Influence of a Novel Master Alloy Addition on the Grain Refinement of Al-Si Cast Alloys

2013 ◽  
Vol 765 ◽  
pp. 311-315 ◽  
Author(s):  
Leandro Bolzoni ◽  
Magdalena Nowak ◽  
N. Hari Babu

The grain refinement practice using Ti based chemical additions is well established for wrought Al alloys, especially in the last few decades. In the case of Al-Si casting alloys the practice of adding grain refiners and the impact on castability is not well established in industries. The main reason is the chemical instability of conventionally known Ti based grain refiner which reacts with silicon forming intermetallic phases. Recently, researchers at Brunel University have identified a novel chemical composition that can refine the grain structure of Al-Si alloys in an effective way. Over the last year, this novel grain refiner in the form of master alloy was developed and tested in various Al-Si cast alloys that are commonly used in industry. Significant grain refinement is obtained when the master alloy is added to the liquid metal prior to casting. Moreover, the grain size of the Al-Si cast alloys is observed to be less sensitive to cooling rate when the master alloy is added. In this work, the influence of addition of the master alloy on microstructural evolution of various Al-Si alloys cast under various cooling rates is presented.

Metals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1333 ◽  
Author(s):  
Wang Chang ◽  
Yanping Shen ◽  
Yueying Su ◽  
Long Zhao ◽  
Yunhu Zhang ◽  
...  

It has long been recognized that grain refinement of Mg-Al alloys is difficult, although various methods have been tried. In the present paper, a novel grain refiner, Al-3.4V-1B master alloy, has been developed to refine the as-cast AZ91 alloy. A comparative study on grain refinement effects of Al-3.4V-1B, Al-5V, and Al-3Ti-1B master alloys was performed under the same solidification conditions. It is shown that Al-3.4V-1B master alloy not only has significant grain refinement ability, but also keeps stable anti-fading capacity with holding time up to 2 h. Based on the analysis of grain refinement, VB2 particles introduced by Al-3.4V-1B master alloy are the heterogeneous nuclei for AZ91 alloy.


2015 ◽  
Vol 816 ◽  
pp. 459-464
Author(s):  
Guang Zong Wang ◽  
Da Quan Li ◽  
Qiang Zhu

In this paper the physical and chemical grain refining of the Mg-10Sm alloy was investigated. Physical grain refinement was achieved by strongly shearing the melt above the liquidus temperature using a twin-screw string device and then cast at the near liquidus temperature. Chemical grain refiner was added into Zr master alloy in the melt. Casting the Mg-10Sm alloy at 730°C produced an extremely coarse microstructure consisting of huge dendritic grains. The physical grain refinement greatly refined the dendritic grains to smaller rosette grains, being reduced from several millimeters to about 200μm. Chemical grain refinement produced fine and equiaxed grain structure with size of approximated 111μm. Combination of the physical and chemical grain refinement creates more significant refining effect than either of the two methods.


Author(s):  
Jiawei Yang ◽  
Sarina Bao ◽  
Shahid Akhtar ◽  
Yanjun Li

AbstractIn this work, a systematic study on the interactions between aluminum oxide films and TiB2 grain refiner particles and their effect on grain refinement behavior have been conducted. Oxide films were introduced into a commercial purity aluminum melt by adding AA 6061 alloy chips while the grain refiner particles were introduced by adding Al-3T-1B master alloy. Strong sedimentation of TiB2 grain refiner particles was observed in aluminum melt without chip addition during long-time settling. Most of the TiB2 particles were settled and accumulated at the bottom of crucible. In contrast, the sedimentation of TiB2 particles is much less in the melt with the addition of oxide films. A large fraction of TiB2 particles were found to be adhered to the oxide films located at the top part of the crucible, which inhibited the sedimentation of grain refiner particles. TP-1 type tests were also done to study the grain refinement efficiency of Al-3Ti-1B master alloy under different melt cleanliness and settling time. It is found that sedimentation of TiB2 particles greatly reduces the grain refinement efficiency. The introduction of oxide films seems to slightly alleviate the fading effect. This is owing to the strong adherence between the oxide films and TiB2 particles, which leads to a retardation of particle sedimentation.


