Biosorption of C. I. Reactive Red 2 from Aqueous Solution by Saccharomyces Cerevisiae

2013 ◽  
Vol 739 ◽  
pp. 327-331
Author(s):  
Li Fang Zhang ◽  
Yin Ling Wang
Keyword(s):  
Saccharomyces Cerevisiae ◽  
Aqueous Solution ◽  
Maximum Adsorption Capacity ◽  
Adsorption Model ◽  
Langmuir Adsorption ◽  
Optimum Ph ◽  
Initial Ph ◽  
Equilibrium Data ◽  
Adsorption Equilibrium Data ◽  
Reactive Red 2

The biosorption of C. I. Reactive Red 2 from aqueous solution onto biomass of Saccharomyces cerevisiae was examined. The biosorption studies were carried out under various parameters such as initial pH, contact time and initial dye concentration. The experimental results showed that optimum pH for dye biosorption was found to be 2.0 for the yeast biomass. The bosorption capacity was increased with the increasing initial dye concentration in studied dye concentration range. It was found that the adsorption equilibrium data followed the Langmuir adsorption model. The maximum adsorption capacity obtained from the Langmuir equation at temperature of 30°C was 500mg/g (R2=0.991) for the dye. The results indicate that the biomass of Saccharomyces cerevisiae can be used as an effective biosorbent to removal C. I. Reactive Red 2 from aqueous solution.

Removal of C. I. Reactive Red 2 from Aqueous Solution by Ni-Al Layered Double Hydroxide

2011 ◽  
Vol 148-149 ◽  
pp. 1276-1279 ◽  
Author(s):  
Li Fang Zhang
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Layered Double Hydroxide ◽  
Molar Ratio ◽  
Maximum Adsorption Capacity ◽  
Adsorption Model ◽  
Equilibrium Data ◽  
Adsorption Equilibrium Data ◽  
Double Hydroxide ◽  
Reactive Red 2

In this study, the adsorption of C. I. Reactive Red 2 from aqueous solution on Ni-Al layered double hydroxide (LDH) was investigated in a batch system. The effect of Ni-Al molar ratio, pH, temperature and initial dye concentration on adsorption of the dye was carried out. The results showed that Ni-Al layered double hydroxide had higher capacity of removal of the dye. Ni-Al LDH with Ni-Al molar ratio of 3 exhibited the maximum dye removal at pH 4.0. Adsorption capacity of dye increased with increasing temperature or initial dye concentration. It was found that the adsorption equilibrium data followed the Langmuir adsorption model. The maximum adsorption capacity obtained from the Langmuir equation at temperature of 30°C was 333.3mg/g (R2=0.991) for the dye.

scholarly journals Removal of phenol from aqueous solution by adsorption onto seashells: equilibrium, kinetic and thermodynamic studies

2013 ◽  
Vol 3 (2) ◽  
pp. 119-127 ◽  
Author(s):  
Papita Das Saha ◽  
Jaya Srivastava ◽  
Shamik Chowdhury
Keyword(s):  
Aqueous Solution ◽  
Adsorption Process ◽  
Phenol Concentration ◽  
Phenol Removal ◽  
Solution Ph ◽  
Initial Ph ◽  
Equilibrium Data ◽  
Initial Phenol Concentration ◽  
Adsorption Equilibrium Data ◽  
Adsorbent Dose

The efficacy of seashells as a new adsorbent for removal of phenol from aqueous solutions was studied by performing batch equilibrium tests under different operating parameters such as solution pH, adsorbent dose, initial phenol concentration, and temperature. The phenol removal efficiency remained unaffected when the initial pH of the phenol solution was in the range of 3–8. The amount of phenol adsorbed increased with increasing initial phenol concentration while it decreased with increasing temperature. The adsorption equilibrium data showed excellent fit to the Langmuir isotherm model with maximum monolayer adsorption capacity of 175.27 mg g−1 at pH 4.0, initial phenol concentration = 50 mg L−1, adsorbent dose = 2 g and temperature = 293 K. Analysis of kinetic data showed that the adsorption process followed pseudo-second-order kinetics. Activation energy of the adsorption process, calculated using the Arrhenius equation, was found to be 51.38 kJ mol−1, suggesting that adsorption of phenol onto seashells involved chemical ion-exchange. The numerical value of the thermodynamic parameters (ΔG0, ΔH0 and ΔS0) indicated that adsorption of phenol onto seashells was feasible, spontaneous and endothermic under the examined conditions. The study shows that seashells can be used as an economic adsorbent for removal of phenol from aqueous solution.

