Elemental Analysis and Wettability Properties of Polyene with Epoxidised Oil Based Coating

2013 ◽  
Vol 701 ◽  
pp. 389-393
Author(s):  
Mohd Nurazzi Norizan ◽  
Rahmah Mohamed

Presence of chlorine in by product of degradation process from polyvinyl chloride was analysed through structural feature changes and elemental analysis. Coating samples with polyene was also tested for its wettability via contact angle. Analyzing the elimination of chlorine content from polyvinylchloride through chemical dechlorination with tetrahydrofuran (THF) has been studied via FTIR spectra, energy-dispersive x-ray spectroscopy (EDS) and static contact angle measurement. Qualitative value of decreasing chlorine content of polyene at 2 hours reaction time was found to be about 96% from supplied PVC. All treated samples at different reaction time of polyene synthesize showed good wettability properties since the contact angle value were less than 90o.

2011 ◽  
Vol 396-398 ◽  
pp. 1619-1623
Author(s):  
Zhao Ping Song ◽  
Jun Rong Li ◽  
Hui Ning Xiao

Hydrophobic modification of cellulose fibres was conducted by plasma-induced polymer grafting in an attempt to increase the hydrophobicity of paper. Two hydrophobic monomers, i.e., butyl acrylate (BA) and 2-ethylhexyl acrylate (2-EHA) were grafted on cellulose fibres, induced by atmospheric cold plasma. Various influencing factors associated with the plasma-induced grafting were investigated, including the contact time and reaction temperature with monomers, and the dosage of monomers. Contact-angle measurement, infrared spectrum (IR), X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM) were used to ascertain the occurrence of the grafting. The results showed that the hydrophobic property of the modified paper sheet was improved significantly after the plasma-induced grafting. The water contact angle on the surface of the paper reached up to higher than125°.


2011 ◽  
Vol 221 ◽  
pp. 90-94 ◽  
Author(s):  
Gang Li ◽  
Hai Peng Yu ◽  
Yi Xing Liu

To convert the hydrophilic cotton fiber into hydrophobic, grafting methyl methacrylate (MMA) on cotton fiber surface using ARGET (activators regenerated by electron transfer) ATRP (atom transfer radical polymerization) was studied in this paper. Four parallel experiments with different reaction time (2h/4h/6h/8h) were designed. The modified cotton fibers and the untreated control were examined using FTIR, SEM and contact angle analysis. The results show that as the reaction time prolonged, the peak of carbonyl stretching band of 2-bromoester at 1730cm-1 was stronger and the surface of cotton fiber was rougher, which demonstrates MMA has been grafted on the surface of cotton fiber successively and its amount increases with the reaction time. As the results of contact angle measurement, it shows that the hydrophilicity of cotton fiber can easily be modified by grafting of MMA, but the increasing amount of grafting chain had no obvious effects on further improving its hydrophobicity.


Langmuir ◽  
2017 ◽  
Vol 33 (14) ◽  
pp. 3358-3366 ◽  
Author(s):  
Pengfei Lv ◽  
Yu Liu ◽  
Zhe Wang ◽  
Shuyang Liu ◽  
Lanlan Jiang ◽  
...  

1995 ◽  
Vol 396 ◽  
Author(s):  
Sung-Chul Park ◽  
Hyung-Jin Jung ◽  
Seok-Keun Koh

AbstractA surface of PC, PMMA, and PET samples irradiated with Ar+ ion of 1 keV energy with and without oxygen environment was investigated by contact angle measurement and x-ray photoelectron spectroscopy (XPS) spectra. Contact angle of water droplets on the irradiated surface of the polymers decreased and remained almost constant with increasing Ar+ irradiation without oxygen. However, when the polymers were irradiated under oxygen environment, the contact angle markedly decreased with increasing ion dose upto 1016 ions/cm2. XPS results show that, after Ar+ irradiation under oxygen, hydrophilic groups were developed on PC, PMMA, and PET. The peak ratio (O/C) of PET irradiated without oxygen decreased with increasing ion dose, whereas that of PET irradiated under oxygen increased with ion dose upto 1016 ions/cm2


2018 ◽  
Vol 5 (9) ◽  
pp. 180893 ◽  
Author(s):  
Grace Y. Stokes ◽  
Evangelea N. DiCicco ◽  
Trevor J. Moore ◽  
Vivian C. Cheng ◽  
Kira Y. Wheeler ◽  
...  

