Development and Investigation of High-Strength Neutron-Absorbing Composite Coatings Based on Borides of Metals

2019 ◽  
Vol 945 ◽  
pp. 660-664 ◽  
Author(s):  
A.S. Larionov ◽  
L.V. Chekushina ◽  
E.E. Suslov

At present, structural materials capable of absorbing thermal neutrons are used for long-term, compacted storage of spent nuclear fuel. This is necessary to prevent the occurrence of a fission reaction in clusters of nuclear materials. A promising direction in this area is the use of neutron-absorbing coatings. In this paper, it is proposed to use coatings of the B-Ti system for this purpose. The model calculations carried out using the MCU-REA program show the sufficient effectiveness of such coatings. The average path length of the neutron in the coating is ~ 90 μm. The dependence of the degree of attenuation of the neutron flux on the thickness of the coating is shown. Calculations show that the main role is played not by the thickness of the coating, but by the boron concentration in the material. For the synthesis of coatings, the method of magnetron sputtering is considered. Аn experimental magnetron boron-containing target for a four-channel magnetron installation VUP-5M was fabricated.

2000 ◽  
Vol 663 ◽  
Author(s):  
Allan Hedin ◽  
Ulrik Kautsky ◽  
Lena Morén ◽  
Jan-Olof Selroos ◽  
Patrik Sellin ◽  
...  

ABSTRACTIn preparation for coming site investigations for siting of a deep repository for spent nuclear fuel, the Swedish Nuclear Fuel and Waste Management Company, SKB has carried out the long- term safety assessment SR 97, requested by the Swedish Government. The repository is of the KBS-3 type, where the fuel is placed in isolating copper canisters with a high-strength cast iron insert. The canisters are surrounded by bentonite clay in individual deposition holes at a depth of 500 m in granitic bedrock. Geological data are taken from three sites in Sweden to shed light on different conditions in Swedish granitic bedrock.The future evolution of the repository system is analyzed in the form of five scenarios. The first is a base scenario where the repository is postulated to be built entirely according to specifications and where present-day conditions in the surroundings, including climate, persist. The four other scenarios show the evolution if the repository contains a few initially defective canisters, in the event of climate change, in the event of earthquakes, and in the event of future inadvertent human intrusion.The principal conclusion of the assessment is that the prospects of building a safe deep repository for spent nuclear fuel in Swedish granitic bedrock are very good. The results of the assessment also serve as a basis for formulating requirements and preferences regarding the bedrock in site investigations, for designing a program for site investigations, for formulating functional requirements on the repository's barriers, and for prioritization of research.


2009 ◽  
Vol 58 (6) ◽  
pp. 525-532 ◽  
Author(s):  
Yoshitaka NARA ◽  
Masafumi TAKADA ◽  
Daisuke MORI ◽  
Hitoshi OWADA ◽  
Tetsuro YONEDA ◽  
...  

Alloy Digest ◽  
2010 ◽  
Vol 59 (1) ◽  

Abstract Kubota KNC-03 is a grade with a combination of high strength and excellent resistance to oxidation. These properties make this alloy suitable for long-term service at temperature up to 1250 deg C (2282 deg F). This datasheet provides information on physical properties, hardness, elasticity, tensile properties, and compressive strength as well as creep. It also includes information on high temperature performance as well as casting and joining. Filing Code: Ni-676. Producer or source: Kubota Metal Corporation, Fahramet Division. See also Alloy Digest Ni-662, April 2008.


Alloy Digest ◽  
2020 ◽  
Vol 69 (8) ◽  

Abstract ATI 6-2-4-2 is a near-alpha, high strength, titanium alloy that exhibits a good combination of tensile strength, creep strength, toughness, and long-term stability at temperatures up to 425 °C (800 °F). Silicon up to 0.1% frequently is added to improve the creep resistance of the alloy. This datasheet provides information on composition, physical properties, hardness, and tensile properties as well as creep. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: Ti-169. Producer or Source: ATI.


2021 ◽  
Vol 7 (1) ◽  
pp. eabc5442
Author(s):  
Dianyu Dong ◽  
Caroline Tsao ◽  
Hsiang-Chieh Hung ◽  
Fanglian Yao ◽  
Chenjue Tang ◽  
...  

The high mechanical strength and long-term resistance to the fibrous capsule formation are two major challenges for implantable materials. Unfortunately, these two distinct properties do not come together and instead compromise each other. Here, we report a unique class of materials by integrating two weak zwitterionic hydrogels into an elastomer-like high-strength pure zwitterionic hydrogel via a “swelling” and “locking” mechanism. These zwitterionic-elastomeric-networked (ZEN) hydrogels are further shown to efficaciously resist the fibrous capsule formation upon implantation in mice for up to 1 year. Such materials with both high mechanical properties and long-term fibrous capsule resistance have never been achieved before. This work not only demonstrates a class of durable and fibrous capsule–resistant materials but also provides design principles for zwitterionic elastomeric hydrogels.


2020 ◽  
Vol 5 (1) ◽  
pp. 18
Author(s):  
Simon Evertz ◽  
Stephan Prünte ◽  
Lena Patterer ◽  
Amalraj Marshal ◽  
Damian M. Holzapfel ◽  
...  

