Effect of Carboxylmethyl Cellulose Sulfate (CMC-S) on the Hydration Process of Cement Paste

2013 ◽  
Vol 838-841 ◽  
pp. 123-126
Author(s):  
Feng Yuan Huang ◽  
Xiao Jie Wu ◽  
Wei Feng Ying ◽  
Yong Peng Yu ◽  
Hong Xun Chi
Keyword(s):  
Cement Paste ◽  
Differential Scanning Calorimeter ◽  
Setting Time ◽  
Reducing Agent ◽  
Hydration Heat ◽  
Hydration Process ◽  
Early Age ◽  
Cellulose Sulfate

The application of Carboxylmethyl Cellulose Sulfate (CMC-S) in cement paste was studied. The effect of CMC-S on the setting time of cement paste was investigated. Hydration heat of specimens with different cured age was measured via the Hydration Heat Tester (HHT), and hydration process was recorded via Differential Scanning Calorimeter (DSC). The results indicated that CMC-S was a kind of set-retarding and water-reducing agent; its retarding properties appeared at early age, but after three days, the hydration process of cement paste was even improved.

scholarly journals The Influence of Water Reducing Agents on Early Hydration Property of Ferrite Aluminate Cement Paste

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 731
Author(s):  
Chunlong Huang ◽  
Zirui Cheng ◽  
Jihui Zhao ◽  
Yiren Wang ◽  
Jie Pang
Keyword(s):  
Setting Time ◽  
Critical Role ◽  
Hydration Product ◽  
Reducing Agents ◽  
Reducing Agent ◽  
Hydration Process ◽  
Early Hydration ◽  
Cement Pastes ◽  
Hydration Rate ◽  
Aluminate Cement

The ferrite aluminate cement (FAC) could rapidly lose fluidity or workability due to its excessive hydration rate, and greatly reduce the construction performance. Chemical admixtures are commonly used to provide the workability of cement-based materials. In this study, to ensure required fluidity of FAC, chemically different water reducing agents are incorporated into the FAC pastes. The experiments are performed with aliphatic water reducing agent (AP), polycarboxylic acid water reducing agent (PC) and melamine water reducing agent (MA), respectively. Influence of the water reducing agents on fluidity, setting time, hydration process, hydration product and zeta potential of the fresh cement pastes is investigated. The results show that PC has a better dispersion capacity compared to AP and MA. Besides decreasing water dosage, PC also acts as a retarder, significantly increasing the setting times, delaying the hydration rate and leading to less ettringite in the hydration process of FAC particles. The water reducing agents molecules are adsorbed on the surface of positively charged minerals and hydration products, however, for PC, steric hindrance from the long side chain of PC plays a critical role in dispersing cement particles, whereas AP and MA acting through an electrostatic repulsion force.

Controlling the early-age hydration heat release of cement paste for deep-water oil well cementing: A new composite designing approach

2021 ◽  
Vol 285 ◽  
pp. 122949
Author(s):  
Da-heng Wang ◽  
Xiao Yao ◽  
Tao Yang ◽  
Wen-rui Xiang ◽  
Ying-tao Feng ◽  
...  
Keyword(s):  
Heat Release ◽  
Cement Paste ◽  
Deep Water ◽  
Hydration Heat ◽  
Early Age ◽  
Oil Well ◽  
Early Age Hydration

scholarly journals Effect of nano-SnO2 on early-age hydration of Portland cement paste

2019 ◽  
Vol 11 (6) ◽  
pp. 168781401985194 ◽  
Author(s):  
Jianping Zhu ◽  
Genshen Li ◽  
Ruijie Xia ◽  
Huanhuan Hou ◽  
Haibin Yin ◽  
...  
Keyword(s):  
Portland Cement ◽  
Cement Paste ◽  
Cement Hydration ◽  
Cementitious Materials ◽  
Hydration Process ◽  
Strength Development ◽  
Early Age ◽  
Test Machine ◽  
Portland Cement Paste ◽  
Scanning Electron