Insects from the order Embioptera (webspinners) spin silk fibres which are less than 200 nm in diameter. In this work, we characterized and compared the diameters of single silk fibres from nine species— Antipaluria urichi , Pararhagadochir trinitatis , Saussurembia calypso , Diradius vandykei , Aposthonia ceylonica , Haploembia solieri , H. tarsalis , Oligotoma nigra and O. saundersii . Silk from seven of these species have not been previously quantified. Our studies cover five of the 10 named taxonomic families and represent about one third of the known taxonomic family-level diversity in the order Embioptera. Naturally spun silk varied in diameter from 43.6 ± 1.7 nm for D. vandykei to 122.4 ± 3.2 nm for An. urichi. Mean fibre diameter did not correlate with adult female body length. Fibre diameter is more similar in closely related species than in more distantly related species. Field observations indicated that silk appears shiny and smooth when exposed to rainwater. We therefore measured contact angles to learn more about interactions between silk and water. Higher contact angles were measured for silks with wider fibre diameter and higher quantity of hydrophobic amino acids. High static contact angles (ranging up to 122° ± 3° for An. urichi ) indicated that silken sheets spun by four arboreal, webspinner species were hydrophobic. A second contact angle measurement made on a previously wetted patch of silk resulted in a lower contact angle (average difference was greater than 27°) for all four species. Our studies suggest that silk fibres which had been previously exposed to water exhibited irreversible changes in hydrophobicity and water adhesion properties. Our results are in alignment with the ‘super-pinning’ site hypothesis by Yarger and co-workers to describe the hydrophobic, yet water adhesive, properties exhibited by webspinner silk fibres. The physical and chemical insights gained here may inform the synthesis and development of smaller diameter silk fibres with unique water adhesion properties.


2016 ◽  
Vol 5 (1) ◽  
Author(s):  
Jose L. Ocaña ◽  
R. Jagdheesh ◽  
J.J. García-Ballesteros

AbstractThe current availability of new advanced fiber and DPSS lasers with characteristic pulse lengths ranging from ns to fs has provided a unique frame in which the development of laser-generated microstructures has been made possible for very diverse kinds of materials and applications. At the same time, the development of the appropriate laser-processing workstations granting the appropriate precision and repeatability of the respective laser interaction processes in line with the characteristic dimension features required in the microstructured samples has definitively consolidated laser surface microstructuring as a reference domain, nowadays, unavoidable for the design and manufacturing of current use microsystem: MEMSs, fluidic devices, advanced sensors, biomedical devices and instruments, etc., are all among the most well-known developments of the micromanufacturing technology. Completing the broad spectrum of applications developed mostly involving the generation of geometrical features on a subtrate with specific functional purposes, a relatively new, emerging class of laser-microstructuring techniques is finding an important niche of application in the generation of physically structured surfaces (particularly of metallic materials) with specific contact, friction, and wear functionalities, for whose generation the concourse of different types of laser sources is being found as an appropriate tool. In this paper, the application of laser sources with emission in the UV and at ns time regime to the surface structuration of metal surfaces (specifically Al) for the modification of their wettability properties is described as an attractive application basis for the generation of self-cleaning properties of extended functional surfaces. Flat aluminum sheets of thickness 100 μm were laser machined with ultraviolet laser pulses of 30 ns with different laser parameters to optimize the process parameters. The samples produced at the optimum conditions with respect to contact angle measurement were subjected to microstructure and chemical analysis. The wetting properties were evaluated by static contact angle measurements on the laser-patterned surface. The laser-patterned microstructures exhibited superhydrophobicity with a maximum contact angle of 180° for the droplet volumes in the range of 8–12 μl.


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