2005 ◽  
Vol 488-489 ◽  
pp. 299-302 ◽  
Author(s):  
L. Lu ◽  
Arne K. Dahle ◽  
John A. Taylor ◽  
David H. StJohn

The fundamentals of grain refinement are reviewed with particular focus on magnesium alloys. This is followed by considerations of the theoretical and practical aspects of grain refinement of Mg-Al alloys by carbon-based grain refiners. Finally, experimental results using Al4C3 as a potential grain refiner are presented and discussed.


2000 ◽  
Vol 331-337 ◽  
pp. 391-396 ◽  
Author(s):  
Kenichi Yaguchi ◽  
Hiroyasu Tezuka ◽  
Tatsuo Sato ◽  
Akihiko Kamio

2012 ◽  
Vol 217-219 ◽  
pp. 377-381 ◽  
Author(s):  
Ying Long Li ◽  
Fu Rong Cao ◽  
Li Jin

The microstructural characters and refining property of Al-Ti-C grain refinement alloy prepared by ultrasound coupling method were studied by analytical means such as SEM, and the reaction synthesis mechanism of Al-Ti-C grain refinement was discussed. Experimental results show that the Al-Ti-C alloy refiner using “thermite reduction method” under high-energy ultrasound was prepared experimentally. Its microstructure character is that master alloy has smaller size of TiC, its quantities are larger and are dispersed. Melt reaction is generally that the source of titanium releases Ti atoms under high temperature of ultrasonic. Ti atoms react with aluminum to generate TiAl3, and react with carbon to generate TiC.


2015 ◽  
Vol 15 (2) ◽  
pp. 51-54 ◽  
Author(s):  
W.K. Krajewski ◽  
J. Buraś ◽  
P.K. Krajewski ◽  
G. Piwowarski

Abstract The paper presents results of measuring attenuation coefficient of the Al-20 wt.% Zn alloy (AlZn20) inoculated with different grain refiners. During experiments the melted alloys were doped with Al-Ti3-C0.15 refining master alloy. Basing on measurements performed by Krautkramer USLT2000 device with 1MHz ultrasound wave frequency it was stated that grain refinement reduces the attenuation coefficient by about 20-25%. However, the examined alloys can be still classified as the high-damping ones of attenuation greater than 150 dB/m.


2014 ◽  
Vol 574 ◽  
pp. 391-395
Author(s):  
Li Mi ◽  
Jun Jun Wang ◽  
Zhi Liu Hu

Al-Ti-B master alloy is the most widely used grain refiner in the aluminum fabrication industry, while it’s refinement mechanism is not clearly understand yet. The TiB2 in Al-Ti-B master alloy is one of important phase to grain refining, which intimately related to the generation of initial nucleus, the “fading” phenomenon of refining effect declines with the increase of holding or standing time in grain refining process. Besides, TiB2 is analyzed in several studies about the “poisoning” phenomenon, a large extent weaken of refining effect when Zr, Cr, Mn etc. exists. In this article, the impact of TiB2 to the refining effect of Al-Ti-B master alloy is discussed aiming at the roles and phenomenon mentions above.


2019 ◽  
Vol 54 (23) ◽  
pp. 14561-14576 ◽  
Author(s):  
J. Xu ◽  
Y. Li ◽  
B. Hu ◽  
Y. Jiang ◽  
Q. Li

2012 ◽  
Vol 538-541 ◽  
pp. 2264-2268 ◽  
Author(s):  
Yi Jie Zhang ◽  
Nai Heng Ma ◽  
Brian J. McKay ◽  
Xian Feng Li ◽  
Hao Wei Wang

The role of Fe on the grain refinement of high purity aluminium (HPAl) was investigated after adding commercial Al-5Ti-1B grain refiner rod. Experimental results show that with a 0.08% Fe addition, the grain structure at chill zone of the HPAl sample changes from coarse to fine equiaxed grains. More importantly, the grain size observed at the centre of the HPAl sample decreased from 500±50µm to 206±30µm. The improvement has been attributed to the interfacial segregation and solute concentration of the Fe at the solid-liquid interface.


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