Nanomaterial, as a new emerging material in the field of civil engineering, has been widely utilized to enhance the mechanical properties of cementitious material. Nano-SnO2 has presented high hardness characteristics, but there is little study of the application of nano-SnO2 in the cementitious materials. This study mainly investigated the hydration characteristics and strength development of Portland cement paste incorporating nano-SnO2 powders with 0%, 0.08%, and 0.20% dosage. It was found that the early-age compressive strength of cement paste could be greatly improved when nano-SnO2 was incorporated with 0.08% dosage. The hydration process and microstructure were then measured by hydraulic test machine, calorimeter, nanoindentation, X-ray diffraction, scanning electron microscope, and mercury intrusion porosimetry. It was found that the cement hydration process was promoted by the addition of nano-SnO2, and the total amount of heat released from cement hydration is also increased. In addition, the addition of nano-SnO2 can promote the generations of high density C-S-H and reduce the generations of low density C-S-H indicating the nucleation effect of nano-SnO2 in the crystal growth process. The porosity and probable pore diameter of cement paste with 0.08% nano-SnO2 were decreased, and the scanning electron microscopic results also show that the cement paste with 0.08% nano-SnO2 promotes the densification of cement microstructure, which are consistent with the strength performance.

scholarly journals Effects of Shrinkage Reducing Agent and Expansive Additive on Plastic Shrinkage of Mortar at Different Temperatures

2018 ◽  
Vol 206 ◽  
pp. 02002
Author(s):  
Sarapon Treesuwan ◽  
Komsan Maleesee ◽  
Shigeyuki Date
Keyword(s):  
High Temperature ◽  
Setting Time ◽  
Reducing Agent ◽  
Early Age ◽  
Initial Setting Time ◽  
Plastic Shrinkage ◽  
Different Temperatures ◽  
Expansive Additive ◽  
Hot Weather ◽  
Shrinkage Reducing Agent

In the construction, it is inevitable to perform plaster work in hot weather which causes the dehydration and rapid shrinkage on the paste during the early age. This research shows the studies of reducing the plastic shrinkage of mortar during the early age with such additives as the Shrinkage Reducing Agent (SRA), the Expansive Additive (EX), and the Fly Ash (FA) in controlled temperatures at 30°C and 40°C, with relative humidity between 60% and 70% according to the ASTM C1579-06 standard, with the strain gauge installed at 0.5 cm.from the surface. The shrinkage rate was measured starting from the Initial Setting Time and every 10 minutes afterwards for 24 hours. The results show that high temperature effects the cracking and how to use different formulas of additive under different circumstances is considerably important. To use only one additive is not sufficient in high temperature. To use the SRA in addition to the EX enhances better expansion than to use only the EX. Moreover, it is recommended to pay close attention in adding large amount of the FA into mortar with the EX and SRA added which extremely enhances the expansion and potential cracking.

scholarly journals A Mathematical Model for the Electrical Resistivity of Cement Paste at Early Ages Considering the Partially Saturated State

Materials ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3306 ◽  
Author(s):  
Ye Tian ◽  
Xin Xu ◽  
Haodong Ji ◽  
Zushi Tian ◽  
Xianyu Jin ◽  
...  
Keyword(s):  
Mathematical Model ◽  
Electrical Resistivity ◽  
Cement Paste ◽  
Isothermal Calorimetry ◽  
Setting Time ◽  
Degree Of Saturation ◽  
Early Age ◽  
Saturation State ◽  
Partially Saturated ◽  
Saturated State