Equilibrium and Thermodynamic Studies on Biosorption of Dye from Aqueous Solution by PeniciIlium sp.

2011 ◽  
Vol 80-81 ◽  
pp. 678-682
Author(s):  
Li Fang Zhang ◽  
Ying Ying Chen ◽  
Shu Juan Dai
Keyword(s):  
Aqueous Solution ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Freundlich Model ◽  
Thermodynamic Studies ◽  
Biosorption Process ◽  
Optimum Ph ◽  
Initial Ph ◽  
Equilibrium Data ◽  
Increasing Temperature

In this study, biosorption of C. I. Acid Red 18 from aqueous solution was investigated by using acid treated biomass of Penicilium sp. in a batch system. The effects of initial pH, contact time, initial dye concentration and temperature on dye biosorption were investigated. Optimum pH for efficient dye biosorption was found to be 3.0 for acid treated biomass. The bosorption capacity was increased with the increasing temperature in studied temperature range. The Langmuir and Freundlich isotherm models were applied to experimental equilibrium data and the Langmuir model better described the equilibrium dye uptake than the Freundlich model. Thermodynamic studies revealed that the biosorption process was successful, spontaneous and endothermic in nature.

Biogenic Jarosite: A Friendly Adsorbent for the Removal of Chromate from Aqueous Solution

2015 ◽  
Vol 737 ◽  
pp. 533-536 ◽  
Author(s):  
Dong Xue Xiao ◽  
Chang Ling Fang ◽  
Jun Zhou ◽  
Xiao Yi Lou ◽  
Jiu Hua Xiao ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Adsorption Isotherm ◽  
Mine Drainage ◽  
Langmuir Adsorption Isotherm ◽  
Isotherm Models ◽  
Maximum Adsorption Capacity ◽  
Langmuir Adsorption ◽  
Adsorption Isotherm Models ◽  
Optimum Ph ◽  
Sulfate Leaching

Ferric hydrosulfate minerals are commonly byproducts of biotic oxidation of Fe (II) in acid mine drainage and biohydrometallurgy like biogenic jarosite. In this study, adsorption of Cr (VI) on jarosite was a rapid process and the optimum pH for Cr (VI) adsorption was found at 7.0. The variation of Cr (VI) adsorbed on jarosite fitted the Langmuir adsorption isotherm models and the maximum adsorption capacity was 3.23 mg/g. It was evident that anion exchange mechanism was responsible for Cr (VI) adsorption on jarosite based on the sulfate leaching data and optimum pH experiments.

scholarly journals PERBANDINGAN DAYA SERAP SERBUK GERGAJI KAYU DAMAR LAUT (SHOREA SP) DAN MERBAU (INTSIA SP) TERHADAP LOGAM Pb(II)

2018 ◽  
Vol 1 (1) ◽  
pp. 56-63
Author(s):  
Ibnu Khaldun ◽  
Aristia Aristia ◽  
Faucut Sarah
Keyword(s):  
Contact Time ◽  
Langmuir Model ◽  
Operating Conditions ◽  
Maximum Adsorption Capacity ◽  
Adsorption Model ◽  
Solution Ph ◽  
Langmuir Adsorption ◽  
Freundlich Isotherms ◽  
Langmuir Adsorption Model ◽  
Equilibrium Data

Abstrak. Penelitian ini bertujuan untuk  menginvestigasi kemampuan daya serap serbuk gergaji kayu damar laut (Shorea sp) dan merbau (Intsia sp) terhadap logam Pb(II) dari larutan, dan mempelajari pengaruh kondisi percobaan seperti pH larutan, waktu kontak, jumlah adsorben dan konsentrasi adsorbat. Efisiensi adsorpsi maksimum  berturut-turut sebanyak 95,72% pada pH 4 dan 98,78% pada pH 5 oleh damar laut (Shorea sp) dan   kayu merbau (Intsia sp). Adsorpsi timbal oleh kedua adsorben meningkat dengan bertambahnya waktu dan pH (dari 1 hingga 5) dan menurun dengan menurunnya kekuatan ion. Data kesetimbangan dikorelasikan dengan isotherm Langmuir dan Freundlich. Kapasitas adsorpsi maksimum berdasarkan isotherm Langmuir untuk serbuk kayu damar laut dan kayu merbau berturut-turut sebesar 45,45 mg/g dan 14,706 mg/g dan berdasarkan isotherm Freundlich sebesar untuk serbuk kayu damar laut dan kayu merbau berturut-turut sebesar 1,2475 mg/g dan 1,616 mg/g. Dari hasil tersebut disimpulkan bahwa model Langmuir adalah yang terbaik.Kata kunci: Adsorpsi, damar laut, merbau, isotherm, serbuk gergaji. Abstract. The aim of this work is to investigate the performance of damar laut (Shorea sp) and  merbau (Intsia sp) sawdust  for the adsorption of  lead(II) from aqueous solutions, and to study the influence of the operating conditions such as solution pH, contact time, amount of adsorbent, and concentration of adsorbate.  The maximum adsorpsi efficiencies were 95.72% for damar laut (Shorea sp) at pH 4 and  98.78% for  kayu merbau (Intsia sp) at pH 5.  The adsorption  of lead by both sorbents increased with an increase in contact time and pH (from 1 to 5) and decreased with an increase in ionic strength. The equilibrium data has been correlated with both Langmuir and Freundlich isotherms.  The maximum adsorption capacity of the sawdust evaluated by Langmuir adsorption model  by damar laut (Shorea sp) and  merbau (Intsia sp) sawdust was 45.45 mg/g and 14.706 mg/g respectively and by Freundlich adsorption model by damar laut (Shorea sp) and  merbau (Intsia sp) sawdust was 1.2473 mg/g and 1.616 mg/g respectively. The results indicate that the Langmuir model fits the data better.Keywords: adsorption, Shorea sp, Intsia sp, Isotherms, Sawdust. 

