Synthesis and Properties of a Novel Cationic Polymer PTMAEPAC

2012 ◽  
Vol 602-604 ◽  
pp. 739-742
Author(s):  
Rui Xia Niu ◽  
Bo Lin Li ◽  
Biao Long
Keyword(s):  
Reaction Time ◽  
Nitrogen Atom ◽  
Ammonium Chloride ◽  
1H Nmr ◽  
Reaction Temperature ◽  
Raw Materials ◽  
Cationic Polymer ◽  
Side Chain ◽  
Nmr Analysis ◽  
Copolymerization Reaction

Poly(bis(2-(trimethylamino)ethyl) 2-hydroxyl propylidene ammonium) chloride (PTMAEPAC) is one kind of oligomeric cationic polymer with a quarter nitrogen atom on its main and side chain. It was synthesized from Bis(2-trimethyl ammonium)ethyl ammonium chloride (TMAEAC) and epichlorohydrin (ECH) by copolymerization reaction, effects of reaction temperature, mole ratio of raw materials, reaction time, amount of solvent on the cationicity of product were studied. The structure of PTMAEPAC was confirmed by IR and 1H-NMR, and its anti-clay-expanding ability was studied. The results show that the cationicity of PTMAEPAC can reach 83.9% with the reaction time of 6h at 65°C when TMAEAC-to-ECH mole ratio is 1.2:1 and the amount of solvent is 30% in total. According to the IR and NMR analysis the product has the same structure with the aim compound. When the content of the product is 3 wt% it has a good anti-clay-expanding ratio of 96.1%.

Synthesis of Quaternary Ammonium Cationic Polymer PEA

2013 ◽  
Vol 690-693 ◽  
pp. 1599-1603
Author(s):  
Rong Ming Zhang ◽  
Hong Man Shan ◽  
Min Zhao ◽  
Dong Hui Ma ◽  
Wei Li
Keyword(s):  
Reaction Time ◽  
Water Absorption ◽  
Reaction Temperature ◽  
Quaternary Ammonium ◽  
Ring Opening ◽  
Cationic Polymer ◽  
Ring Opening Reaction ◽  
Epoxy Value ◽  
Polymerization Conditions

The cationic polymer PEA was synthesized by ring-opening reaction and quaterisation with epichlorohydrin and β-hydroxy alkyl propyl ether amine as the main materials.Study on the efffect of rate of charge, reaction time and reaction temperature on cationic degree and epoxy value. Capability of adsorption on the sand and anti-swelling resistance were studied. The results showed that the best polymerization conditions as follows,reaction temperature was 60 °C, reaction time was 6 h, the rate of charge of epichlorohydrin toβ-hydroxy alkyl propyletheramine was 2.5:1. Under these conditions , the cationic degree of PEA was 3.962 mmol/g, epoxy value was 0.12. Then it was performed the water absorption.

Synthesis of Butanone 1,2 - Propanediol Ketal by Sulfamic Acid as Catalyzed

2013 ◽  
Vol 781-784 ◽  
pp. 276-279
Author(s):  
Yu Hang Zhao ◽  
Li Cui ◽  
Da Zhi Wang ◽  
Tong Kuan Xu ◽  
Yong Peng Li
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Raw Materials ◽  
Sulfamic Acid ◽  
Product Yield ◽  
Experimental Results ◽  
Reaction Conditions ◽  
Optimal Reaction

Butanone 1,2-propanediol ketal was synthesized by butanone and 1,2-propanediol as raw materials and sulfamic acid as catalyst. The effects of the mole ratio of raw materials agent, the dosage of the water-carrying agent and catalyst, reaction time on the product yield were discussed separately. Experimental results showed that sulfamic acid was a suitable catalyst for synthesizing of butanone 1,2-propanediol ketal. And the optimal reaction conditions are as follows: the mole ratio of butanone to 1,2-propanediol is 1:1.5, the amount of the catalyst is 2.2%, the water-carrying agent is 25ml, the reaction temperature is 358-378K and reaction time 3h. In this condition, the yield of production could reach 93.8%.

Synthesis and Tribological Properties of TiSe2 Nanoparticles

2017 ◽  
Vol 45 ◽  
pp. 34-41 ◽  
Author(s):  
Qin Shi ◽  
Jing Xu ◽  
Li Feng Dang ◽  
Jun Chen ◽  
Guo Gang Tang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Reaction Time ◽  
Reaction Temperature ◽  
Tribological Properties ◽  
Raw Materials ◽  
Homogeneous Distribution ◽  
Formation Mechanisms ◽  
Base Oil ◽  
Transmission Electron

TiSe2 nanobelts/nanoplates have been successfully fabricated through a facile and environment-friendly pressureless sintered process using micro-sized Ti and Se elements as raw materials. The morphology and structure of the as-prepared TiSe2 products were investigated by X-ray diffractometer, scanning electron microscopy, transmission electron microscopy and high resolution transmission electron microscopy. The experimental results indicated that the morphology of TiSe2 products were strongly dependent on the reaction temperature and reaction time. As the reaction temperature was set at 600°C and 800°C, long belts-like and plates-like structures of as-prepared TiSe2 products could be observed, respectively. However, a mixture of nanobelts and nanoplates could be obtained at a reaction temperature of 700°C. It was also found that the reaction time played a crucial role in obtaining the homogeneous distribution nanoparticles, therefore, reasonable reaction process and formation mechanisms of as-prepared TiSe2 nanoparticles were proposed. Moreover, the tribological properties of the TiSe2 nanobelts/nanoplates were investigated. The test results showed that the addition of TiSe2 nanoparticles could improve the tribological properties of base oil. Furthermore, the friction coefficient of base oil containing TiSe2 nanoplates was lower and more stable than those of TiSe2 nanobelts and pure base oil.

