Effect of CaTiO3 Content on the Dielectric Properties of Ba0.5Sr0.5TiO3

2007 ◽  
Vol 280-283 ◽  
pp. 89-90
Author(s):  
Chun Lai Xu ◽  
He Ping Zhou

In this paper, a microwave material (Ba0.85Ca0.15)0.5Sr0.5TiO3 with 5 wt% MgO additive was prepared by traditional solid-state reactions, i.e., mixing BaTiO3 and SrTiO3 powders and then doping CaTiO3 and MgO. It was found that, with the increasing CaTiO3 content, the dielectric constant of the resultant material decreases and the tunability and dielectric loss increase.

2013 ◽  
Vol 675 ◽  
pp. 200-204
Author(s):  
Fei Shi ◽  
Peng Cheng Du ◽  
Jing Xiao Liu ◽  
Ji Wei Wu ◽  
De Qing Chen ◽  
...  

The Mg2SiO4-MgTiO3-CaTiO3 composite dielectric ceramics with different Mg2SiO4 addition amounts were prepared by solid state reaction method. The effects of Mg2SiO4 addition amounts on the microstructure and dielectric properties as well as sintering temperature of xMg2SiO4-(0.95-x)MgTiO3-0.05CaTiO3 (abbreviated as xMSTC, 0.25≦x≦0.75) composite ceramics were investigated. The results indicated that the sintering temperature of MgTiO3-CaTiO3 based ceramics with Mg2SiO4 addition could be lowered effectively to 1320~1340°C, and the dielectric constant decreased and dielectric loss increased gradually with the increase of Mg2SiO4 content. The 0.45MSTC ceramics containing 45 wt% Mg2SiO4 and sintered at 1340°C showed desirable dielectric properties with dielectric constant εr=13.3,dielectric loss tanδ=4.5×10-4 and temperature coefficient of relative permittivity τε =10 ppm/°C.


2010 ◽  
Vol 434-435 ◽  
pp. 278-280
Author(s):  
Yan Hong Gu ◽  
Wan Ping Chen ◽  
Ming Jian Ding ◽  
Jian Quan Qi

BiFeO3, BiFe0.9Ti0.1O3 and BiFe0.9Ti0.05O3 ceramics were prepared by solid state reactions and were compared in electrical and dielectric properties. The resistivity of BiFe0.9Ti0.05O3 was 1.3×1012 Ω cm, which was about two and a half orders of magnitude higher than that of BiFeO3. and three times higher than that of BiFe0.9Ti0.1O3. The dielectric loss of BiFe0.9Ti0.05O3 was 0.1 and 0.02 at 100Hz and 1MHz, respectively. These phenomena can be explained base on the decrease of oxygen vacancies VO•• and defect complexes between the ferrum vacancies VFe and oxygen vacancies VO•• in the ceramics.


2012 ◽  
Vol 549 ◽  
pp. 749-752
Author(s):  
Hai Tang Hua ◽  
Xin You Huang ◽  
Zhi Wen Zhu ◽  
Yin Qun Hua ◽  
Yan Li

(Bi2-xLix) (Mg2/3Nb1.1833Sn0.15)O7 piezoelectric ceramics were prepared by conventional solid state reaction method. The microstructure and dielectric properties of dielectric ceramics were studied which was doped by different amount of Li2CO3. The experiment results showed that the density of the ceramics would decrease, but have little effect on the microstructure of the ceramics when the amount of the Li2CO3 doped increases. With the increasing of Li2CO3 doped, the dielectric constant(εr) and dielectric loss(tanδ) of dielectric ceramics first decreases and then increases. When tested in 1MHz frequency, the piezoelectric ceramics display the optimum properties tanδ is 0.00009, εr is 163 while Li2CO3 doped amount is 0.05 mol%.


2007 ◽  
Vol 280-283 ◽  
pp. 79-80
Author(s):  
Hao Xue ◽  
He Ping Zhou ◽  
Chen Ai

Ba1-xSrxTiO3 ceramic (BST) was one of the promising materials applied in phased array antennas due to its excellent dielectric properties. Ba1-xSrxTiO3 ceramic was prepared by traditional solid state reactions. Effects of different amount of ZrO2 as additive upon the dielectric properties of BST were investigated. The analyzed results showed that, as the amount of ZrO2 increasing, the dielectric constant and temperature dependence of dielectric constant of this ceramic both decreased, while its dielectric tunability kept high value.


