°C. Effects of some basic parameters affecting anaerobic digestion in terms of biogas production and Chemical Oxygen Demand (COD) reduction were carried out. They include substrate temperature, minimal average temperature, changes in temperature, substrate content and properties, available nutrient, retention time, organic loading rate, pH level, nitrogen inhibition and C/N ratio, substrate agitation, and inhibitory factors. Results showed that UBSCD generated the highest level of Biogas yield of up to 52915 ml, while UB and CSTR yielded 23550ml and 28980ml respectively. Similarly for COD removal, 24343 mg/l, 5775.4 mg/l, and 23155 mg/l were achieved for UBCSD, UB and CSTR respectively from an initial value of 120,320 mg/l. These results show that the use of UBCSD better enhances biofuel production from organic municipal waste.


Author(s):  
Napisa Pattharaprachayakul ◽  
Narumon Kesonlam ◽  
Pongpitak Duangjumpa ◽  
Vilai Rungsardthong ◽  
Worakrit Suvajittanont ◽  
...  

Pineapple wastes are produced in huge amount during the industrial canning process of pineapple; in Thailand over 400,000 tons per annum of canned pineapple exported leaving behind the waste. Besides the pulps and peels as solid wastes, the squeezed pineapple liquid wastes (SPLW) extracted from solid wastes can also be used for anaerobic digestion. In the present study, the anaerobic digestion of liquid squeezed from industrial pineapple peels was carried out using a lab-scale hybrid reactor. The reactor was operated for over 170 days with the hydraulic retention time (HRT) of 20 days decreasing down to 5 days and simultaneous control of organic loading rate (OLR). Under controlled conditions in the hybrid reactor, pH was maintained at 6.5–7.6 by adding alkaline for anaerobic microbial activity. Results showed that the chemical oxygen demand (COD) removal efficiency was at ≥ 90% for all conditions. The biogas production (mL/day) increased thoroughly from longer HRT to shorter HRT, as same as methane production with the maximum values (HRT 5 days, OLR 5 g/COD/ day with recirculation) of 55,130 and 30,322 mL/day, respectively. Moreover, the highest yields of biogas and methane were also investigated under similar conditions with the values of 0.504 and 0.277 L/gCOD, respectively. Interestingly, this optimization of both HRT and OLR of lab-scale anaerobic digestion process could be further practically applied to pilot or industrial scale in canned pineapple factories for biogas production.


2018 ◽  
Vol 7 (2) ◽  
pp. 93-100 ◽  
Author(s):  
Agus Haryanto ◽  
Sugeng Triyono ◽  
Nugroho Hargo Wicaksono

The efficiency of biogas production in semi-continuous anaerobic digester is influenced by several factors, among other is loading rate. This research aimed at determining the effect of hydraulic retention time (HRT) on the biogas yield. Experiment was conducted using lab scale self-designed anaerobic digester of 36-L capacity with substrate of a mixture of fresh cow dung and water at a ratio of 1:1. Experiment was run with substrate initial amount of 25 L and five treatment variations of HRT, namely 1.31 gVS/L/d (P1), 2.47 gVS/L/d (P2), 3.82 gVS/L/d (P3), 5.35 gVS/L/d (P4) and 6.67 gVS/L/d (P5). Digester performance including pH, temperature, and biogas yield was measured every day. After stable condition was achieved, biogas composition was analyzed using a gas chromatograph. A 10-day moving average analysis of biogas production was performed to compare biogas yield of each treatment. Results showed that digesters run quite well with average pH of 6.8-7.0 and average daily temperature 28.7-29.1. The best biogas productivity (77.32 L/kg VSremoval) was found in P1 treatment (organic loading rate of 1.31 g/L/d) with biogas yield of 7.23 L/d. With methane content of 57.23% treatment P1 also produce the highest methane yield. Biogas production showed a stable rate after the day of 44. Modified Gompertz kinetic equation is suitable to model daily biogas yield as a function of digestion time.Article History: Received March 24th 2018; Received in revised form June 2nd 2018; Accepted June 16th 2018; Available onlineHow to Cite This Article: Haryanto, A., Triyono, S., and Wicaksono, N.H. (2018) Effect of Loading Rate on Biogas Production from Cow Dung in A Semi Continuous Anaerobic Digester. Int. Journal of Renewable Energy Development, 7(2), 93-100.https://doi.org/10.14710/ijred.7.2.93-100


2020 ◽  
Author(s):  
Dejene Tsegaye Bedane ◽  
Mohammed Mazharuddin Khan ◽  
Seyoum Leta Asfaw

