Investigation on Microstructure and Phase Transformation of La Added Ti49.3Ni50.7 Shape Memory Alloy

2012 ◽  
Vol 557-559 ◽  
pp. 1041-1044 ◽  
Author(s):  
Jia Wen Xu ◽  
Ai Lian Liu ◽  
Bing Yu Qian ◽  
Wei Cai

The effect of La addition on the microstructure and phase transformation behavior of Ti 49.3Ni50.7 alloy is investigated by optical microscope (OP), scanning electron microscope (SEM), X-ray diffraction analysis (XRD) and differential scanning calorimeter (DSC). The results show that the microstructure of Ti-Ni alloy is changed obviously with La addition, and the microstructure of Ti-Ni alloy containing La at room temperature is made up of the matrix and LaNi phase. La addition firstly increases the martensitic transformation temperatures evidently and the increase of Ms is about 62°C with 1at.% La. Secondly Adding La changes the type of phase transformation behavior of Ti-Ni alloys, and R phase transformation with Rs temperature about room temperature occurs in La added Ti-Ni alloy.

ChemSusChem ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 2240-2250 ◽  
Author(s):  
Lea de Biasi ◽  
Alexander Schiele ◽  
Maria Roca‐Ayats ◽  
Grecia Garcia ◽  
Torsten Brezesinski ◽  
...  

2003 ◽  
Vol 112 ◽  
pp. 893-896 ◽  
Author(s):  
T.-H. Nam ◽  
J.-H. Kim ◽  
M.-S. Choi ◽  
H.-W. Lee ◽  
Y.-W. Kim

2020 ◽  
Vol 17 (3(Suppl.)) ◽  
pp. 0961
Author(s):  
Ali Abadi Aljubouri ◽  
Safa hasan Mohammed ◽  
Mudhafar ali Mohammed

Sn effect on the phase transformation behavior, microstructure, and micro hardness of equiatomic Ni-Ti shape memory alloy was studied. NiTi and NiTiSn alloys were produced using vacuum induction melting process with alloys composition (50% at. Ni, 50% at.Ti) and (Ni 48% at., Ti 50% at., Sn 2% at.). The characteristics of both alloys were investigated by utilizing Differential Scanning Calorimetry, X- ray Diffraction Analysis, Scanning Electron Microscope, optical microscope and vicker's micro hardness test. The results showed that adding Sn element leads to decrease the phase transformation temperatures evidently. Both alloy samples contain NiTi matrix phase and Ti2Ni secondary phase, but the Ti2Ni phase content decreases with Sn addition and this is one of the reasons that leads to decrease the micro hardness of alloy with adding Sn element in a noticeable manner. The micro hardness decreases from 238.74 for NiTi equiatomic alloy to 202 for NiTiSn alloy after heat treatment.


2011 ◽  
Vol 121-126 ◽  
pp. 65-69
Author(s):  
Li Peng Zhang ◽  
Xian Jin Yu ◽  
Zhi Wei Ge ◽  
Yun Hui Dong ◽  
Dang Gang Li

Al-Ni Alloys were obtained from NiCl2-AlCl3-1-ethyl-3-methylimidazolium bromide ([EMIM]Br) ionic liquid at room temperature. The analysis of Al-Ni alloys that co-deposited at different potentials for 2h were performed using Scanning Electron Microscopy (SEM) and X-ray diffraction analysis (XRD). It appears that Ni has been rapidly solidified in the alloys and homogeneous Al-Ni alloys can be obtained at room temperature. As increasing the overpotential, the amount of Ni in the alloys was decreased whereas the amount of Al was increased. The chloride pitting potentials of alloys with the molar ratio of NiCl2/AlCl3/[EMIM]Br 0.03:2:1 was approximately 0.3 V more than pure Al.


2014 ◽  
Vol 783-786 ◽  
pp. 2517-2522
Author(s):  
Raju Arockiakumar ◽  
Madoka Takahashi ◽  
Satoshi Takahashi ◽  
Yoko Yamabe-Mitarai

The phase transformation behavior of Ti-50Pd-5x (x =Zr, Hf, V, Nb, Ta, Cr, Mo, W) (at.%) alloys was studied by X-ray diffraction measurements from room temperature to 800 oC. In all the alloys, B19 martensite was observed at room temperature and it transformed to B2 phase upon heating. In addition, peaks corresponding to formation of (Ti, x)2Pd3 phase was seen for all the alloys. However, the temperature of formation of (Ti, x)2Pd3, interestingly, varied with respect to the elements group from the periodic table. Elements except from group IV (Zr and Hf) have been identified to accelerate the formation of (Ti, x)2Pd3 phase even at low temperatures (~400 oC).


2011 ◽  
Vol 279 ◽  
pp. 66-70
Author(s):  
Peng Wu ◽  
Jing Ji Zhang ◽  
Li Na Sun ◽  
Jing Tao Liu ◽  
Huang Zhou ◽  
...  

Microstructure, phase transformation behavior and electrical properties of BaTi1-x(Li2/3Nb2/3)xO3 with x=0.01-0.40 ceramics have been investigated. Only perovskite phase is detected for all the compositions. The room temperature state of BaTi1-x(Li2/3Nb2/3)xO3 ceramics experiences a transformation from a ferroelectric phase to a paraelectric phase with increasing x. Meanwhile, the permittivity of BaTi1-x(Li2/3Nb2/3)xO3 ceramics reduces, while the Q×f value increases. A degree of frequency dispersion of dielectric peak is obviously increased as x increases from 0.01 to 0.10. It is of great interest that a dielectric abnormity represented by a broad dielectric peak at 200-400K is observed for the composition with x=0.40.


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