Effect of Hydrogen Concentration at Overlay / Base Metal Interface on Repair Weldability of Petroleum Pressure Vessel

2008 ◽  
Vol 580-582 ◽  
pp. 5-8
Author(s):  
Hiroaki Mori ◽  
Kazutoshi Nishimoto ◽  
Rinzo Kayano

In order to extend the life of petroleum pressure vessels operated in long term, it is demanded to establish the repair welding technique. To make clear the effect of weld thermal cycles during repair welding on the hydrogen content and weld cold cracking at the base metal of 2.25Cr- 1Mo steel / overlaying metal of austenitic stainless steels interface in the structural material of petroleum pressure vessels, the crack susceptibility was estimated by y-groove weld cracking test and repair welding test with varying overlay thickness and hydrogen exposure conditions. In addition, the hydrogen distribution in the material was calculated by the theoretical analysis using the diffusion equation based on activity. The crack susceptibility was raised with increase in the hydrogen content at the interface. It was concluded that the cracking could be prevented by controlling the repair welding process to reduce the hydrogen content at the interface.

Author(s):  
Rinzo Kayano ◽  
Hiroaki Mori ◽  
Kazutoshi Nishimoto

In order to extend the life of petroleum pressure vessels operated in long term, it is needed to establish the reliable repair welding technique. Weld cold cracking sometimes occurred in long-term operated petroleum pressure vessels due to hydrogen embrittlement by thermal stress and diffusible hydrogen after repair welding. The cracking was caused by the hydrogen concentration at the base meal of 2.25Cr-1Mo steel/overlaying metal of austenitic stainless steels interface during the service with high temperature and hydrogen partial pressure. The tendency was accelerated by carbide precipitation at the interface due to the post weld heat treatment (PWHT) and the operation with high temperature. That is, the crack susceptibility at the interface became markedly higher owing to the hydrogen embrittlement with metallurgical degradation by thermal embrittlement. To make clear the effect of weld thermal cycles during repair welding on the hydrogen content and weld cold cracking at the interface in the structural material of petroleum pressure vessels, the crack susceptibility was estimated by y-groove weld cracking test with varying overlay thickness and hydrogen exposure conditions. In addition, the hydrogen distribution in the material was calculated by the theoretical analysis using the diffusion equation based on activity. The crack susceptibility was raised with increase in the hydrogen content at the interface. It was concluded that the cracking could be prevented by controlling the repair welding process to reduce the hydrogen content at the interface.


Author(s):  
Rinzo Kayano ◽  
Eiichi Yamamoto ◽  
Takayasu Tahara

Pressure vessels made from Cr-Mo steels are utilized for high temperature and high pressure services including hot hydrogen services. After long term operation, there are several past experiences of damages and/or degradation of materials such as temper embrittlement, creep embrittlement, hydrogen attack and hydrogen embrittlement. This paper summarizes typical damages/degradation and examples of weld repairs including special attention to development of weld repair procedure. The subject equipments are heavy wall petroleum pressure vessels made from Cr-Mo steel with austenitic stainless steel overlay cladding. Cracking could be prevented by controlling the repair welding process to reduce the hydrogen content at the interface. After repair welding, adequate post weld heat treatment (PWHT) has to be executed. Recently, repair welding has become an important aspect as part of post construction codes for pressure equipment to keep safe and long term continuous operation of the process plants because many of the plants have been operated for more than thirty years in Japan. Responding to the needs of petroleum and chemical industries, The Chemical Plant Welding Research Committee (CPWRC) of The Japan Welding Engineering Society (JWES) established the Pressure Equipment Repair Welding Subcommittee (PERW S/C) [1]. The S/C has developed optimum repair welding methods and procedures in the guideline on November 2009, with reference to the above investigation results. This paper also introduces the repair welding guideline for the pressure vessels made from Cr-Mo steels.


Author(s):  
Rinzo Kayano ◽  
Masamitsu Abe ◽  
Yukio Hirai

It has been recognized that repair welding plays an important role in the long term, safe operation of pressure equipment. In 2009, The Japan Welding Society (JWES) published guidelines for repair welding of pressure equipment [1], to meet the great need for the safe operation and proper maintenance of aging plants. Pressure equipments made from carbon steel, high tensile steel and Cr-Mo steels are utilized for high pressure services. The subject equipments are pressure vessels, heat exchangers, piping, and storage tanks for petroleum, petrochemical and liquefied natural gas industry. This paper summarizes category and property of these steels and repair welding method including special attention. Especially, weld cold cracking for these steels could be prevented by controlling the repair welding and post-weld heat treatment process to reduce the hydrogen content, hardness and weld residual stress.