Abstract Background : Wastewater from agro-industries such as slaughterhouse is typical organic wastewater with high value of biochemical oxygen demand, chemical oxygen demand, biological organic nutrients (Nitrogen and phosphate) which are insoluble, slowly biodegradable solids, pathogenic and non-pathogenic bacteria and viruses, parasite eggs. Moreover it contains high protein and putrefies fast leading to environmental pollution problem. This indicates that slaughterhouses are among the most environmental polluting agro-industries. Anaerobic digestion is a sequence of metabolic steps involving consortiums of several microbial populations to form a complex metabolic interaction network resulting in the conversation of organic matter into methane (CH 4 ), carbon dioxide (CO 2 ) and other trace compounds. Separation of the phase permits the optimization of the organic loading rate and HRT based on the requirements of the microbial consortiums of each phase. The purpose of this study was to optimize the working conditions for the hydrolytic - acidogenic stage in two step/phase anaerobic digestion of slaughterhouse wastewater. The setup of the laboratory scale reactor was established at Center for Environmental Science, College of Natural Science with a total volume of 40 liter (36 liter working volume and 4 liter gas space). The working parameters for hydrolytic - acidogenic stage were optimized for six hydraulic retention time 1-6 days and equivalent organic loading rate of 5366.43 – 894.41 mg COD/L day to evaluate the effect of the working parameters on the performance of hydrolytic – acidogenic reactor. Result : The finding revealed that hydraulic retention time of 3 day with organic loading rate of 1,788.81 mg COD/L day was a as an optimal working conditions for the parameters under study for the hydrolytic - acidogenic stage. The degree of hydrolysis and acidification were mainly influenced by lower hydraulic retention time (higher organic loading rate) and highest values recorded were 63.92 % at hydraulic retention time of 3 day and 53.26% at hydraulic retention time of 2 day respectively. Conclusion : The finding of the present study indicated that at steady state the concentration of soluble chemical oxygen demand and total volatile fatty acids increase as hydraulic retention time decreased or organic loading rate increased from 1 day hydraulic retention time to 3 day hydraulic retention time and decreases as hydraulic retention time increase from 4 to 6 day. The lowest concentration of NH 4 + -N and highest degree of acidification was also achieved at hydraulic retention time of 3 day. Therefore, it can be concluded that hydraulic retention time of 3 day/organic loading rate of 1,788.81 mg COD/L .day was selected as an optimal working condition for the high performance and stability during the two stage anaerobic digestion of slaughterhouse wastewater for the hydrolytic-acidogenic stage under mesophilic temperature range selected (37.5℃). Keywords : Slaughterhouse Wastewater, Hydrolytic – Acidogenic, Two Phase Anaerobic Digestion, Optimal Condition, Agro-processing wastewater


Energies ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2392 ◽  
Author(s):  
Marcin Dębowski ◽  
Marcin Zieliński ◽  
Marta Kisielewska ◽  
Joanna Kazimierowicz

The aim of this study was the performance evaluation of anaerobic digestion of dairy wastewater in a multi-section horizontal flow reactor (HFAR) equipped with microwave and ultrasonic generators to stimulate biochemical processes. The effects of increasing organic loading rate (OLR) ranging from 1.0 g chemical oxygen demand (COD)/L·d to 4.0 g COD/L·d on treatment performance, biogas production, and percentage of methane yield were determined. The highest organic compounds removals (about 85% as COD and total organic carbon—TOC) were obtained at OLR of 1.0–2.0 g COD/L·d. The highest biogas yield of 0.33 ± 0.03 L/g COD removed and methane content in biogas of 68.1 ± 5.8% were recorded at OLR of 1.0 g COD/L·d, while at OLR of 2.0 g COD/L·d it was 0.31 ± 0.02 L/COD removed and 66.3 ± 5.7%, respectively. Increasing of the OLR led to a reduction in biogas productivity as well as a decrease in methane content in biogas. The best technological effects were recorded in series with an operating mode of ultrasonic generators of 2 min work/28 min break. More intensive sonication reduced the efficiency of anaerobic digestion of dairy wastewater as well as biogas production. A low nutrient removal efficiency was observed in all tested series of the experiment, which ranged from 2.04 ± 0.38 to 4.59 ± 0.68% for phosphorus and from 9.67 ± 3.36 to 20.36 ± 0.32% for nitrogen. The effects obtained in the study (referring to the efficiency of wastewater treatment, biogas production, as well as to the results of economic analysis) proved that the HFAR can be competitive to existing industrial technologies for food wastewater treatment.