Due to their unique property combination of high strength and toughness, metallic glasses are promising materials for structural applications. As the behaviour of metallic glasses depends on the electronic structure which in turn is defined by chemical composition, we systematically investigate the influence of B concentration on glass transition, topology, magnetism, and bonding for B concentrations x = 2 to 92 at.% in the (Co6.8±3.9Ta)100−xBx system. From an electronic structure and coordination point of view, the B concentration range is divided into three regions: Below 39 ± 5 at.% B, the material is a metallic glass due to the dominance of metallic bonds. Above 69 ± 6 at.%, the presence of an icosahedra-like B network is observed. As the B concentration is increased above 39 ± 5 at.%, the B network evolves while the metallic coordination of the material decreases until the B concentration of 67 ± 5 at.% is reached. Hence, a composite is formed. It is evident that, based on the B concentration, the ratio of metallic bonding to icosahedral bonding in the composite can be controlled. It is proposed that, by tuning the coordination in the composite region, glassy materials with defined plasticity and processability can be designed.


2004 ◽  
Vol 50 (8) ◽  
pp. 65-72 ◽  
Author(s):  
Y.Q. Zhao ◽  
G. Sun ◽  
C. Lafferty ◽  
S.J. Allen

A gravel-based tidal flow reed bed system was operated with three different strategies in order to investigate its optimal performance for the treatment of a high strength agricultural wastewater. According to the three strategies, individual reed beds were saturated and unsaturated with the wastewater for different periods while reasonably stable hydraulic and organic loadings were maintained. Experimental results demonstrated that the system produced the highest pollutant removal efficiencies with a relatively short saturated period and long unsaturated period, highlighting the importance of oxygen transfer into reed bed matrices during the treatment. Significant removals of some major organic and inorganic pollutants were achieved under all three operational conditions. Nitrification was not the major route of ammoniacal-nitrogen removal when the system was under high organic loading. Due to the filtration of suspended solids and the accumulation of biomass, gradual clogging of the reed bed matrices took place, which caused concerns over the long-term efficiency of the tidal flow system.


2002 ◽  
Vol 713 ◽  
Author(s):  
Allan Hedin ◽  
Ulrik Kautsky ◽  
Lena Morén ◽  
Patrik Sellin ◽  
Jan-Olof Selroos

ABSTRACTIn preparation for coming site investigations for siting of a deep repository for spent nuclear fuel, the Swedish Nuclear Fuel and Waste Management Company, SKB has carried out the longterm safety assessment SR 97, requested by the Swedish Government. The repository is of the KBS-3 type, where the fuel is placed in isolating copper canisters with a high-strength cast iron insert. The canisters are surrounded by bentonite clay in individual deposition holes at a depth of 500 m in granitic bedrock. Geological data are taken from three sites in Sweden to shed light on different conditions in Swedish granitic bedrock.The future evolution of the repository system is analysed in the form of five scenarios. The first is a base scenario where the repository is postulated to be built entirely according to specifications and where present-day conditions in the surroundings, including climate, persist. The four other scenarios show the evolution if the repository contains a few initially defective canisters, in the event of climate change, in the event of earthquakes, and in the event of future inadvertent human intrusion.The principal conclusion of the assessment is that the prospects of building a safe deep repository for spent nuclear fuel in Swedish granitic bedrock are very good. The results of the assessment also serve as a basis for formulating requirements and preferences regarding the bedrock in site investigations, for designing a programme for site investigations, for formulating functional requirements on the repository's barriers, and for prioritisation of research.SR 97 has been reviewed both by an international group of OECD/NEA experts and by Swedish authorities. The NEA reviewers concluded that “SR 97 provides a sensible illustration of the potential safety of the KBS-3 concept”, and no issues were identified that need to be resolved prior to proceeding to the investigation of potential sites. The authorities' conclusions were in principal consistent with those of the NEA.Uncertainties and lack of knowledge in different areas identified in SR 97 have strongly influenced the contents and structure of SKBs most recent research programme, RD&DProgramme 2001.Since SR 97, the methodology for probabilistic consequence analyses have been further developed. Analytic approximations to the numerical transport models used in SR 97 have been developed. The new models have been used to extend the probabilistic calculations in SR 97.


Author(s):  
Kazuhiro Kimura ◽  
Kota Sawada ◽  
Kiyoshi Kubo ◽  
Hideaki Kushima

Influence of stress on creep deformation and degradation behavior has been investigated. Corresponding to inflection of stress vs. time to rupture curve, difference in recovery phenomena, that was homogeneous in short-term and inhomogeneous in long-term, was observed. Inflection of stress vs. time to rupture curve took place at the stress condition corresponding to half of 0.2% offset yield stress at the temperature. Elastic limit stress of Grade 91 steel was evaluated to be 150MPa at 600°C and 100MPa at 650°C, by means of stress abrupt change test. These stresses were found to be almost the same as half of 0.2% offset yield stress at the temperatures. Inflection of stress vs. time to rupture curve is caused by transient of applied stress from higher level than elastic limit to within elastic range. It has been concluded that long-term creep strength of ferritic creep resistant steels should be predicted from the selected creep rupture data under the stresses lower than elastic limit by considering half of 0.2% offset yield stress at the temperature, by means of Larson-Miller parameter with a constant of 20.


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