Author(s):  
Yurianto ◽  
Gunawan Dwi Haryadi ◽  
Sri Nugroho ◽  
Sulardjaka ◽  
Susilo Adi Widayanto

The heating and cooling at the end of the welding process can cause residual stresses that are permanent and remain in the welded joint. This study aims to evaluate the magnitude and direction of residual stresses on the base metal and heat-affected zone of rail joints welded by the manual shielded metal arc and thermite welding. This research supports the feasibility of welding for rail. The material used in this study is the R-54 rail type, and the procedure used two rail samples of one meter long each, welded using manual shielded metal arc welding and thermite welding. The base metal and heat-affected zone of the welded joints were scanned with neutron ray diffraction. The scan produces a spectrum pattern and reveals the direction of the residual stress along with it. We found the strain value contained in both types of welded joints by looking at the microstrain values, which we obtained using the Bragg equation. The results show that the magnitude and direction of the residual stress produced by manual shielded metal arc welding and thermite welding are not the same. Thermite welding produces lower residual stress (lower crack susceptibility) than manual shielded metal arc welding. The melt's freezing starts from the edge to the center of the weld to create random residual stresses. The residual stress results of both the manual shielded metal arc welding and thermite welding are still below the yield strength of the base metal.


Author(s):  
Hiroaki Mori ◽  
Rinzo Kayano ◽  
Hiroyuki Ogiwara ◽  
Kazuyoshi Saida ◽  
Kazutoshi Nishimoto

Numerical analysis of hydrogen distributions in the welds of stainless clad steels, which are the structural material of hydrogen storage pressure vessels, was conducted to predict the hydrogen embrittlement in the pressure vessels. The theoretical model for the calculation was based on the activity of hydrogen considering residual stresses induced by welding and hydrogen accumulating sites such as precipitates and dislocations. From the calculations, hydrogen concentrates at the center of weld metals in both of longitudinal and circumferential directions in welded joints of stainless clad steels. However, the hydrogen contents were much lower than those in the carbide layers, in which are observed in steels with weld overlay of stainless steels, as the calculation of hydrogen distribution in the materials using the higher evaluated diffusion coefficient of hydrogen with considering margin of safety. Therefore, it seemed that the risk of cold cracking due to hydrogen embrittlement was sufficiently lower in the welds of stainless clad steels during many cycles of shutdown and restart of the pressure vessels in long-term operation.


Author(s):  
Keiji Kubushiro ◽  
Noriko Saito ◽  
Hirokatsu Nakagawa ◽  
Kota Sawada ◽  
Kazuhiro Kimura

The microstructure and creep properties of the Mod.9Cr-1Mo steel of repair welds after long-term service for about 80,000 hours at around 600°C were investigated. Two types of heat affected zone (HAZ) were formed after repair welding performed at the interface between base metal and original weld metal. The first type was a HAZ formed in an ex-service original weld metal and another type was formed in an ex-service base metal. Creep rupture life of HAZ formed in an ex-service original weld metal was extremely short and it was about one fourth of that of HAZ formed in an ex-service base metal. From microstructural observation, many fine ferrite grains surrounded by carbides were present on grain boundaries and, therefore, duplex structure of ferrite and martensite was observed in the fine grain HAZ region formed in an ex-service original weld metal. These fine ferrite grains were considered to be formed by diffusion transformation of gamma phase to alpha phase instead of martensitic transformation during cooling of thermal history due to repair welding. It has been concluded that the creep strength of an ex-service weld metal is remarkably reduced by the formation of many fine ferrite grains due to repair welding.


Author(s):  
Dorian K. Balch ◽  
Steve H. Goods ◽  
Chris San Marchi

Aluminum alloys offer significant advantages for hydrogen service such as low weight, improved uniformity of properties relative to forged austenitic stainless steels, and immunity to embrittlement in the presence of dry hydrogen. For these reasons aluminum alloys are now being considered for high-pressure hydrogen isotope pressure vessel applications where forged stainless steels have been the standard materials of construction for decades. In particular, alloy AA2219 is being evaluated due to its excellent weldability, microstructural stability, and good mechanical and fracture toughness properties. Prototype AA2219 pressure vessels have been fabricated and tested, including electron beam weld development, weld hardness and tensile testing prior to and after post-weld heat treatment, and burst testing. The design, manufacture, and testing of AA2219 pressure vessels will be discussed, including an ongoing long-term shelf storage program where pressure vessels are loaded with gaseous hydrogen at pressure of 103 MPa (85% of the burst pressure for these vessels).


