Spatial variability of trace metals in Podzols of northern forest ecosystems: Sampling implications

2003 ◽  
Vol 83 (5) ◽  
pp. 581-587 ◽  
Author(s):  
J. D. MacDonald ◽  
W. H. Hendershot
Keyword(s):  
Trace Metals ◽  
Spatial Variability ◽  
Point Source ◽  
Forest Ecosystems ◽  
Physical Factors ◽  
Individual Plant ◽  
Forest Site ◽  
Organic Carbon Content ◽  
Metal Concentrations ◽  
Northern Forest

The concentrations of metals in soils are spatially heterogeneous and soil sampling carried out when studying metals in forest ecosystems is often inadequate. We examined the spatial variability of Cd, Cu, Mn, Ni, Pb and Zn in northern forest ecosystems on a transect with distance from two point source emitters with the goal of providing basic information about the distribution and variability of metals in these soils. Samples were taken under six sampling points at four depths from three experimental sites on each of the two transects. Soils were analysed for acid digestible metals, pH and organic carbon content. Standard deviation, coefficients of variation, mean and medians were analysed for each horizon of each site. It was observed that Cu and Mn variability is higher in closer proximity to the point source while the variability of Zn increased with decreasing soil pH. In Sudbury, emitted metals Ni and Cu accumulate together in soils, whereas in Rouyn-Noranda, with the exception of Cd and Zn, metal concentrations were not related in forest floors. Observations suggest that physical factors influencing where metals are deposited as well as the inherent variability in soil chemical characteristics, and the distance from the point source can all act together to result in high variability in soil metal concentrations in a single forest site. Sampling in the interest of relating vegetation metal concentrations or response to soil metals should be carried out on an individual plant basis with multiple samples taken for each individual. Soil samples taken at intervals of 1 to 1.7 m will provide relative error in estimating soil concentrations of 10% or 20%, respectively. Key words: Spatial variability, trace metals, podzolic soils, smelter emissions

A Comparison of PCB Congener Distributions in Two Point-Source Contaminated Lakes and One Uncontaminated Lake in Ontario

1989 ◽  
Vol 24 (1) ◽  
pp. 23-46 ◽  
Author(s):  
C. R. Macdonald ◽  
C. D. Metcalfe
Keyword(s):  
Point Source ◽  
Yellow Perch ◽  
Water Solubility ◽  
Smallmouth Bass ◽  
Physical Factors ◽  
Organic Carbon Content ◽  
Substitution Pattern ◽  
Significant Difference ◽  
The Individual ◽  
High Organic Carbon Content

Abstract PCB congener accumulation in biota and sediments involves several processes, including physical factors characterized by octanol-water partition coefficients and water solubility, and chemical factors which are influenced by the degree of chlorination and the substitution pattern of the individual congeners. The present study was conducted to determine if PCB congeners are distributed in a consistent pattern in two lakes known to have received point-source contamination with PCBs, and a control lake with no known point source. Samples of 4 groups of biota, water and sediment indicated that each lake had a unique pattern of congener distribution which was probably related to the source of the contamination. A comparison of total and individual PCB congener concentrations within each study lake showed that no one species consistently contained the highest residues of PCBs. Smallmouth bass had the highest concentration of PCBs in Rice lake while yellow perch was highest in Lakes Clear and Scugog. Sediments contained lower concentrations of PCBs than biota and did not show enrichment of higher chlorinated congeners, despite having high organic carbon content. Within the contaminated lakes, young-of-the-year (YOY) and older yellow perch had the same congener pattern, and there was no significant difference in their PCB concentration. This indicates that equilibrium concentrations of PCBs are established rapidly in the young fish and that all congeners equilibrate at the same rate.