Study on the Synthesis Optimization of Paper Wet-Strengthening Resin PAE

2011 ◽  
Vol 236-238 ◽  
pp. 1135-1138
Author(s):  
Shi Min Chen ◽  
Hong Xiang Zhu ◽  
Nan Nan Xia ◽  
Shuang Fei Wang ◽  
Hai Nong Song
Keyword(s):  
Reaction Time ◽  
Reaction Temperature ◽  
Adipic Acid ◽  
Raw Materials ◽  
Solid Content ◽  
Injection Time ◽  
Optimum Conditions ◽  
Wet Strength ◽  
Soaking Time ◽  
Diethylene Triamine

The Polyamide Polyamine Epichlorhydrin Resin was obtained by using adipic acid, diethylene triamine and epoxy chloropropane as raw materials. The factors that would affect the properties of PAE resin were considered, including the reaction time, the dosage of the epoxy chloropropane, the injection time of epoxy chloropropane and the soaking time, and the wet strengthening property of PAE resin were studied through experiments. The results are as following: the ratio of epoxy chloropropane to diethylenetriamine is 1:1, the injection time of epoxy chloropropane is 8.5 min, the reaction temperature is 75 °C and the soaking time is 35min~40min. Under the optimum conditions, the PAE has a higher wet-strength and solid content, and its viscosity up to 25~35cp.

Preparation and Characterization of Magnesium Borate Whisker

2013 ◽  
Vol 662 ◽  
pp. 481-484
Author(s):  
Zhi Liang Jin ◽  
Xu Jing ◽  
Yuan Hong ◽  
Xue Ying Nai ◽  
Li Wu
Keyword(s):  
Reaction Time ◽  
Molten Salt ◽  
Reaction Temperature ◽  
High Performance ◽  
Raw Materials ◽  
Price Ratio ◽  
Magnesium Borate ◽  
Synthesis Conditions ◽  
Ft Ir

Being a new whisker products with high performance to price ratio, magnesium borate whiskers with a length of 10 - 50μm and a diameter of 0.5 - 2μm were prepared by molten salt and characterized by XRD, FT - IR, SEM and chemical titration. The experiments show that the synthesis conditions are as follows: raw materials ratio: Mg:B:flux =1:11.05:1-3.5(mol); reaction temperature: 800 - 950°C;reaction time:6 - 10hours; flux: NaCl、KCl or NaOH.

scholarly journals Preparation of Biodiesel through Transesterification of Animal Oil and AlcoholUnder the Catalysis of SO42-/ TiO2

2009 ◽  
Vol 6 (1) ◽  
pp. 189-195 ◽  
Author(s):  
Xiu-Yan Pang ◽  
Ting-Ting You
Keyword(s):  
Reaction Time ◽  
Optimum Condition ◽  
Reaction Temperature ◽  
Raw Materials ◽  
Orthogonal Experiment ◽  
Hydrolysis Product ◽  
Mass Ratio ◽  
Optimum Conditions ◽  
Activation Temperature ◽  
Effective Catalyst

Biodiesel was obtained through transesterification of animal oil and ethanol under the catalysis of SO42-/ TiO2We have inspected the activation of SO42-/ TiO2prepared under different dipping vitriol concentration，baking activation temperature. The optimum conditions to prepare SO42-/ TiO2are; dipping vitriol concentration of TiCl4 hydrolysis product is 1.5 mol / L, baking activation temperature for this catalyst takes 500°C. It can guarantee the catalyst has a smaller size and a higher load of vitriol. With animal oil as raw materials, ethanol as transesterifying agent and SO42-/ TiO2as catalyst, the influence of reaction time, mass ratio of ethanol to oil and the dosage of catalyst were investigated. Optimum condition to obtain biodiesel was studied through orthogonal experiment, and it is listed as follow: mass ratio of ethanol to oil is 1.5:1.0, dosage of catalyst is 30 g SO42-/ TiO2versusper 100 g animal oil, and reaction time is 8.0 h when reaction temperature is controlled as 80°C. The yield of biodiesel is 0.796 g/g under the above condition. SO42-/ TiO2can be used as an effective catalyst during transesterification of animal oil and ethanol, and it can be reused

