The Effect of Different Ions on Photodegradation Rhodamine B in TiO2 Suspension Liquid

2013 ◽  
Vol 807-809 ◽  
pp. 2739-2742
Author(s):  
Peng Wei Huo ◽  
Mao Bin Wei ◽  
Xin Lin Liu ◽  
Dan Dan Wang ◽  
Zi Yang Lu ◽  
...  
Keyword(s):  
Waste Water ◽  
Photocatalytic Degradation ◽  
Rhodamine B ◽  
Degradation Rate ◽  
Ph Value ◽  
Degradation Process ◽  
Photocatalytic Process ◽  
Negative Effect ◽  
Anions And Cations

The photocatalytic degradation process of waste water was usually influenced by many factors, such as different ions, addition reagent and pH value. In order to investigate the effect of ions strength in the photocatalytic process, the anions and cations were systematically investigated with P25 TiO2 photocatalyst with Rhodamine B (RB) as waste water in this work. The results showed that the cations of low valence showed minimum negative effect on degradation rate and the most anions showed enhance the degradation rate of RB. The ions strength showed random in the photocatalytic process.

scholarly journals Optimal H2O2 concentration in advanced oxidation over titanium dioxide photocatalyst

2021 ◽  
Vol 22 (1) ◽  
pp. 73-79
Author(s):  
Nazarii Danyliuk ◽  
Ivan Mironyuk ◽  
Tetiana Tatarchuk ◽  
Alexander Shyichuk
Keyword(s):  
Waste Water ◽  
Photocatalytic Degradation ◽  
Rhodamine B ◽  
Industrial Waste ◽  
Degradation Rate ◽  
Oxidative Degradation ◽  
H2o2 Concentration ◽  
Industrial Waste Water ◽  
Rhodamine B Dye ◽  
The Relationship

The oxidative degradation of Rhodamine B dye under ultraviolet irradiation was studied. The degradation rate was measured with using of smartphone camera. Photocatalytic degradation of the Rhodamine B dye over the P25-TiO2 catalyst has been found to accelerate substantially in the presence of hydrogen peroxide. The relationship between the photocatalytic degradation rate and H2O2 concentration has been studied. The optimal concentration of H2O2 has been found to in the range of 10-25 mM. The proposed mixture of P25 photocatalyst and H2O2 oxidizer can be used to remove organic pollutions from industrial waste water.

Visible Light Induced Photocatalytic Degradation of Rhodamine B in the Presence of Cr(VI)

2013 ◽  
Vol 295-298 ◽  
pp. 1434-1437
Author(s):  
Dong Dong Zhang ◽  
Rong Liang Qiu ◽  
Xiong Fei Huang
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Rhodamine B ◽  
Active Sites ◽  
Photocatalytic Process ◽  
Photocatalytic System

Here we report the photocatalytic degradation characteristics of Rhodamine B in the presence of Cr(VI). Some interesting results were observed during the photocatalytic process. Cr(VI) caused a deactivation effect on the catalyst due to the formation of Cr(OH)3precipitate blocking the active sites of catalyst. Moreover, a kind of red oligomer precipitate was found during the RhB degradation when Cr(VI) was presented. This precipitate was rarely reported in photocatalytic system.

Photoelectrocatalytic Properties of Porous TiO2 Films Prepared Using ODA as Template

2012 ◽  
Vol 457-458 ◽  
pp. 521-524 ◽  
Author(s):  
Wen Jie Zhang ◽  
Qian Li ◽  
Hong Bo He
Keyword(s):  
Reaction Time ◽  
Methyl Orange ◽  
Degradation Rate ◽  
Synergetic Effect ◽  
Degradation Process ◽  
Absorption Peak ◽  
Photocatalytic Process ◽  
Applied Potential ◽  
Peak Intensity ◽  
Photoelectrocatalytic Degradation

The functions of applied potential to the photoelectrocatalytic degradation process of methyl orange were investigated. When using 0.05 M NaCl and under different applied potentials, the degradation rate increased obviously with increasing applied potential. When the applied potential was between 0.6 V-1.0 V, the degradation rate was enhanced drastically. The detected current values got larger as the applied potential increased from 0 up to 1.2 V. There was no direct electro-degradation to the dye in the solution. The applied potential and the irradiated light had synergetic effect when they were applied to the solution at the same time. While after irradiation for 0 to 60 min, with the increasing reaction time, methyl orange absorption peak intensity shrank obviously. The azo and benzene groups in methyl orange degraded totally under photocatalytic process.

