Preparation and Properties of Thiol-Ene UV-Curable Fluorinated Emulsion
2014 ◽
Vol 960-961
◽
pp. 138-142
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Keyword(s):
Single electron transfer living radical emulsion polymerization (SET-LRP) of allyl methacrylate (AMA) coupled with 2,2,3,4,4,4-hexafluorobutyl methacrylate (HFBA) was investigated in the presence of Cu(0)/N,N,N’,N’’,N’’-pentamethyldiethylenetriamine (PMDETA) as catalyst and ethyl 2-bromoisobutyrate (EBiB) as initiator. Solid content of the emulsion and the amount of the catalyst, initiator and emulsifier were discussed for the optimal reaction conditions. Then, the emulsion was combined with thiol capped polyurethane (SHPU) under UV to form the UV curable fluorinated films. Mechanical properties and contact angle of the UV cured films were studied.
2019 ◽
Vol 37
(11)
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pp. 1130-1141
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2011 ◽
Vol 306-307
◽
pp. 1663-1666