Synthesis of LC Intermediate Containing Trimethyl Silyl Acetylene Group

2013 ◽  
Vol 781-784 ◽  
pp. 280-282
Author(s):  
Zong Cheng Miao ◽  
Yi Wei Wang ◽  
Yuan Yuan Li ◽  
Lei Zhang ◽  
Xin Zhang ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Reaction Time ◽  
Reaction Temperature ◽  
Raw Materials ◽  
Coupling Reaction ◽  
Sonogashira Coupling ◽  
Reaction Conditions ◽  
Sonogashira Coupling Reaction ◽  
Acetylene Group ◽  
Optimum Reaction

In order to obtain the important liquid crystal intermediate with trifluoromethyl substitutent, Sonogashira coupling reaction was used to synthesize the compound. In this paper, the intermediate was synthesized by 4'-Iodo-4-pentyl-biphenyl and trimethyl silyl acetylene (TMSA) as raw materials. During the synthesis, the optimum reaction conditions were obtained, that the mol ratio of 4'-Iodo-4-pentyl-biphenyl and trimethyl silyl acetylene is 1:2, the reaction temperature is 30 oC, and the reaction time is 10 h.

Synthesis of Benzaldehyde 1, 2-Propanediol Acetal by Using Ionic Liquid [Hmim]HSO4 as Catalyst

2012 ◽  
Vol 550-553 ◽  
pp. 400-403 ◽  
Author(s):  
Xue Nan Sun ◽  
Li Cui ◽  
Tong Kuan Xu ◽  
Da Zhi Wang
Keyword(s):  
Ionic Liquid ◽  
Reaction Time ◽  
Reaction Temperature ◽  
Raw Materials ◽  
Product Yield ◽  
Experimental Results ◽  
Molar Ratio ◽  
Reaction Conditions ◽  
Good Catalyst ◽  
Optimal Reaction

Benzaldehyde 1, 2-propanediol acetal was synthesized from benzaldehyde and 1, 2-propanediol in the presence of ionic liquid [HMIM]HSO4. The effect of the amount of catalyst, reaction time, reaction temperature, and the molar ratio of raw materials agent on the product yield was investigated respectively. Experimental results demonstrate that ionic liquid [HMIM]HSO4is a good catalyst for preparation of benzaldehyde 1, 2-propanediol acetal. Results showed the optimal reaction conditions are as follows: the mole ratio of benzaldehyde to 1, 2-propanediol is 1：1.3, the amount of catalyst is 3.0g, the reaction temperature is 343K, and the reaction time is 4h. The achieved yield of acetal is 78. 7%.

scholarly journals Polyvinyl Butyral Synthesis Process Based on Deep Eutectic Solvent as a Catalyst

2021 ◽  
pp. 31-39
Author(s):  
Po Li ◽  
Weilan Xue ◽  
Zuoxiang Zeng ◽  
Li Sun ◽  
Yu Bai
Keyword(s):  
Reaction Time ◽  
Low Temperature ◽  
Reaction Temperature ◽  
Raw Materials ◽  
Condensation Reaction ◽  
Deep Eutectic Solvent ◽  
Polyvinyl Butyral ◽  
Synthesis Process ◽  
Temperature Reaction ◽  
Mass Ratio

Polyvinyl butyral (PVB) was prepared by the condensation reaction of polyvinyl alcohol (PVA) with n-butyraldehyde using a catalyst which is a kind of deep eutectic solvent (DES) made of dodecyltrimethylammonium chloride and p-toluenesulfonic acid. The raw materials and products were characterized by Fourier transform infrared spectroscopy (FT-IR). The effects of the following reaction conditions on the degree of PVB acetal, yield and agglomeration of the products were investigated: the mass ratio of n-butyraldehyde to PVA (mBA/mPVA) of 0.48-0.96, the mass ratio of catalyst to PVA (mcat/mPVA) of 0.16-0.64, the low temperature reaction temperature (5-20℃), and the low temperature reaction time (1-3h). The results showed that at mBA/mPVA =0.8, mcat/mPVA =0.32, low temperature reaction temperature of 15°C and low temperature reaction time of 2 hours, the obtained PVB was a homogeneous powder with the highest acetal degree of 73.85%.

A Novel Process for Synthesis of Cyclohexyl Ferulate

2013 ◽  
Vol 781-784 ◽  
pp. 283-286
Author(s):  
Xiang Wen Kong ◽  
Han Wang ◽  
Zhao Jing Li ◽  
Jing Zhang
Keyword(s):  
Reaction Time ◽  
Ferulic Acid ◽  
1H Nmr ◽  
Raw Materials ◽  
Molar Ratio ◽  
Synthesis Process ◽  
Mass Ratio ◽  
Reaction Conditions ◽  
Sodium Bisulfate ◽  
Optimal Reaction

Cyclohexyl ferulate was prepared by direct sterification of ferulic acid and cyclohexanol as raw materials with sodium bisulfate supported by silica as a catalyst. The influences of some factors on the synthesis process were studied. The optimal reaction conditions based upon 0. 2 mol of ferulic acid were chosen that the molar ratio of cyclohexanol and ferulic acid was 10 : 1, the mass ratio of catalyst to reactants was 5%, refluing reaction time was 3.5 hours, et a1. The yield of the product reached 80%. The structure of the product was characterized by IR, 1H NMR and MS spectrum. The catalyst could be recycled and used for many times, which is friendly to the environment.

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