scholarly journals Assessment of health risks from consumption of food crops fumigated with metal based pesticides in Gwadam, Gombe State, Nigeria

2021 ◽  
Vol 14 (1) ◽  
pp. 100-110
Author(s):  
U. Bawa ◽  
A. Ahmad ◽  
J.N. Ahmad ◽  
A.G. Ezra

Intensive use of agrochemicals has led to build of heavy metals in the soil ecosystem and their transfer to edible parts of crops. This study was aimed to determine the heavy metals (Cd, Pb, Cr, Cu and Zn) concentrations in some twenty commonly used pesticides in northern Nigeria, and health risk associated from the consumption of food crops fumigated with these pesticides as the only source of metal contamination. Heavy metals content in pesticides, food crops and soils were analyzed after acid digestion using atomic absorption spectrometry. Traces of heavy metals (Cd, Pb, Cr, Cu and Zn) were detected in most of the pesticides. The concentrations of heavy metals in crops fumigated with pesticides ranged from 0.33-4.68, 1.75-38.08, 0.67-16.83, 9.01-436.75, 0.17-20.80mg/kg for Cd, Pb, Cr, Cu, and Zn respectively. The mean concentrations of Cd, Pb, and Cr in all the crops were above WHO, (2019) permissible limit. Heavy metals in soils of corresponding crops were below the permissible limits by UNEP, (2013) and NESREA, (2011). Bioaccumulation factor BAF showed high BAF>1 for Cu and Pb in all the studied crops,while pollution index value revealed contamination for Cd and Pb in all the studied crops. Hazard quotient showed potential health risk from the consumption of only Capsicumannuum for Pb. However, consumers may experience advance health risk through the consumption of Oryza sativa, Zea mays, Solanumlycopersicum, Capsicumfrustescens for all metals (Hazard index). Hence, there is the need for screening of heavy metals in pesticides and monitoring of metals contents in food crops.

2019 ◽  
Vol 48 (4) ◽  
pp. 337-354 ◽  
Author(s):  
Mohamed E.M. Hassouna ◽  
Mohamed E. Goher ◽  
Seliem M. El-Sayed ◽  
Reda A.A.A. Hassan

Abstract The Bahr Yusuf Canal is the life artery of the Fayoum Province, which provides the province with two thirds of the freshwater quota from the Nile River. The present work was carried out to assess the suitability of water in the Bahr Yusuf Canal for various purposes and to assess the potential health risk associated with metal content. The results showed that the water quality of Bahr Yusuf was classified as poor and very poor for recreational use according to the Oregon WQI. On the other hand, the Aquatic Toxicity Index indicated the suitability of water for all fish species. The Canadian WQI and the Weighted Arithmetic WQI classified the canal water as good (WQI = 92), fair (WQI = 73) & marginal (WQI = 64) and excellent, poor to good & good to excellent for irrigation, drinking and aquatic life, respectively. Despite the significant contamination of water with heavy metals (as indicated by the Heavy Pollution Index, ranging from 104.44 to 206.32, from 16.81 to 38.48 and from 219.07 to 472.24 μg l−1), the Hazard Quotient (HQ) and the Hazard Index (HI) data indicate that water of Bahr Yusuf does not pose a human health risk through ingestion or dermal contact. In general, the study showed that water in the Bahr Yusuf Canal is characterized by different levels of pollution, which requires rapid and critical intervention by responsible authorities to prevent the discharge of different types of waste and further deterioration of the water quality during the lifetime of the channel and its subsequent rehabilitation.


2021 ◽  
Vol 14 (1) ◽  
pp. 130-141
Author(s):  
U. Bawa ◽  
A. Ahmad ◽  
J.N. Ahmad ◽  
A. G. Ezra