Biosorption of Acid Red R from Aqueous Solution by Acid-Treated Penicillium sp.

2012 ◽  
Vol 433-440 ◽  
pp. 35-40
Author(s):  
Li Fang Zhang ◽  
Ying Ying Chen ◽  
Shu Juan Dai
Keyword(s):  
Aqueous Solution ◽  
Ph Value ◽  
Dye Adsorption ◽  
Adsorption Model ◽  
Batch Mode ◽  
Operating Variables ◽  
Penicillium Sp ◽  
Initial Ph ◽  
Equilibrium Data ◽  
Biosorption Equilibrium

The biosorption of Acid Red R, from aqueous solutions by acid treated Penicilium sp. was studied in a batch mode. Operating variables like contact time, pH and initial dye concentration was investigated. The acid treated biomass exhibited maximum dye uptake at initial pH value of 3. The dye adsorption by the biomass was rapid process and the equilibrium was established in 60 min for 50 mg/L of initial dye concentration. Biosorption equilibrium data were fitted very well to the Langmuir as well as to the Freundlich adsorption model. According to the Langmuir model, the monolayer biosorption capacity of Penicillium sp. biomass was found to be 312.5 mg/g for Acid Red R at temperature of 30°C. The results indicate that the acid treatedPeniciliumsp. biomass can be used as an effective biosorbent to remove Acid Red R from aqueous solution.

Adsorption of Dye from Aqueous Solution by Zn-Al Calcined Layered Double Hydroxide

2011 ◽  
Vol 287-290 ◽  
pp. 390-393
Author(s):  
Li Fang Zhang ◽  
Ying Ying Chen
Keyword(s):  
Aqueous Solution ◽  
Adsorption Capacity ◽  
Layered Double Hydroxide ◽  
Molar Ratio ◽  
Maximum Adsorption Capacity ◽  
Adsorption Model ◽  
Equilibrium Data ◽  
Calcined Layered Double Hydroxide ◽  
Ph Range ◽  
Double Hydroxide

The adsorption of C. I. Reactive Red 2 from aqueous solution on Zn-Al calcined layered double hydroxide (CLDH) was investigated. Experiments were carried out as a function of Zn-Al molar ratio, contact time, pH, temperature and initial dye concentration. The results showed that Zn-Al calcined layered double hydroxide had higher capacity of removal of the dye. Zn-Al CLDH with Zn-Al molar ratio of 3 and with pH range of 4.0-8.0 was found to be optimal for dye removal. Adsorption capacity of dye decreased with increasing temperature and increased with increasing initial dye concentration. It was found that the adsorption equilibrium data followed the Langmuir adsorption model. The maximum adsorption capacity obtained from the Langmuir equation at temperature of 30°C was 116.28mg/g (R2=0.9992) for the dye.