For cementitious materials, electrical resistivity is often used in the study of the cement hydration process at early age, as one of the few indicators that can be continuously and non-destructively monitored. Variation characteristics of resistivity are widely reported to interact with the early-age performance of cement paste, such as hydration kinetics parameters and setting time. However, there is no reasonable mathematical model to predict the resistivity at early ages, especially within the first 24 h, due to significant changes in the porosity and degree of saturation. In this work, a mathematical model was developed by considering the partially saturated state and density change of C-S-H (calcium silicate hydrate). To verify the model, two experimental methods were chosen, including the non-contact electrical resistivity test and isothermal calorimetry test. The hydration heat and resistivity of cement paste with a water–cement ratio of 0.35 and 0.45 were continuously monitored for 3 days. In the resistivity test, embedded temperature sensors were used to monitor the internal temperature and temperature correction was treated carefully in order to obtain accurate data. The test results prove that the mathematical model can accurately predict electrical resistivity and describe the saturation state of early-age cement pastes under sealed curing.

scholarly journals Effects of Nano-SiO2 and SAP on Hydration Process of Early-Age Cement Paste Using LF-NMR

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Haitao Zhao ◽  
Yi Wan ◽  
Jun Xie ◽  
Kaidi Jiang ◽  
Donghui Huang ◽  
...  
Keyword(s):  
Cement Paste ◽  
Bound Water ◽  
Hydration Process ◽  
Early Age ◽  
Superabsorbent Polymer ◽  
Test Results ◽  
Low Field ◽  
Water To Cement Ratio ◽  
Hydration Model ◽  
Zero Points

The effects of nano-SiO2 and superabsorbent polymer on the hydration process of early-age cement paste are investigated through the physically bound water evolution test by means of the low-field nuclear magnetic resonance technology. The test results show that the hydration process can be characterized by four-stage patterns based on the zero points of the second-order differential hydration curve, i.e., the initial, accelerated, decelerated, and steady periods. The beginning time of each stage is postponed and the hydration duration is prolonged with an increasing water to cement ratio. The beginning time of each stage and the hydration duration are shortened with an increasing content of nano-SiO2. And the beginning time of each stage and the hydration duration are prolonged with an increasing content of superabsorbent polymer. Based on the test data and the Avrami–Erofeev model, a modified hydration model taking the influence of nano-SiO2 and SAP into account is proposed, and the predicted results are consistent with the test results.

scholarly journals Effects of Highly Crystalized Nano C-S-H Particles on Performances of Portland Cement Paste and Its Mechanism

Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 816
Author(s):  
Yuli Wang ◽  
Huijuan Lu ◽  
Junjie Wang ◽  
Hang He
Keyword(s):  
Portland Cement ◽  
Cement Paste ◽  
Setting Time ◽  
Tricalcium Silicate ◽  
Strength Development ◽  
Early Age ◽  
Hydration Products ◽  
X Ray ◽  
Early Strength ◽  
Portland Cement Paste

In order to improve the early age strength of ordinary Portland cement-based materials, many early strength agents were applied in different conditions. Different from previous research, the nano calcium silicate hydrate (C-S-H) particles used in this study were synthesized through the chemical reaction of CaO, SiO2, and H2O under 120 °C using the hydrothermal method, and the prepared nano C-S-H particles were highly crystalized. The influences of different amounts of nano C-S-H particles (0%, 0.5%, 1%, 2% and 3% by weight of cement) on the setting time, compressive strength, and hydration heat of cement paste were studied. The hydration products and microstructure of the cement paste with different additions of nano C-S-H particles were investigated through thermogravimetry-differential thermal analysis (TG-DTA), X-ray powder diffraction (XRD), and scanning electron microscope (SEM) tests. The results show that the nano C-S-H particles could be used as an early strength agent, and the early strength of cement paste can be increased by up to 43% through accelerating the hydration of tricalcium silicate (C3S). However, the addition of more than 2% nano C-S-H particles was unfavorable to the later strength development due to more space being left during the initial accelerated hydration process. It is suggested that the suitable content of the nano C-S-H particles is 0.5%−1% by weight of cement.