Study on the Properties of Photocatalytic Degradation of DMP on WO3/TNAs Photoelectrodes

2013 ◽  
Vol 850-851 ◽  
pp. 12-15 ◽  
Author(s):  
Yan Shi ◽  
Yong Ping Liu ◽  
Yan Jun Xin
Keyword(s):  
Photocatalytic Degradation ◽  
Degradation Rate ◽  
Ph Value ◽  
Photocatalytic Property ◽  
Alkaline Condition ◽  
Deposition Method ◽  
Dimethyl Phthalate ◽  
Nanotube Array ◽  
Electro Deposition ◽  
Positive Effect

In this study, WO3/TiO2nanotube array photoelectrodes were fabricated by anodic oxidation and electro-deposition method. The effects of WO3, H2O2, oxygen, and pH value were investigated in the degradation of Dimethyl phthalate (DMP). Results show that the photocatalytic property of the photoelectrode was improved by the modification of WO3. The degradation rate of DMP was increased by 9.3% after 120min irradiation. H2O2could significantly promote the degradation of DMP. The degradation rate of DMP was increased by 27.9% and arrived 97.5% after 120 min irradiation. A certain amount of O2added to the solution had positive effect on the degradation of DMP. While excessive O2would undermine the degradation. The degradation rate of DMP was improved in both acidic condition and alkaline condition. It was separately increased by 38.4% and 40.2% at the pH value of 3.0 and 7.0, compared with that of pH = 7.

scholarly journals Photocatalytic Degradation of Monolinuron and Linuron in an Aqueous Suspension of Titanium Dioxide Under Simulated Solar Irradiation

2007 ◽  
Vol 20 (2) ◽  
pp. 163-172 ◽  
Author(s):  
Razika Zouaghi ◽  
Abdennour Zertal ◽  
Bernard David ◽  
Sylvie Guittonneau
Keyword(s):  
Photocatalytic Degradation ◽  
Degradation Rate ◽  
Ph Value ◽  
Degradation Kinetics ◽  
Aqueous Suspension ◽  
Operating Conditions ◽  
Solar Irradiation ◽  
Point Of Zero Charge ◽  
Degradation Rates ◽  
Simulated Solar Irradiation

Abstract The photocatalytic degradation of two phenylurea herbicides, monolinuron (MLN) and linuron (LN), was investigated in an aqueous suspension of TiO2 using simulated solar irradiation. The objective of the study was to compare their photocatalytic reactivity and to assess the influence of various parameters such as initial pesticide concentration, catalyst concentration and photonic flux on the photocatalytic degradation rate of MLN and LN. A comparative study of the photocatalytic degradation kinetics of both herbicides showed that these two compounds have a comparable reactivity with TiO2/simulated sun light. Under the operating conditions of this study, the photocatalytic degradation of MLN and LN followed pseudo first-order decay kinetics. The kobs values indicated an inverse dependence on the initial herbicide concentration and were fitted to the Langmuir-Hinshelwood equation. Photocatalytic degradation rates increased with TiO2 dosage, but overdoses did not necessarily increase the photocatalytic efficiency. The degradation rate of MLN increased with radiant flux until an optimum at 580 W m‑2 was reached and then decreased. Under these conditions, an electron-hole recombination was favored. Finally, the photocatalytic degradation rate depended on pH, where an optimum was found at a pH value close to the pH of the point of zero charge (pH = 6).

Research on the Solvothermal Synthesis and Photocatalytic Properties of Nano-Size ZnO

2013 ◽  
Vol 295-298 ◽  
pp. 503-506
Author(s):  
Da Jiang ◽  
Hong Liang Zhang ◽  
Ji Jie Wang
Keyword(s):  
Photocatalytic Degradation ◽  
Rhodamine B ◽  
Solvothermal Synthesis ◽  
Degradation Rate ◽  
Crystallization Mechanism ◽  
Photocatalytic Properties ◽  
Dimensional Structure ◽  
One Dimensional ◽  
Nano Size

Nano-size ZnO of one dimensional structure was prepared by solvothermal synthesis through dissolution-crystallization mechanism and characterized by TEM and XRD. Moreover, photocatalytic degradation rate of dye Rhodamine B (RhB) at the present of nano-size ZnO were carried out, and the results indicated that the nano-size ZnO prepared by such a method has excellent photocatalytic properties.