Incorporation of spatial variability in modeling non-point source groundwater nitrate pollution

1996 ◽  
Vol 33 (4-5) ◽  
pp. 233-240 ◽  
Author(s):  
F. S. Goderya ◽  
M. F. Dahab ◽  
W. E. Woldt ◽  
I. Bogardi
Keyword(s):  
Spatial Variability ◽  
Point Source ◽  
Three Dimensional ◽  
Nitrate Contamination ◽  
Geostatistical Simulation ◽  
Chemical Measurements ◽  
Spatially Distributed ◽  
Potential Benefits ◽  
Zone Modeling ◽  
Physical And Chemical

A methodology for incorporation of spatial variability in modeling non-point source groundwater nitrate contamination is presented. The methodology combines geostatistical simulation and unsaturated zone modeling for estimating the amount of nitrate loading to groundwater. Three dimensional soil nitrogen variability and 2-dimensional crop yield variability are used in quantifying potential benefits of spatially distributed nitrogen input. This technique, in combination with physical and chemical measurements, is utilized as a means of illustrating how the spatial statistical properties of nitrate leaching can be obtained for different scenarios of fixed and variable rate nitrogen applications.

scholarly journals Significance of building and plumbing specifics on trace metal concentrations in drinking water

1991 ◽  
Vol 18 (6) ◽  
pp. 893-903 ◽  
Author(s):  
Inderjit Singh ◽  
Donald S. Mavinic
Keyword(s):  
Drinking Water ◽  
Trace Metals ◽  
Trace Metal ◽  
Water Samples ◽  
First Flush ◽  
Single Family ◽  
Metal Concentrations ◽  
Building Height ◽  
High Rise ◽  
Family House

Samples were taken from 72 high-rise apartment suites (6 suites in 12 individual high-rise towers) and 60 single-family houses located within the Greater Vancouver Regional District. The influence of the following factors on trace metal concentrations in 1-L first-flush drinking water samples and “running” hot water samples was investigated: building height, location, plumbing age, type of plumbing, and type of building. Results of this survey show that with the exception of building height, all factors had a correlation with one or more of the trace metals investigated. The trace metals examined were lead, copper, iron, and zinc. Lead was influenced primarily by building type, copper by plumbing age and type of plumbing, and iron by location. Elevated lead levels were associated with high-rise samples. New copper plumbing systems resulted in high copper levels. Highest iron levels in the drinking water were measured in the East Vancouver location. Zinc did not show a distinct correlation with any of the factors investigated. Brass faucets were the primary source of zinc in tap water. They also contributed substantially to the lead detected in the 1-L first-flush sample. Metal concentrations measured in the high-rise and house samples were compared with the U.S. Environmental Protection Agency's (USEPA) maximum contaminant levels (MCLs) and the proposed “no-action” level for lead. In high-rise samples, the 0.01 mg/L “no-action” level proposed for lead was exceeded in 43% of the samples, and 62% of the samples exceeded the current 1.0 mg/L MCL standard for copper. In single-family house samples, these values were 47% and 73%, respectively. The average lead concentrations were 0.020 mg/L for all high-rise samples and 0.013 mg/L for house samples. Regulatory levels stated above would still be exceeded in 6% of the cases for lead and 9% of the cases for copper, even after prolonged flushing of the tap in a high-rise building. In all cases associated with single-family houses, flushing the cold water tap for 5 minutes was successful in achieving compliance levels. Key words: aggressive water, compliance, corrosive, drinking water, first-flush, GVRD, high-rise, single-family house, trace metals, USEPA.

Insect Defoliators as Periodic Disturbances in Northern Forest Ecosystems

2007 ◽  
pp. 487-525 ◽  
Author(s):  
Barry J. Cooke ◽  
Vincent G. Nealis ◽  
Jacques Régnière
Keyword(s):  
Forest Ecosystems ◽  
Northern Forest ◽  
Periodic Disturbances

scholarly journals Atmospheric trace metals measured at a regional background site (Welgegund) in South Africa