2018 ◽  
Vol 65 ◽  
pp. 05025 ◽  
Author(s):  
Sagor Kumar Pramanik ◽  
Fatihah Binti Suja ◽  
Biplob Kumar Pramanik ◽  
Shahrom Bindi Md Zain

Solid organic wastes create potential risks to environmental pollution and human health due to the uncontrolled discharge of huge quantities of hazardous wastes from numerous sources. Now-a-days, anaerobic digestion (AD) is considered as a verified and effective alternative compared to other techniques for treating solid organic waste. The paper reviewed the biological process and parameters involved in the AD along with the factors could enhance the AD process. Hydrolysis is considered as a rate-limiting phase in the complex AD process. The performance and stability of AD process is highly influenced by various operating parameters like temperature, pH, carbon and nitrogen ratio, retention time, and organic loading rate. Different pre-treatment (e.g. mechanical, chemical and biological) could enhance the AD process and the biogas yield. Co-digestion can also be used to provide suitable nutrient balance inside the digester. Challenges of the anaerobic digestion for biogas production are also discussed.


Processes ◽  
2020 ◽  
Vol 8 (11) ◽  
pp. 1487
Author(s):  
Vicky De Groof ◽  
Marta Coma ◽  
Tom C. Arnot ◽  
David J. Leak ◽  
Ana B. Lanham

Production of medium chain carboxylic acids (MCCA) as renewable feedstock bio-chemicals, from food waste (FW), requires complicated reactor configurations and supplementation of chemicals to achieve product selectivity. This study evaluated the manipulation of organic loading rate in an un-supplemented, single stage stirred tank reactor to steer an anaerobic digestion (AD) microbiome towards acidogenic fermentation (AF), and thence to chain elongation. Increasing substrate availability by switching to a FW feedstock with a higher COD stimulated chain elongation. The MCCA species n-caproic (10.1 ± 1.7 g L−1) and n-caprylic (2.9 ± 0.8 g L−1) acid were produced at concentrations comparable to more complex reactor set-ups. As a result, of the adjusted operating strategy, a more specialised microbiome developed containing several MCCA-producing bacteria, lactic acid-producing Olsenella spp. and hydrogenotrophic methanogens. By contrast, in an AD reactor that was operated in parallel to produce biogas, the retention times had to be doubled when fed with the high-COD FW to maintain biogas production. The AD microbiome comprised a diverse mixture of hydrolytic and acidogenic bacteria, and acetoclastic methanogens. The results suggest that manipulation of organic loading rate and food-to-microorganism ratio may be used as an operating strategy to direct an AD microbiome towards AF, and to stimulate chain elongation in FW fermentation, using a simple, un-supplemented stirred tank set-up. This outcome provides the opportunity to repurpose existing AD assets operating on food waste for biogas production, to produce potentially higher value MCCA products, via simple manipulation of the feeding strategy.


2018 ◽  
Vol 36 (11) ◽  
pp. 1106-1112 ◽  
Author(s):  
Xiaohui Guo ◽  
Kang Kang ◽  
Gaoyuan Shang ◽  
Xiunan Yu ◽  
Ling Qiu ◽  
...  

The mesophilic reactor (MR) exhibited advantages in biogas production and performance stability over thermophilic reactor (TR) during the long-term anaerobic digestion (AD) of food waste (FW) with stepwise organic loading rate elevating. It was interesting to explore the mechanism causing the divergences in performances between these two reactors. The microbial activity was compared on day 110 when TR began to deteriorate. The results show that MR had significantly higher specific acetoclastic methanogenic activities (SAMA) and specific propionate and butyrate oxidative activities (SPOA and SBOA) than TR. The SAMA, SPOA and SBOA in TR were only 50.3%, 18.6% and 46.4% of those values in MR, respectively. Remarkably, the specific hydrogenotrophic methanogenic activity of 15.5±2.1, 15.7±4.6 mmol CH4·L−1 original slurry·d−1 in MR and TR was comparative with insignificant difference, which indicates that the microbial activity in TR had been inhibited widely apart from the hydrogenotrophic methanogenesis. Additionally, many particles with the diameters of 1–2 mm were observed to form in MR and identified as complexes of calcium and long chain fatty acids (LCFAs). The formation of calcium crystallization might alleviate the inhibition of LCFAs during AD of FW, which further supports the better performance in MR than TR.


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