2021 ◽  
Vol 3 (3) ◽  
Author(s):  
Payam Tayebi ◽  
Ali Fazli ◽  
Parviz Asadi ◽  
Mahdi Soltanpour

AbstractIn this study, in order to obtain the maximum possible formability in tailor-welded blank AA6061 sheets connected by the friction stir welding (FSW) procedure, the incremental sheet forming process has been utilized. The results are presented both numerically and experimentally. To obtain the forming limit angle, the base and FSWed sheets were formed in different angles with conical geometry, and ultimately, the forming limit angle for the base metal and FSWed sheet is estimated to be 60° and 57.5°, respectively. To explore the effects of welding and forming procedures on AA6061 sheets, experimental studies such as mechanical properties, microstructure and fracture analysis are carried out on the samples. Also, the thickness distribution of the samples is studied to investigate the effect of the welding process on the thickness distribution. Then, the numerical process was simulated by the ABAQUS commercial software to study the causes of the FSWed samples failure through analyzing the thickness distribution parameter, and major and minor strains and the strain distribution. Causes of failure in FSWed samples include increased minor strain, strain distribution and thickness distribution in welded areas, especially in the proximity of the base metal area.


2021 ◽  
Author(s):  
Zhiyuan Han ◽  
Guoshan Xie ◽  
Haiyi Jiang ◽  
Xiaowei Li

Abstract The safety and risk of the long term serviced pressure vessels, especially which serviced more than 20 years, has become one of the most concerned issues in refining and chemical industry and government safety supervision in China. According to the Chinese pressure vessel safety specification TSG 21-2016 “Supervision Regulation on Safety Technology for Stationary Pressure Vessel”, if necessary, safety assessment should be performed for the pressure vessel which reaches the design service life or exceeds 20 years without a definite design life. However, the safety and risk conditions of most pressure vessels have little changes after long term serviced because their failure modes are time-independent. Thus the key problem is to identify the devices with the time-dependent failure modes and assess them based on the failure modes. This study provided a case study on 16 typical refining and chemical plants including 1870 pressure vessels serviced more than 20 years. The quantitative risk and damage mechanisms were calculated based on API 581, the time-dependent and time-independent failure modes were identified, and the typical pressure vessels were assessed based on API 579. Taking the high pressure hydrogenation plant as an example, this study gave the detailed assessment results and conclusions. The results and suggestions in this study are essential for the safety supervision and extending life of long term serviced pressure vessels in China.


Author(s):  
Geoff W. Connors

Protection of the pipe during and after pipeline construction is of paramount importance for safety and pipeline integrity. Areas of rock and stone are often encountered during construction of new pipelines. Even with modern pipeline coatings, additional protection for the pipe is necessary where rock or stone exposure is significant. Historically, additional pipe protection used in these types of situations is achieved through adding either a significant layer of sand or select backfill above and below the pipeline (sand padding) and/or by attaching a high-impact resistant, poly-type rock shield around the pipeline during the pipeline installation process. To accommodate sand padding, some form of intermittent support of the pipeline is generally required to elevate the pipeline off the trench bottom. Similar intermittent support is also recommended practice when using poly-type rock shields to keep the pipeline from fully resting on trench rocks. Current methods of in-trench support involve sand piles, sand bags, spray foam and individually formed foam pillows — each with drawbacks: i) Sand Piles are difficult to install and often oval or dent the pipe when improperly placed. ii) Sand bags require hand placement for proper support. In open trenches, this can be time consuming and unsafe. Improper placement can cause the pipe to oval or dent. iii) Spray-in foam is considered to be an obstruction of cathodic protection currents. Newly constructed pipelines full of hydrostatic test water and one metre cover can cause foam to compress excessively. iv) Foam pillows are light and easily placed — but can float out of position and compress or crack under heavy loads. As with all foam, cathodic shielding is always a concern. A new, engineered method of in-trench pipeline support is now available — the Structured Pipeline Pillow (SPP). SPP’s are injection molded and made from high strength, environmentally inert polypropylene or polyethylene resins. Designed to support any size pipeline, SPP’s are most effective with larger diameter, heavier pipelines. One SPP is engineered to carry a single 40′ joint of heavy wall pipeline filled with hydrostatic test water. Compared with current methods, SPP’s: i) Stack tightly for transport. ii) Are light enough for installation from outside the trench and resist floatation when ground water is present. iii) Help ensure the pipeline is centered in the trench during the pipeline installation. iv) Maintain long-term pipe clearance above rocky trench bottoms. v) Ovality and denting concerns are reduced. vi) Allow cathodic protection an easy path to the pipeline. vii) Will never biodegrade. In their extended stacking mode, SPP’s tested well as an effective alternative to wooden skids for many situations such as pipe stockpiling; stringing along the rights-of-way (ROW); and even for some low level skidding during the welding process.


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