Experimental Study on the Impact of Admixture for Concrete Heat of Hydration and Early-Age Contractile Properties

2012 ◽  
Vol 253-255 ◽  
pp. 385-389 ◽  
Author(s):  
Jian Cheng Sun ◽  
Bo Jun Wang ◽  
Wen Zhong Zhao
Keyword(s):  
Experimental Study ◽  
Fly Ash ◽  
Concrete Structure ◽  
Autogenous Shrinkage ◽  
Heat Of Hydration ◽  
Reducing Agent ◽  
Hydration Heat ◽  
Early Age ◽  
Mix Proportion ◽  
Structure Crack

During the technology development of modem concrete, concrete structure crack (especially early-age crack) becomes more and more serious and has been one of main research directions of civil engineering. This paper aims at the seriousness of concrete structure crack and presents one of main cause is that concrete early-age (especially autogenous shrinkage) become large through the experimental study. autogenous shrinkage are mainly belongs to temperature cracks and desiccation cracks. Analyses the affection of ash and water reducing agent on the hydration heat, under the optimum proportion experiment which aims at reducing he hydration heat of cement. The best program are obtained that double mix with 20% fly ash and 1.5% water reducing agent .Design mortar’s early anti-crack experiment, and study crack-resistance and other mechanical properties based on different ages & different mix proportion. From the experiment, analyses early cracking under the influence of admixtures. The mix proportion of 20% fly ash, 10% slag and 1.2% water reducing agent can minimize the creation of cracks.

scholarly journals Hydration of Early Age Cement Paste with Nano-CaCO3 and SAP by LF-NMR Spectroscopy: Mechanism and Prediction

2019 ◽  
Vol 2019 ◽  
pp. 1-10 ◽  
Author(s):  
Haitao Zhao ◽  
Gaoyang Sun ◽  
Lu Yu ◽  
Kaidi Jiang ◽  
Xiaodong Chen ◽  
...  
Keyword(s):  
Cement Paste ◽  
Initial Period ◽  
Bound Water ◽  
Hydration Process ◽  
Early Age ◽  
Starting Time ◽  
Water To Cement Ratio ◽  
Acceleration Period ◽  
Hydration Model ◽  
Lf Nmr

In this paper, by testing the evolution of the physically bound water using the low-field nuclear magnetic resonance (LF-NMR) technology, the hydration process of cement paste with nano-CaCO3 (NC) and superabsorbent polymer (SAP) at early age is investigated. Results indicate that the hydration process can be divided into four periods according to the zero points of the second-order differential hydration curve: initial period, acceleration period, deceleration period, and steady period. Firstly, with the increase in the water to cement ratio, the starting time of the hydration period is delayed, and the duration becomes longer. Secondly, the addition of NC leads to the speedy arrival of each period and shortens the duration of each period in the hydration process, and the optimal NC content is 1.5%. Thirdly, with the increase in SAP content, the starting time of the hydration period is delayed and the duration becomes longer. Finally, based on the experimental results and the existing hydration model, the modified hydration model considering the content of NC and SAP is proposed.

scholarly journals Effect of Delaminated MXene (Ti3C2) on the Performance of Cement Paste

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Jianping Zhu ◽  
Genshen Li ◽  
Chunhua Feng ◽  
Libo Wang ◽  
Wenyan Zhang
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Cement Paste ◽  
Cement Hydration ◽  
Hydration Heat ◽  
Hydration Process ◽  
Cement Matrix ◽  
Cement Composites ◽  
Hydrated Cement ◽  
Hydration Products

Delaminated MXene was incorporated into cement to improve the properties of cement composites, and its effects on the hydration process, microstructures, and mechanical properties were investigated, respectively. The investigation results showed that delaminated MXene was well-dispersed in the cement matrix and significantly reinforced the compressive strength of cement, especially when the addition is 0.01 wt%. Meanwhile, the total hydration heat of cement hydration and the quantity of hydration products were increased with the addition of delaminated MXene. In addition, the formation of HD C-S-H gel was promoted, and the microstructure of hydrated cement became more compact.

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