2017 ◽  
Vol 17 (6) ◽  
pp. 4251-4263 ◽  
Author(s):  
Andrew D. Venter ◽  
Pieter G. van Zyl ◽  
Johan P. Beukes ◽  
Micky Josipovic ◽  
Johan Hendriks ◽  
...  
Keyword(s):  
South Africa ◽  
Trace Metals ◽  
Trace Metal ◽  
Size Fraction ◽  
Abundant Species ◽  
Metal Species ◽  
Metal Concentrations ◽  
Igneous Complex ◽  
Size Fractions ◽  
Bushveld Igneous Complex

Abstract. Atmospheric trace metals can cause a variety of health-related and environmental problems. Only a few studies on atmospheric trace metal concentrations have been conducted in South Africa. Therefore the aim of this study was to determine trace metal concentrations in aerosols collected at a regional background site, i.e. Welgegund, South Africa. PM1, PM1–2. 5 and PM2. 5–10 samples were collected for 13 months, and 31 atmospheric trace metal species were detected. Atmospheric iron (Fe) had the highest concentrations in all three size fractions, while calcium (Ca) was the second-most-abundant species. Chromium (Cr) and sodium (Na) concentrations were the third- and fourth-most-abundant species, respectively. The concentrations of the trace metal species in all three size ranges were similar, with the exception of Fe, which had higher concentrations in the PM1 size fraction. With the exception of titanium (Ti), aluminium (Al) and manganese (Mg), 70 % or more of the trace metal species detected were in the smaller size fractions, which indicated the influence of industrial activities. However, the large influence of wind-blown dust was reflected by 30 % or more of trace metals being present in the PM2. 5–10 size fraction. Comparison of trace metals determined at Welgegund to those in the western Bushveld Igneous Complex indicated that at both locations similar species were observed, with Fe being the most abundant. However, concentrations of these trace metal species were significantly higher in the western Bushveld Igneous Complex. Fe concentrations at the Vaal Triangle were similar to levels thereof at Welgegund, while concentrations of species associated with pyrometallurgical smelting were lower. Annual average Ni was 4 times higher, and annual average As was marginally higher than their respective European standard values, which could be attributed to regional influence of pyrometallurgical industries in the western Bushveld Igneous Complex. All three size fractions indicated elevated trace metal concentrations coinciding with the end of the dry season, which could partially be attributed to decreased wet removal and increases in wind generation of particulates. Principal component factor analysis (PCFA) revealed four meaningful factors in the PM1 size fraction, i.e. crustal, pyrometallurgical-related and Au slimes dams. No meaningful factors were determined for the PM1–2. 5 and PM2. 5–10 size fractions, which was attributed to the large influence of wind-blown dust on atmospheric trace metals determined at Welgegund. Pollution roses confirmed the influence of wind-blown dust on trace metal concentrations measured at Welgegund, while the impact of industrial activities was also substantiated.

scholarly journals Vitality Structure of the Populations of Vegetative Motile Plants of Forest Ecosystems of the North-East of Ukraine

2019 ◽  
Vol 13 (1) ◽  
pp. 125-132
Author(s):  
Kovalenko Ihor ◽  
Skliar Iurii ◽  
Klymenko Hanna ◽  
Kovalenko Nataliia
Keyword(s):  
Quality Index ◽  
Forest Ecosystems ◽  
Morphological Structure ◽  
Field Studies ◽  
Complete Analysis ◽  
Individual Plant ◽  
North East ◽  
The North ◽  
Motile Species ◽  
Two Populations