Heavy metals bioaccumulation in agricultural crops fumigated with pesticides has growninto a major concern globally. This study assessed heavy metals concentrations (Cd, Pb, Cr, Cu, Zn) in commonly consumed crops and their corresponding soil from agricultural farm lands in Jos Plateau State, Nigeria. The mean concentrations of heavy metals in the studied crops ranged from 0.17-100.75, 0.17-54.33, 0.83-28.75, 0.17-5.50, 0.5-0.5mg/kg for Zn, Pb, Cu, Cr, and Cd respectively. The trend of heavy metals in the crops were in decreasing order of Zn>Pb>Cu>Cr>Cd and their concentrations varied in different parts of the crops. The mean concentration of Cd, Pb, and Cr in the studiedcrops were above the WHO, (2019) permissible limits and therefore a call for concern. The mean concentrations of heavy metals in the soil varied from 0.5-0.5, 2.50-13.83, 3.67-5.75, 11.83-26.33, and 41-89.50 mg/kg for Cd, Pb, Cr, Cu and Zn respectively and were below the UNEP, (2013) permissible limits for agricultural soil. The result showed that Pb had the highest transfer factor (1.91) in (Capsicum annuum) and Zn had theleast. Similarly, the result revealed high Pollution index value for Pb compared to other metals. Hazard quotient and Hazard index of all the crops were less than 1; thus the consumption of these crops is unlikely to pose health risks to the target population. However, the result showed health risk from daily intake of some of the studied crops for Pb ((Brassica oleracea, Lactucasativus, Zea mays, Spinaciaoleracea, and Capsicum annuum). Hence, regular monitoring and screening of pesticides for heavy metals should be employed by government agencies.


2020 ◽  
Vol 15 (3) ◽  
pp. 56-63
Author(s):  
L.U Usman ◽  
R. Yerima

Ingestion of vegetables containing heavy metal is one of the main ways in which these elements enter the human body. Once entered, heavy metals are deposited in bone and fat tissues, overlapping noble minerals. Slowly released into the body, heavy metals can cause an array of diseases. This study aimed to assess the heavy metals residues in some vegetables and potential health risk among consumers within Katsina Metropolis. Six different vegetable samples comprising of cucumber (Cucumis sativus), cabbage (Brassica oleracea), lettuce (Lactuca sativa), spinach (Spinacia oleracea), red pepper (Piper nigrum) and tomato (Lycopersicum esculentus) were randomly collected from two main irrigation farmland located in Katsina Metropolis (Kofar sauri and Kofar marusa). Their level of toxic metals namely (Copper, Zinc, Cadmium, Chromium and Lead) were assessed using standard materials and methods. Results obtained were used to estimate the health risk of these heavy metals via consumption of the vegetable samples. The results from the study showed that the mean heavy metal concentration ranged between 1.10±0.00 mg/kg to 4.45±0.16 mg/kg, 1.78±0.07 mg/kg to 4.9±0.11 mg/kg, 0.02±0.00 mg/kg to 1.28±0.02 mg/kg, 1.51±0.02 mg/kg to 4.34±0.02 mg/kg and 1.05±0.01 mg/kg to 2.86±0.02 mg/kg for Cu, Zn, Cd, Cr, and Pb respectively. The concentration of Cu and Zn were found to be below permissible limit while Cd, Cr and Pb concentration exceeded the permissible limit recommended by WHO/FAO. Health risks associated with the intake of these metals were evaluated in terms of estimated daily intake (EDI), hazard quotient (HQ) and hazard index (HI). EDI value of Cu and Zn were found to be below the maximum tolerable daily intake (MTDI). The HQ of all the metals were >1, suggesting health hazards risk for the population. Moreover, HQ of Cd and Pb were greatly higher through consumption of cucumber, cabbage, lettuce and red pepper indicating significant health risks. HI was found to be higher >1 (3.32 mg/kg and 3.91 mg/kg) in adult and children respectively for consumption of spinach; however, it was much higher >1 (10.49 mg/kg and 12.4 mg/kg) in adult and children respectively for consumption of cabbage, suggesting more adverse health effects from cabbage consumption than spinach. The findings of this study shows the health risks associated with the consumption of heavy metals through the intake of some the selected vegetables within Katsina Metropolis, therefore, there is need for biomonitoring of these heavy metals in the vegetable because these are some of the main sources of food for humans in many parts of the world. Keywords: Heavy metal, Estimated Daily Intake, Hazard Quotient, Hazard Index, Consumption


2017 ◽  
Vol 2017 ◽  
pp. 1-8 ◽  
Author(s):  
O. C. Ekhator ◽  
N. A. Udowelle ◽  
S. Igbiri ◽  
R. N. Asomugha ◽  
Z. N. Igweze ◽  
...  