Removal of Cr(VI) from Aqueous Solution by Acid Treated Fungal Biomass

2011 ◽  
Vol 197-198 ◽  
pp. 131-135
Author(s):  
Li Fang Zhang ◽  
Ying Ying Chen ◽  
Wen Jie Zhang
Keyword(s):  
Aqueous Solution ◽  
Fungal Biomass ◽  
Adsorption Model ◽  
Solution Ph ◽  
Initial Concentration ◽  
Biosorption Capacity ◽  
Penicillium Sp ◽  
Chromium Vi ◽  
Equilibrium Data ◽  
Biosorption Equilibrium

Biosorption of chromium (VI) ions from aqueous solution with fungal biomass Penicillium sp. was investigated in the batch system. The influence of contact time, solution pH, biosorbent concentration, initial concentration of Cr (VI) ions and temperature on biosorption capacity of Cr (VI) ions was studied. The uptake of Cr (VI) was highly pH dependent and the optimum pH for biosorption of Cr (VI) ions was found to be 2.0. Biosorption capacity of Cr (VI) ions decreased with increased biosorbent concentration and increased with increase in initial concentration of Cr (VI) ions. The experiment results also showed that high temperatures increased the biosorption capacity of Cr (VI) by fungal biomass. It was found that the biosorption equilibrium data were fitted very well to the kangmuir as well as to the Freundlich adsorption model. The maximum sorptive capacities obtained from the Langmuir equation at temperature of 20, 30 and 40°C were 25.91, 32.68 and 35.97 mg/g for Cr (VI) ions, respectively. The results of this study indicated that the fungal biomass of Penicillium sp. is a promising biosorbent for removal of chromium (VI) ions from the water.

scholarly journals Removal of Ni (II) from Aqueous Solution by Adsorption onto Activated Carbon Prepared from Lapsi (Choerospondias axillaris) Seed Stone

2014 ◽  
Vol 9 (1) ◽  
pp. 166-174 ◽  
Author(s):  
Rajeshwar M. Shrestha ◽  
Margit Varga ◽  
Imre Varga ◽  
Amar P. Yadav ◽  
Bhadra P. Pokharel ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Activated Carbons ◽  
Low Cost ◽  
Chemical Characterization ◽  
Maximum Adsorption Capacity ◽  
Adsorption Data ◽  
Optimum Ph ◽  
Nickel Adsorption

Activated carbons were prepared from Lapsi seed stone by the treatment with H2SO4 and HNO3 for the removal of Ni (II) ions from aqueous solution. Two activated carbon have been prepared from Lapsi seed stones by treating with conc.H2SO4 and a mixture of H2SO4 and HNO3 in the ratio of 1:1 by weight for removal of Ni(II) ions. Chemical characterization of the resultant activated carbons was studied by Fourier Transform Infrared Spectroscopy and Boehm titration which revealed the presence of oxygen containing surface functional groups like carboxyl, lactones and phenols in the carbons. The optimum pH for nickel adsorption is found to be 5. The adsorption data were better fitted with the Langmuir equations than Freundlich adsorption equation to describe the equilibrium isotherms. The maximum adsorption capacity of Ni (II) on the resultant activated carbons was 28.25.8 mg g-1 with H2SO4 and 69.49 mg g-1 with a mixture of H2SO4 and HNO3. The waste material used in the preparation of the activated carbons is inexpensive and readily available. Hence the carbons prepared from Lapsi seed stones can act as potential low cost adsorbents for the removal of Ni (II) from water. DOI: http://dx.doi.org/10.3126/jie.v9i1.10680Journal of the Institute of Engineering, Vol. 9, No. 1, pp. 166–174

scholarly journals Removal of nitrate from synthetic aqueous solution and groundwater in a continuous pilot system using chemical activated carbon derived from walnut shell

2016 ◽  
Vol 11 (4) ◽  
pp. 784-795 ◽  
Author(s):  
Abolghasem Alighardashi ◽  
Shooza Shahali
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Average Pore Size ◽  
Fixed Bed ◽  
Walnut Shell ◽  
Maximum Adsorption Capacity ◽  
Average Pore ◽  
Langmuir Adsorption ◽  
Bet Specific Surface Area ◽  
Nitrate Adsorption

Excessive nitrate in the water impose a danger to human health and contribute to eutrophication. The present continuous fixed bed pilot study was carried out using granular activated carbon made from walnut shell for removal of nitrate from aqueous solution and natural groundwater. The carbon was characterized using SEM, FTIR and BET. The BET specific surface area and average pore size before nitrate adsorption were 1434.6 m2g−1 and 2.08 nm, respectively, and after were 633.28 m2g−1 and 2.04 nm, respectively. Optimum removal of nitrate was achieved at a contact time of 2 min, pH of 6.5 and a nitrate concentration of 200 mg/l. The hydraulic loading rate was calculated to be 10 m3/h.m2 and the maximum adsorption capacity using the Langmuir adsorption isotherm model (R2 = 0.99) was 10 mg NO3/g. These experiments were also carried out using groundwater and the removal of nitrate decreased from 68% to 60% because of competition with other cations and anions.

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