Application of an Equivalent Circuit Model for Ionic Polymer-Metal Composite (IPMC) Bending Actuator Loaded With Multiwalled Carbon Nanotube (M-CNT)

2006 ◽  
Vol 309-311 ◽  
pp. 593-596 ◽  
Author(s):  
Deuk Yong Lee ◽  
Kwang Jin Kim ◽  
Seok Heo ◽  
Myung Hyun Lee ◽  
Bae Yeon Kim

Biomimetic actuators that can produce soft-actuation but large force generation capability are of interest. NafionTM, an effective ionomeric material from DuPont, has been shown to produce large deformation under low electric fields (<10V/mm). In this effort, multi-walled carbon nanotube (M-CNT)/NafionTM nanocomposites were prepared by casting in order to investigate the effect of M-CNT loading in the range of 0 to 7 wt% on electromechanical properties of the MCNT/ NafionTM nanocomposites. The measured elastic modulus and actuation force of the MCNT/ NafionTM nanocomposites are drastically different, showing larger elastic modulus and improved electromechanical coupling, from the one without M-CNT. In this work, we attempted to incorporate an equivalent circuit analysis to address the effect of capacitance and resistance of such M-CNT/NafionTM nanocomposites that would differ from conventional IPMCs.

2005 ◽  
Vol 284-286 ◽  
pp. 733-736 ◽  
Author(s):  
Deuk Yong Lee ◽  
Seok Heo ◽  
Kwang Jin Kim ◽  
D. Kim ◽  
Myung Hyun Lee ◽  
...  

Biomimetic actuators that can produce soft-actuation but large force generation capability are of interest. Nafion, an effective ionomeric material from DuPont, has been shown to produce large deformation under low electric fields (<10V/mm). This response is caused by a direct electro-osmotic effect due to the existence and mobility of cations and subsequent swelling and deswelling of the material. In this effort, multiwalled carbon nanotube (MWNT)/Nafion nanocomposites were prepared by a casting in order to investigate the effect of MWNT loading in the range of 0 to 7 wt% on electromechanical properties of the MWNT/Nafion nanocomposites. The measured elastic modulus and actuation force of the MWNT/Nafion nanocomposites are drastically different, showing larger elastic modulus and improved electromechanical coupling, from the one without MWNT, implying that the effective MWNT loading is crucial to develop high-performance biomimetic actuators.


Energies ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 213 ◽  
Author(s):  
Evgeny P. Kitsyuk ◽  
Renat T. Sibatov ◽  
Vyacheslav V. Svetukhin

The development of portable electronic devices has greatly stimulated the need for miniaturized power sources. Planar supercapacitors are micro-scale electrochemical energy storage devices that can be integrated with other microelectronic devices on a chip. In this paper, we study the behavior of microsupercapacitors with in-plane interdigital electrodes of carbon nanotube array under sinusoidal excitation, step voltage input and sawlike voltage input. Considering the anomalous diffusion of ions in the array and interelectrode space, we propose a fractional-order equivalent circuit model that successfully describes the measured impedance spectra. We demonstrate that the response of the investigated micro-supercapacitors is linear and the system is time-invariant. The numerical inversion of the Laplace transforms for electric current response in an equivalent circuit with a given impedance leads to results consistent with potentiostatic measurements and cyclic voltammograms. The use of electrodes based on an ordered array of nanotubes reduces the role of nonlinear effects in the behavior of a supercapacitor. The effect of the disordering of nanotubes with increasing array height on supercapacitor impedance is considered in the framework of a distributed-order subdiffusion model.


Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 3927
Author(s):  
Eo Ryeong Lee ◽  
Se Eun Shin ◽  
Naoki Takata ◽  
Makoto Kobashi ◽  
Masaki Kato

This study provides a novel approach to fabricating Al/C composites using laser powder bed fusion (LPBF) for a wide range of structural applications utilizing Al-matrix composites in additive manufacturing. We investigated the effects of LPBF on the fabrication of aluminum/multiwalled carbon nanotube (Al/MWCNT) composites under 25 different conditions, using varying laser power levels and scan speeds. The microstructures and mechanical properties of the specimens, such as elastic modulus and nanohardness, were analyzed, and trends were identified. We observed favorable sintering behavior under laser conditions with low energy density, which verified the suitability of Al/MWCNT composites for a fabrication process using LPBF. The size and number of pores increased in specimens produced under high energy density conditions, suggesting that they are more influenced by laser power than scan speed. Similarly, the elastic modulus of a specimen was also more affected by laser power than scan speed. In contrast, scan speed had a greater influence on the final nanohardness. Depending on the laser power used, we observed a difference in the crystallographic orientation of the specimens by a laser power during LPBF. When energy density is high, texture development of all samples tended to be more pronounced.


Author(s):  
Yung J. Jung ◽  
Laila Jaber-Ansari ◽  
Xugang Xiong ◽  
Sinan Mu¨ftu¨ ◽  
Ahmed Busnaina ◽  
...  

We will present a method to fabricate a new class of hybrid composite structures based on highly organized multiwalled carbon nanotube (MWNT) and singlewalled carbon nanotube (SWNT) network architectures and a polydimethylsiloxane (PDMS) matrix for the prototype high performance flexible systems which could be used for many daily-use applications. To build 1–3 dimensional highly organized network architectures with carbon nanotubes (both MWNT and SWNT) in macro/micro/nanoscale we used various nanotube assembly processes such as selective growth of carbon nanotubes using chemical vapor deposition (CVD) and self-assembly of nanotubes on the patterned trenches through solution evaporation with dip coating. Then these vertically or horizontally aligned and assembled nanotube architectures and networks are transferred in PDMS matrix using casting process thereby creating highly organized carbon nanotube based flexible composite structures. The PDMS matrix undergoes excellent conformal filling within the dense nanotube network, giving rise to extremely flexible conducting structures with unique electromechanical properties. We will demonstrate its robustness under large stress conditions, under which the composite is found to retain its conducting nature. We will also demonstrate that these structures can be directly utilized as flexible field-emission devices. Our devices show some of the best field enhancement factors and turn-on electric fields reported so far.


2014 ◽  
Vol 609-610 ◽  
pp. 152-158 ◽  
Author(s):  
Mei Rong Sui ◽  
Xiu Quan Gu

TiO2 nanorod arrays (NRA) were synthesized via a facile hydrothermal method for preparing the dye-sensitized solar cells (DSSC). It was found that a post-thermal treatment facilitated enhancing the cell efficiency. The cells containing NRs underwent 500 °C annealing exhibited much higher efficiency than those un-sintered ones. Further, the internal resistance analysis was carried out to reveal the mechanism underlying the DSSC performance improvement. Specifically, the equivalent circuit model was employed to derivate the internal resistances, which was consistent with the experimental results. It was found that the sintered cells exhibited a higher series resistance and a lower shunt resistance than the un-sintered ones, suggesting the higher photocurrent density might result from the larger amount of dye loading.


2011 ◽  
Vol 21 (4) ◽  
pp. 045026 ◽  
Author(s):  
Yang-Che Chen ◽  
Chao Min Chang ◽  
Rongshun Chen ◽  
Max Ti-Kuang Hou ◽  
Hiroshi Toshiyoshi ◽  
...  

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