Background: The vitality level of the populations has turned out to be statistically reliably associated with such coenotic factors: age and density of forest stand. In general, the vitality spectra vary widely: the quality index Q of the populations ranges from 0,00 to 0,50, that is, it fully covers the theoretically possible scale of the values of this coefficient, which indicates the sensitivity of the vitality structure of the populations to the ecological-coenotic conditions and determines high informative value of the vitality analysis. Objective: The aim of the study is to assess the vitality structure of the populations of vegetative motile plant species – typical representatives of the grassy layer of forest ecosystems of the North-East of Ukraine as a factor that determines their stability and dynamics. Methods: The analysis of the vitality structure is based on the field studies of the populations of 4 vegetative motile species of plants – Aegopodium podagraria L., Asarum europaeum L., Carex pilosa Scop. and Stellaria holostea L. in forest ecosystems of the North-East of Ukraine. Vitality analysis was carried out according to Yu. A. Zlobin’s methodology. Vitality analysis procedure, classically, is carried out in three stages: 1) Selection of quantitative features that characterize the vital status of the individual plant; 2) Evaluation of vitality of individual plants that were included in the sample; 3) Integral assessment of the population’s vitality. Depending on the ratio in the population of plants of classes a, b and c, the population belongs to one of three vitality types: prosperous, equilibrium or depressive. Results: The obtained estimates of the vitality structure of populations of the clone-forming plants in the grass-shrub layer of forests of the North-East of Ukraine can be considered quite reliable, because they are based, in general, on a complete analysis of the morphological structure of about 13 thousand ramets of the studied species of plants. The statistical reliability of estimates of the population’s vitality structure is predominantly between 70 and 99% and only in some cases lower than 70%. As the clone grows older, its ramet’s vitality decreases and the clone degrades. New young clones, that start to form on the basis of genets, replace old ones. Such ramets have increased vitality, greater stress and competitive resistance. Due to the mechanisms of clone substitution in the living cover, the dominance of nemoralis herbs persists for a long time. Conclusion: The vitality spectra of the populations of the studied species of plants vary widely: the quality index Q of the populations ranges from 0,00 to 0,50, that is, it covers full theoretically possible scale of the values of this coefficient, which indicates the sensitivity of the vitality structure of the populations to the ecological-coenotic conditions and determines high informative value of vitality analysis. Prosperous populations: two populations A. europaeum of the associations Quercetum (roboris) coryloso (avellanae) – convallariosum (majalis) and Quercetum (roboris) coryloso (avellanae) – convallariosum (majalis), two populations A. podagraria of the associations – Pinetum (sylvestris) vacciniosum (myrtilli) and Querceto (roboris) – Pinetum (sylvestris) convallarioso (majalis) – vacciniosum (myrtilli), one population S. holostea of the association Querceto (roboris) – Pinetum (sylvestris) vacciniosum (myrtilli) and one population C. pilosa of the association Querceto (roboris) – Pinetum (sylvestris) vaccinioso (myrtilli) – convallariosum (majalis).

scholarly journals Resources of dead wood in the municipal forests in Warsaw

2015 ◽  
Vol 76 (4) ◽  
pp. 322-330 ◽  
Author(s):  
Konrad Skwarek ◽  
Szymon Bijak
Keyword(s):  
National Parks ◽  
Coarse Woody Debris ◽  
Forest Ecosystems ◽  
Dead Wood ◽  
Woody Debris ◽  
Forest Site ◽  
Natural Forests ◽  
Dead Trees ◽  
Standing Dead ◽  
High Degree

Abstract Dead wood plays an important role for the biodiversity of forest ecosystems and influences their proper development. This study assessed the amount of coarse woody debris in municipal forests in Warsaw (central Poland). Based on the forest site type, dominant tree species and age class, we stratified all complexes of the Warsaw urban forests in order to allocate 55 sample plots. For these plots, we determined the volume of dead wood including standing dead trees, coarse woody debris and broken branches as well as uprooted trees. We calculated the amount of dead wood in the distinguished site-species-age layers and for individual complexes. The volume of dead matter in municipal forests in Warsaw amounted to 38,761 m3, i.e. 13.7 m3/ha. The obtained results correspond to the current regulations concerning the amount of dead organic matter to be left in forests. Only in the Las Bielański complex (northern Warsaw) volume of dead wood is comparable to the level observed in Polish national parks or nature reserves, which is still far lower than the values found for natural forests. In general, municipal forests in Warsaw stand out positively in terms of dead wood quantity and a high degree of variation in the forms and dimensions of dead wood.

Sign in / Sign up

Export Citation Format

Share Document