Photocatalytic removal of taste and odour compounds for drinking water treatment

2009 ◽  
Vol 9 (5) ◽  
pp. 477-483 ◽  
Author(s):  
H. Tran ◽  
G. M. Evans ◽  
Y. Yan ◽  
A. V. Nguyen
Keyword(s):  
Drinking Water ◽  
Sodium Bicarbonate ◽  
Photocatalytic Degradation ◽  
Rate Constants ◽  
Degradation Rate ◽  
Degradation Mechanism ◽  
Drinking Water Treatment ◽  
Degradation Process ◽  
Negative Effects ◽  
Reaction Rate Constants

Photocatalytic degradation of geosmin and 2-methylisoborneol (MIB), which are two taste and odour compounds commonly found in drinking water supply sources, was investigated using an immobilised TiO2 photoreactor. It was found that the degradation of geosmin and MIB followed similar pseudo-first-order kinetics with reaction rate constants being approximately 0.025 min−1 for typical geosmin and MIB concentrations of 250 and 500 ng/L. The normalised formal quantum efficiency was calculated to be in the range of 162–182 L/mol. Influence of additives (i.e. sodium bicarbonate and alcohols) on the degradation process was also investigated. It was found that there was a small reduction in the degradation rate constants of geosmin and MIB with increasing sodium bicarbonate concentration. At 50 mg/L sodium bicarbonate the degradation rate constants decreased by approximately 5%. Similarly, for methanol and ethanol concentrations up to 35 and 50 mg/L, respectively, these constants were found to also decrease. While addition of sodium bicarbonate and alcohols was seen to have relatively small negative effects on the photocatalytic degradation performance, the magnitude of their influence was consistent with the hypothesis that the degradation mechanism of geosmin and MIB was predominately that of attack involving HO∙ radicals.

Preparation of Bi1-xLaxVO4 and its Photocatalytic Degradation on Rhodamine B

2016 ◽  
Vol 852 ◽  
pp. 1473-1476
Author(s):  
Yan Ding ◽  
Liang Fang Fu ◽  
Yu Huan Wang ◽  
Liang Chao Li ◽  
Juan Bi Li
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Photocatalytic Degradation ◽  
Rhodamine B ◽  
Degradation Rate ◽  
Light Sensitivity ◽  
Structure Morphology ◽  
Photocatalytic Activities ◽  
Testing Techniques ◽  
Composition Structure

A series of photocatalyst Bi1-xLaxVO4 (0.1, 0.3, 0.5, 0.7) powders were prepared by hydrothermal method. The composition, structure, morphology and photocatalytic activity of the samples were researched by means of modern testing techniques. Bi1-xLaxVO4 showed excellent visible-light sensitivity and photocatalytic activities. The degradation rate of sample with x = 0.5 on rhodamine B reached 90 %, which was much higher than that of pure BiVO4.

Influence Factors and Kinetic Study on Photocatalytic Degradation of Rhodamine B by Fe-Doped TiO2/Diatomite Composite

2012 ◽  
Vol 535-537 ◽  
pp. 2209-2213 ◽  
Author(s):  
Jun Xiong Lin ◽  
Lan Wang ◽  
Chong Sun
Keyword(s):  
Photocatalytic Degradation ◽  
Kinetic Study ◽  
Rhodamine B ◽  
Sol Gel ◽  
Influence Factors ◽  
Degradation Process ◽  
Operational Parameters ◽  
Gel Method ◽  
Doped Tio2 ◽  
Decolorization Efficiency

Supported Fe-doped TiO2 has been prepared by a sol-gel method through the use of porous diatomite. The synthesized Fe-doped TiO2/diatomite composites were characterized by SEM and EDX techniques. The composite presented in this study showed higher adsorption and photodegradation ability of Rhodamine B than TiO2/diatomite and diatomite. It was found that the decolorization efficiency were dependent on the operational parameters of pH, photocatalyst dosage and dye concentration, and about 85% of the initial 50 mg/L dye could be adsorbed and degraded in 240 min. Moreover, kinetic study indicated that the photocatalytic degradation process could be described by the Langmuir-Hinshelwood model.

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