The Effect of Hydrogen on Pitting Corrosion of Superaustenitic and Austenitic-Ferritic Stainless Steels

2012 ◽  
Vol 326-328 ◽  
pp. 620-625 ◽  
Author(s):  
Joanna Michalska

Hydrogen entering into steel affects its electrochemical properties and may enhance the susceptibility to environmental degradation. The present work has been aimed at further clarifying the effect of hydrogenation on the corrosion behaviour and passivity of highly-alloyed stainless steels. The results were discussed by taking into account hydrogen charged samples and without hydrogen. The corrosion resistance to pitting was qualified with the cyclic polarization curves. The conclusion is that hydrogen may deteriorated the passive film stability and corrosion resistance to pitting of highly-alloyed stainless steel. Furthermore, the presence of hydrogen in passive films increases corrosion current density, decreasing the potential of the film breakdown and repassivation potential. It was also found that the degree of susceptibility to hydrogen-enhanced pitting corrosion was dependent on the type of steel.

2017 ◽  
Vol 62 (2) ◽  
pp. 711-714
Author(s):  
D. Kasprzyk ◽  
B. Stypuła

AbstractThe present work compares corrosion behaviour of four types of S30403, S31603, S32615 austenitic and S32404 austenitic-ferritic stainless steels in chloride solutions (1%, 3% NaCl) and in Ringer solution, at 37°C temperature. Corrosion resistance was determined by potentiodynamic polarization measurements and a thirty day immersion test conducted in Ringer solution. The immersion test was performed in term of biomedical application. These alloy were spontaneously passivated in all electrolytes, wherein S30403, S31603 and S32404 undergo pitting corrosion. Only S32615 containing 5.5% Si shows resistance to pitting corrosion.


2019 ◽  
Vol 121 ◽  
pp. 01011
Author(s):  
Olga Parmenova ◽  
Svetlana Mushnikova ◽  
Vitaliy Bobyr ◽  
Evgeniy Samodelkin

This paper presents the results of comparative corrosion resistance studies of stainless steels manufactured by selective laser melting (SLM) in the initial state with subsequent heat treatment and machining. Pitting corrosion tests are carried out, according to ASTM G48 method A in 10% FeCl3·6H2O solution at elevated temperature and exposure time for 5h. The studies were performed on the AISI 321 and AISI 316L stainless steels manufactured by SLM. It was obtained that laser scanning speed decrease led to density rise by other SLM parameters being equal. Porosity affected to the stainless steel corrosion behaviour significant. Metal density decrease resulted to corrosion rate rise. Microstructure examination showed that pitting corrosion development depended on surface steel condition.


2019 ◽  
Vol 25 (4) ◽  
pp. 217
Author(s):  
Andrea Di Schino

<p class="AMSmaintext1"><span lang="EN-GB">Following nickel and molybdenum significant price increase, nowadays the stainless steel market is moving toward an increasing use of ferritic stainless steel instead of austenitic stainless and therefore to the development of advanced ferritic stainless steels grades aimed to substitute the more expensive austenitic materials in all applications allowing it. Super-ferritic stainless steels are higher chromium (Cr) and molybdenum (Mo) steels with properties similar to those of standard ferritic alloys. Such elements increase high temperature and corrosion resistance in strong environment. This paper deal about the corrosion resistance of super-ferritic stainless steels with a Cr content ranging from 21% to 24%. </span></p>


2017 ◽  
Vol 754 ◽  
pp. 11-14 ◽  
Author(s):  
Marialaura Tocci ◽  
Lorenzo Montesano ◽  
Annalisa Pola ◽  
Marcello Gelfi ◽  
Marina La Vecchia

In the present work, the effect of Cr and Mn addition on corrosion resistance was investigated on AlSi3Mg alloy. Potentiondynamic corrosion tests in a 3.5 wt. % NaCl solution were performed on samples in different heat-treated conditions, and corrosion current density and potential were determined by Tafel method. Brinnel hardness measurements were also carried out in order to couple corrosion resistance with mechanical properties. It was interestingly found that Cr presence enhanced mechanical properties and corrosion resistance in comparison with the base alloy.


Alloy Digest ◽  
2013 ◽  
Vol 62 (3) ◽  

Abstract ATI 436S is a ferritic stainless steel stabilized with titanium. It is superior to ATI Type 409 and 430 in general and pitting corrosion resistance. The ATI 436S alloy exhibits machining, welding, and forming characteristics similar to those of other stabilized, ferritic stainless steels. This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: SS-1139. Producer or source: Allegheny Ludlum.


Author(s):  
J. Alias

Much research on magnesium (Mg) emphasises creating good corrosion resistance of magnesium, due to its high reactivity in most environments. In this study, powder metallurgy (PM) technique is used to produce Mg samples with a variation of aluminium (Al) composition. The effect of aluminium composition on the microstructure development, including the phase analysis was characterised by optical microscope (OM), scanning electron microscopy (SEM) and x-ray diffraction (XRD). The mechanical property of Mg sample was performed through Vickers microhardness. The results showed that the addition of aluminium in the synthesised Mg sample formed distribution of Al-rich phases of Mg17Al12, with 50 wt.% of aluminium content in the Mg sample exhibited larger fraction and distribution of Al-rich phases as compared to the 20 wt.% and 10 wt.% of aluminium content. The microhardness values were also increased at 20 wt.% and 50 wt.% of aluminium content, comparable to the standard microhardness value of the annealed Mg. A similar trend in corrosion resistance of the Mg immersed in 3.5 wt.% NaCl solution was observed. The corrosion behaviour was evaluated based on potentiodynamic polarisation behaviour. The corrosion current density, icorr, is observed to decrease with the increase of Al composition in the Mg sample, corresponding to the increase in corrosion resistance due to the formation of aluminium oxide layer on the Al-rich surface that acted as the corrosion barrier. Overall, the inclusion of aluminium in this study demonstrates the promising development of high corrosion resistant Mg alloys.


Alloy Digest ◽  
1999 ◽  
Vol 48 (5) ◽  

Abstract J and L Types 409 HP are ferritic stainless steels with 11% chromium. They exhibit an excellent combination of good formability, economy, and resistance to oxidation and corrosion. It is typically used in automotive exhaust systems. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-743. Producer or source: J & L Specialty Steel Inc.


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