Chiral Separation of R,S 3-(4-Fluorophenyl) -2,2-Dimethylcyclopane Carboxamide with Monolithic Molecularly Imprinted Polymers

2013 ◽  
Vol 706-708 ◽  
pp. 40-43
Author(s):  
Chun Mei Xu ◽  
Zhi Wei Li ◽  
Lei Liu

A monolithic column of molecularly imprinted polymer was prepared by an in situ polymerization method with a new compound R, S 3-(4-Fluorophenyl) -2, 2-Dimethylcyclopane Carboxamide which has fluorin organic compound as the template. The molecular recognition capabilities of the prepared monolithic MIP were evaluated by separating the enantiomers. The characteristics of the column and the influences of mobile phases were studied. The results showed that the monolithic column has chiral recognition capability for the template and the enantiomers were baseline separated even in aqueous solution.

The Analyst ◽  
2015 ◽  
Vol 140 (12) ◽  
pp. 4057-4067 ◽  
Author(s):  
Wenying Fan ◽  
Mingqi Gao ◽  
Man He ◽  
Beibei Chen ◽  
Bin Hu

A molecularly imprinted polymer coated stir bar was prepared using a self-designed polytetrafluoroethylene mold andin situpolymerization, with cyromazine as dummy template for target melamine.


2015 ◽  
Vol 3 (45) ◽  
pp. 23042-23052 ◽  
Author(s):  
Sheng-Dong Pan ◽  
Xiao-Hong Chen ◽  
Xiao-Ping Li ◽  
Mei-Qiang Cai ◽  
Hao-Yu Shen ◽  
...  

A novel graphene oxide-based ternary magnetic molecularly imprinted polymer hybrid was synthesized for highly efficient enrichment and sensitive detection of microcystins.


2014 ◽  
Vol 1015 ◽  
pp. 381-384
Author(s):  
Li Liu ◽  
Li Hai Cai ◽  
Dan Liu ◽  
Jun Xu ◽  
Bao Hua Guo

The poly (butylene succinate) (PBS) and 3 wt% attapulgite (ATP) reinforced PBS/ATP nanocomposites with 1,6-hexanediol were fabricated using an in situ polymerization method. The crystallization behaviors indicated that ATP had effectively acted as nucleating agent, resulting in the enhancement on the crystallization temperature. The SEM results showed a superior interfacial linkage between ATP and PBS. Also, ATP could disperse as a single fiber and embed in the polymer matrix, which resulted in the improved mechanical properties.


The Analyst ◽  
2022 ◽  
Author(s):  
Ying Wang ◽  
Xiaomin Yang ◽  
Lin Pang ◽  
Pengfei Geng ◽  
Fang Mi ◽  
...  

Specific recognition and highly sensitive detection of biomarkers play an essential role in identifying, early diagnosis and prevention of many diseases. Magnetic molecularly imprinted polymers (MMIP) have been widely used...


2022 ◽  
Author(s):  
Xue Chen ◽  
Jinyue Chai ◽  
Baodong Sun ◽  
Xue Yang ◽  
Feng Zhang ◽  
...  

In this study, the carbon-based Cu2+-immobilized metal-organic framework modified molecularly imprinted polymer (C@GI@Cu-MOFs@MIPs) adsorbent was prepared using bovine hemoglobin (BHb) as a template molecule with carbon spheres as carriers for...


2019 ◽  
Vol 361 ◽  
pp. 897-907 ◽  
Author(s):  
Jingchun Lv ◽  
Peiwen Zhou ◽  
Linping Zhang ◽  
Yi Zhong ◽  
Xiaofeng Sui ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 54702-54708 ◽  
Author(s):  
Mostafa Khajeh ◽  
Marzieh Sharifirad ◽  
Mousa Bohlooli ◽  
Mansour Ghaffari-Moghaddam

In this study, an efficient and sensitive magnetic molecularly imprinted polymer–silver nanoparticle (MMIPS) system was successfully synthesized.


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