Reliability of Manganese Dioxide and Conductive Polymer Tantalum Capacitors under Temperature Humidity Bias Testing

2015 ◽  
Vol 2015 (1) ◽  
pp. 000713-000719 ◽  
Author(s):  
Anto Peter ◽  
Michael H. Azarian ◽  
Michael Pecht
Keyword(s):  
Manganese Dioxide ◽  
Room Temperature ◽  
Failure Mechanisms ◽  
Conductive Polymer ◽  
Operating Conditions ◽  
Leakage Currents ◽  
Test Population ◽  
Polymer Electrodes ◽  
Surge Current

Despite being highly reliable under steady state operating conditions, manganese dioxide (MnO2) tantalum capacitors are prone to catastrophic exothermic failures under surge current conditions. Such failures can be mitigated by the use of conductive polymers in place of MnO2. However, these polymers are more susceptible to failure at elevated humidity levels. In this paper, the electrical performances of both MnO2 and polymer tantalum capacitors are compared by subjecting them to temperature humidity bias testing at 85°C and 85% RH. The test population consists of tantalum capacitors with two voltage ratings (50V and 16V). At each of these voltage ratings, two sets of tantalum capacitors, one each with MnO2 and conductive polymer electrodes, were tested. The voltage levels used to bias the capacitors were periodically increased in multiples of the rated voltage to accelerate degradation. The performance of the capacitors was tracked by monitoring their capacitance, dissipation factors and leakage currents, both in-situ and at room temperature. The degradation trends are discussed in light of the differences in voltage ratings and electrode types. These trends are also mapped to fundamental failure mechanisms within the capacitors.

Interference-Fit Joining of Aluminium Tubes by Electromagnetic Forming

2013 ◽  
Vol 853 ◽  
pp. 488-493 ◽  
Author(s):  
M. Geier ◽  
M.M. José ◽  
R. Rossi ◽  
P.A.R. Rosa ◽  
P.A.F. Martins
Keyword(s):  
Room Temperature ◽  
New Technologies ◽  
Failure Mechanisms ◽  
Dissimilar Materials ◽  
Polymeric Materials ◽  
Operating Conditions ◽  
Electromagnetic Forming ◽  
Interference Fit ◽  
Structural Adhesives ◽  
New Applications

Interference-fit joining of tubes by electromagnetic forming is an innovative and environmental friendly technology that can successfully replace conventional joining technologies based on fasteners, structural adhesives, welding and brazing. The technology works at room temperature, allows joining dissimilar materials and offers potential to foster new applications in the assembly of lightweight tubular frame structures. As with all new technologies, there is a need to understand interference-fit joining of tubes by electromagnetic forming in terms of its major parameters with the aim of identifying their influence on the overall strength of the joints and establishing the useful range of process operating conditions. This article investigates the interference-fit joining of aluminum-alloy tubes (AA6082-O) with mandrels made from different metallic and polymeric materials (AA6082-O, AISI1045 and Erlaton 6SA). Results show that the strength of the joint and the associated failure mechanisms are directly related to process parameters and materials.

Cathodoluminescence of Catalyst Crystallites

1982 ◽  
Vol 40 ◽  
pp. 664-665
Author(s):  
E.D. Boyes ◽  
P.L. Gai ◽  
D.B. Darby ◽  
C. Warwick
Keyword(s):  
Defect Density ◽  
Chemical Properties ◽  
Operating Conditions ◽  
Semiconductor Materials ◽  
Environmental Cell ◽  
High Resolution Structure ◽  
Commercially Important ◽  
Crystallographic Defects ◽  
Resolution Structure

The extended crystallographic defects introduced into some oxide catalysts under operating conditions may be a consequence and accommodation of the changes produced by the catalytic activity, rather than always being the origin of the reactivity. Operation without such defects has been established for the commercially important tellurium molybdate system. in addition it is clear that the point defect density and the electronic structure can both have a significant influence on the chemical properties and hence on the effectiveness (activity and selectivity) of the material as a catalyst. SEM/probe techniques more commonly applied to semiconductor materials, have been investigated to supplement the information obtained from in-situ environmental cell HVEM, ultra-high resolution structure imaging and more conventional AEM and EPMA chemical microanalysis.