Objective. Street-vended foods offer numerous advantages to food security; nevertheless, the safety of street food should be considered. This study has investigated the level of potential toxic metal (Pb, Cd, Hg, Sb, Mn, and Al) contamination among street-vended foods in Benin City and Umunede. Methods. Twenty street food samples were purchased from vendors at bus stops. Metals were analyzed with atomic absorption spectrophotometry. The methods developed by the US EPA were employed to evaluate the potential health risk of toxic metals. Results. The concentrations of the toxic metals in mg/kg were in the range of Pb (0.014–1.37), Cd (0.00–0.00017), Hg (0.00–0.00014), Sb (0.00–0.021), Mn (0.00–0.012), and Al (0.00–0.22). All the toxic metals except Pb were below permissible limit set by WHO, EU, and USEPA. The daily intake, hazard quotient, and hazard index of all toxic metals except for Pb in some street foods were below the tolerable daily intake and threshold value of 1, indicating an insignificant health risk. Total cancer risk was within the priority risk level of 1.0E-04 but higher than the acceptable risk level of 1E-06. Conclusion. Consumption of some of these street foods is of public health concern.


Author(s):  
A.I. Yaradua ◽  
A. J. Alhassan ◽  
A. Nasir ◽  
S. S. Matazu ◽  
A. Usman ◽  
...  

Vegetable fields in Katsina State are increasingly being loaded with heavy metals through various pollution sources such as agricultural activities mining and traffic. Onion bulb samples from the three senatorial zones that constitute to make up Katsina state in the North West of Nigeria were collected and the concentrations of seven heavy metals (Pb, Cd, Cr, Fe, Zn, Mn and Ni) in all the samples were determined by atomic absorption spectrometry. The health risk assessment methods developed by the United States Environmental Protection Agency (US EPA) were employed to explore the potential health hazards of heavy metals in the samples on the children and adult population. The highest mean concentration (mg/kg) was observed for Fe, followed by Pb, Zn and Mn. While Cd has the lowest concentration with the heavy metals Cr and Ni being below detection level (BDL). Overall hazard index (Hi) for the heavy metals were within the safety limit. The overall cancer risk to the adults based on pseudo-total metal concentrations exceeded the target value, mainly contributed by Pb.  Mn and Zn were the primary heavy metals posing non-cancer risks while Pb caused the greatest cancer risk. It was concluded that consumption of the onion samples from Katsina State may contribute to the population cancer burden.


Author(s):  
D. D. Bwede ◽  
R. A. Wuana ◽  
G. O. EGAH ◽  
A. U. Itodo ◽  
E. Ogah ◽  
...  

Tin mining tailings are unprocessed waste materials that overlie an ore which are displaced during mining activities. This research work is aimed at characterizing and evaluating the human health risk of heavy metals in tin mine tailings in Zabot (S3) and Tafan (S4) districts in Barkin Ladi Local Government Area of Plateau State, Nigeria. The samples were characterized using EDX-XRF and SEM. The concentrations of seven heavy metals (Pb, Cr, As, Ni, Cd, Cu and Zn) were determined in S3 and S4. The results showed that Cr, Ni, Cd, Cu and Zn were within the USEPA permissible limits, except for Pb and As with range of (270-300) mg/kg and (40-70) mg/kg respectively for both mining and control sites of S3 and S4. The SEM results revealed small particles size with fine porous structure, and rough areas with varying sizes and pores distributed over the surface for S3 and S4 respectively. Results of the risk assessment showed that the hazard quotient HQ and HI values were greater than 1 indicating high risk. The Carcinogenic and non-carcinogenic risks associated with Pb, Zn, Cd, Cr, Ni and As were evaluated for S3 and S4 for the three exposure pathway and it was found that the mining sites pose more risk than the control and the children were more exposed than the adults. The carcinogenicity of these samples were due to the high hazard quotient for ingestion and dermal exposure pathway. The R total results for As, Cr, Pb and Ni for mining site S3 were found to be (1.39 × 102 , 2.02 × 10-7 , 3.30 × 103 and 8.17 × 10-8 ), and control site (3.42 × 103 , 2.64 × 10-5 , 38.30 × 101 , 6.90 × 10-8 ) for As, Cr, Pb and Ni respectively. From the R total results As and Pb were more than the acceptable threshold, while Cr and Ni were below the threshold of 1 × 10-4 . For the mining site S4, the R total were found to be (5.70 × 102 , 1.82 × 10-7 , 3.63 × 104 and 9.64 × 10-9 ),and the control (1.16 × 103 , 1.71 × 10-7 , 31.1 × 102 and 1.51 × 10-8 ) for As, Cr, Pb and Ni respectively. From the results of the mining and control sites, As and Pb R total were higher than the acceptable threshold, while Cr and Ni were below the threshold of 1 × 10-4 .