2007 ◽  
Vol 280-283 ◽  
pp. 115-118
Author(s):  
Jian Fei Wang ◽  
Yuan Hua Lin ◽  
Yu Chen ◽  
Lei Jiang ◽  
Ce Wen Nan

NiO-NiTiO3 composite ceramics were prepared by the conventional solid state reaction process and dielectric properties were investigated as a function of frequency and temperature. The results indicate that all samples showed high dielectric constant ~103 at 0.1 kHz, but a remarkable decrease of the dielectric loss appeared when the volume fraction of NiTiO3 phase reached 42.4%. Relaxor-like peaks were observed in the temperature dependence of the dielectric constant with ceramics having low composition of NiTiO3 phase (≤21.2%). The possible response mechanism associated with the microstructure and the associated defects of the composites was discussed.


2015 ◽  
Vol 08 (04) ◽  
pp. 1550040 ◽  
Author(s):  
Chao Zhang ◽  
Shan-Shan Wang ◽  
Rui-Song Guo ◽  
Guang-Lan Cai ◽  
Wei-Na Guo ◽  
...  

Magnetic and dielectric properties of 3Y-TZP/20 wt.% Ba 1-x Sr x Fe 12 O 19 (x = 0, 0.25, 0.5, 0.75) composites prepared by solid state reaction method are investigated. The magnetic properties are improved in the composites with the strontium doped barium ferrite. When x = 0.25, the saturation magnetization of the ferrite reaches the maximum. This is due to the migration of Fe 3+ induced by the Sr 2+ doping. The dielectric properties are also improved in the composite with the strontium doped barium ferrite. When x = 0.5, the dielectric constant and dielectric loss possess the maximum. This is caused by the lattice distortion resulting from the Sr 2+ doping. The dielectric properties are analyzed by the universal relaxation law.


2014 ◽  
Vol 895 ◽  
pp. 190-193
Author(s):  
Mohd Fariz Ab Rahman ◽  
Sabar Derita Hutagalung ◽  
Julie Juliewatty Mohamed ◽  
Mohd Fadzil Ain

Mg-doped CaCu3Ti4O12 (CCTO) systems were prepared by solid state reaction using raw materials of CaCO3, CuO, TiO2 and MgO. The samples were calcined at 900°C for 12 hours and sintered at 1030°C for 10 hours. Single phase CCTO formed after sintering process. It was found that dielectric constant and dielectric loss of CCTO improved by MgO dopant.


2008 ◽  
Vol 368-372 ◽  
pp. 118-120 ◽  
Author(s):  
Jing Han You ◽  
Qing Dong Chen ◽  
Wei Wei Ju ◽  
Li Ben Li ◽  
Kai Chen

CaCu3Ti4O12 and CaCu3Ti3.9Zr0.1O12 ceramics were prepared by the traditional solid-state reaction method and the dielectric properties were investigated. Comparison of the results of the two samples examined indicated that the partial replacement of titanium by zirconium in the system CaCu3Ti4O12 may result in different changes of the dielectric constant and dielectric loss. For these experimental phenomena possible explanations and predictions also have been presented.


2011 ◽  
Vol 326 ◽  
pp. 127-130
Author(s):  
Xian Li Huang ◽  
Fu Ping Wang ◽  
Ying Song

In the present work, the microstructure and microwave dielectric properties of BaTi4O9 ceramics derived from a sol-gel precursor were presented. Density measuring results demonstrated that the largest densities of ceramic sample about 96.7% could be reached by virtue of a cool iso-static press and a sintering process at at 1300 °C for 6 hours. The dielectric constant (εr), quality factor (Q×f) and the temperature coefficients (τf) of the BaTi4O9 ceramic samples were 36.65, 28000 GHz, +20.2 ppm/°C, respectively. XRD, SEM and XPS were used to characterize the microstructure of the ceramics samples. Substantial Ti3+ was proposed to be the cause of dielectric loss.


2010 ◽  
Vol 105-106 ◽  
pp. 355-358 ◽  
Author(s):  
Z.L. Zhu ◽  
Dong Yan Tang ◽  
X.H. Zhang ◽  
Y.J. Qiao

To prevent the potential cracking of gel fibers, La modified lead zirconate titanate (PLZT) ceramic fibers with diameter within 50µm were achieved by embedding into PLZT powders during the heat treatment. Then the 1-3 PLZT fiber/interpenetrating polymer network (IPN) piezoelectric composites were prepared by casting the IPN precursors onto the well aligned ceramic fibers. The influences of the heating temperatures and La amounts on the dielectric constant, dielectric loss with frequencies and piezoelectric constant of PLZT were investigated in detail. The morphologies of fibers and composites were observed by biological microscope. And also, the dielectric constant of PLZT fibers and PLZT fiber/IPN piezoelectric composites were detected.


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