Otoconia perfect/imperfect crystals

1994 ◽  
Vol 52 ◽  
pp. 42-43
Author(s):  
César D. Fermin ◽  
Dale Martin
Keyword(s):  
Image Processing ◽  
Room Temperature ◽  
Phosphotungstic Acid ◽  
Gallus Domesticus ◽  
Crystal Matrix ◽  
Organic Templates ◽  
Image Processing Algorithms ◽  
Processing Algorithms ◽  
Diffraction Patterns

Otoconia of higher vertebrates are interesting biological crystals that display the diffraction patterns of perfect crystals (e.g., calcite for birds and mammal) when intact, but fail to produce a regular crystallographic pattern when fixed. Image processing of the fixed crystal matrix, which resembles the organic templates of teeth and bone, failed to clarify a paradox of biomineralization described by Mann. Recently, we suggested that inner ear otoconia crystals contain growth plates that run in different directions, and that the arrangement of the plates may contribute to the turning angles seen at the hexagonal faces of the crystals.Using image processing algorithms described earlier, and Fourier Transform function (2FFT) of BioScan Optimas®, we evaluated the patterns in the packing of the otoconia fibrils of newly hatched chicks (Gallus domesticus) inner ears. Animals were fixed in situ by perfusion of 1% phosphotungstic acid (PTA) at room temperature through the left ventricle, after intraperitoneal Nembutal (35mg/Kg) deep anesthesia. Negatives were made with a Hitachi H-7100 TEM at 50K-400K magnifications. The negatives were then placed on a light box, where images were filtered and transferred to a 35 mm camera as described.

In Situ Localization of PPAR Gamma and Uncoupling Protein in Mouse Embryo Sections Using Digoxigenin-Labeled Riboprobes

1996 ◽  
Vol 54 ◽  
pp. 32-33
Author(s):  
C. Jennermann ◽  
S. A. Kliewer ◽  
D. C. Morris
Keyword(s):  
Alkaline Phosphatase ◽  
Room Temperature ◽  
Uncoupling Protein ◽  
Ppar Gamma ◽  
Nuclear Hormone Receptor ◽  
Full Length ◽  
Northern Analysis ◽  
Peroxisome Proliferator

Peroxisome proliferator-activated receptor gamma (PPARg) is a member of the nuclear hormone receptor superfamily and has been shown in vitro to regulate genes involved in lipid metabolism and adipocyte differentiation. By Northern analysis, we and other researchers have shown that expression of this receptor predominates in adipose tissue in adult mice, and appears first in whole-embryo mRNA at 13.5 days postconception. In situ hybridization was used to find out in which developing tissues PPARg is specifically expressed.Digoxigenin-labeled riboprobes were generated using the Genius™ 4 RNA Labeling Kit from Boehringer Mannheim. Full length PPAR gamma, obtained by PCR from mouse liver cDNA, was inserted into pBluescript SK and used as template for the transcription reaction. Probes of average size 200 base pairs were made by partial alkaline hydrolysis of the full length transcripts. The in situ hybridization assays were performed as described previously with some modifications. Frozen sections (10 μm thick) of day 18 mouse embryos were cut, fixed with 4% paraformaldehyde and acetylated with 0.25% acetic anhydride in 1.0M triethanolamine buffer. The sections were incubated for 2 hours at room temperature in pre-hybridization buffer, and were then hybridized with a probe concentration of 200μg per ml at 70° C, overnight in a humidified chamber. Following stringent washes in SSC buffers, the immunological detection steps were performed at room temperature. The alkaline phosphatase labeled, anti-digoxigenin antibody and detection buffers were purchased from Boehringer Mannheim. The sections were treated with a blocking buffer for one hour and incubated with antibody solution at a 1:5000 dilution for 2 hours, both at room temperature. Colored precipitate was formed by exposure to the alkaline phosphatase substrate nitrobluetetrazoliumchloride/ bromo-chloroindlylphosphate.

Single Crystal Growth of High-Pressure Phases of Ice and Salt Hydrate Far Below the Original Melting Point by Mixing Alcohol: Crystal Structure Determination of Magnesium Chloride Heptahydrate

2020 ◽  
Author(s):  
Keishiro Yamashita ◽  
Kazuki Komatsu ◽  
Hiroyuki Kagi
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Crystal Growth ◽  
Single Crystal ◽  
Room Temperature ◽  
Growth Technique ◽  
Salt Hydrate ◽  
X Ray

An crystal-growth technique for single crystal x-ray structure analysis of high-pressure forms of hydrogen-bonded crystals is proposed. We used alcohol mixture (methanol: ethanol = 4:1 in volumetric ratio), which is a widely used pressure transmitting medium, inhibiting the nucleation and growth of unwanted crystals. In this paper, two kinds of single crystals which have not been obtained using a conventional experimental technique were obtained using this technique: ice VI at 1.99 GPa and MgCl<sub>2</sub>·7H<sub>2</sub>O at 2.50 GPa at room temperature. Here we first report the crystal structure of MgCl2·7H2O. This technique simultaneously meets the requirement of hydrostaticity for high-pressure experiments and has feasibility for further in-situ measurements.

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