2018 ◽  
Vol 16 (1) ◽  
pp. 214-227 ◽  
Author(s):  
Ibironke Titilayo Enitan ◽  
Abimbola Motunrayo Enitan ◽  
John Ogony Odiyo ◽  
Muhammad Mamman Alhassan

AbstractThe study assessed the level of heavy metals in surface water across Ndawuse River near the dumpsite at Phase 1 District of the Federal Capital Territory (FCT), Abuja, Nigeria. The results indicated that oxygen demand, turbidity and heavy metals were above the standard limits set for drinking water. Multivariate analysis using principal component analysis and hierarchical cluster analysis revealed natural and anthropogenic activities as sources of heavy metal contamination. The estimated non-carcinogenic effects using hazard quotient toxicity potential, cumulative hazard index and daily human exposure dose of surface water through ingestion pathway were less than a unity. The estimated carcinogenic risks (CRing) exceeded the suggested potential risk limits, with lead (Pb) having the highest CRing value for all age groups. However, children were found to be more susceptible to heavy metals over a period of time according to the estimated values. The concentration of heavy metals in the investigated river could pose an adverse health risk to several communities that rely on this receiving water bodies for domestic purposes. Therefore, there is need for strict enforcement of environmental laws to protect aquatic ecosystem and to avoid long term cumulative exposure risk that heavy metals may pose on human health.


Author(s):  
Wan-ce Shao ◽  
Yang-yang Zang ◽  
Hai-yao Ma ◽  
Ye Ling ◽  
Zhen-peng Kai

In the present study, a risk assessment of pesticides, phthalates and heavy metals in strawberries (n = 335) in recent years was conducted by determining the out estimate dietary intake (EDI), target hazard quotient (THQ) and hazard index (HI) . 128 Pesticides, 18 phthalates and 3 heavy metals were determined in this determination. 51 pesticide residues were detected in the strawberry samples, and 97.91% samples had levels of at least one of the 51 pesticides above the LOD (limit of detection). 2.39% of samples had pesticides higher than the Chinese MRL. Multiple pesticides residues were detected in most samples. Bis-2-ethylhexyl phthalate (DEHP), diisobutyl phthalate (DIBP) and dibutyl phthalate (DBP) were detected in the strawberry samples with high frequency of detection. Their detectable rates were 100, 100 and 89.9%, respectively. Most of the samples were detected lead (Pb), cadmium (Cd) and nickel (Ni) with the detectable rates 75.76, 92.93 and 92.93%, respectively. Estimated daily intake of analyzed pesticide, phthalate and heavy metal residues appear to be relatively low compared to the ADI. The average THQs and HI were less than one. That means the customers who are exposed to the average contaminants levels may not pose significant health risk. Our results show that the strawberries may be polluted by many kinds of contaminants. Therefore, monitoring of pesticides, phthalates and heavy metal residues in strawberries should be increasingly developed in order to fully protect the health of the consumer.


Author(s):  
O. A Omotoso

This study was carried out to establish health impacts of some trace elements (Al, As, Ba, Cr, Cu, Fe, Mn, Ni, Pb and Zn) in Asa-river, using Inductively Coupled Plasma-Mass Spectrometer technique for the chemical analysis. Laboratory results show that Al, Fe and Mn average concentrations are higher than prescribed limits unlike others. The Contamination Indexes reveal that the elements are heavily loaded in the water. The exposure dose in both adults and children ranges from 0.021 in As to 181 in Fe (in adults) and from 0.068 in As to 576 in Fe (in children). The average Hazard Quotient (HQ) values for adults and children are generally lower than one except Mn that has average value greater than one in both age groups. However, for children, individual HQ in Fe in some of the locations are >1. The Hazard Index (HI)for adults and children ranged from low to high. The average values of Chronic Daily Intake (CDI) are generally <1. However, in children, values for Fe in some locations are >1. The average Carcinogenic Risk (CR) of Cr and Pb computed for adults and children indicated that the values are greater than the risk limit of 10-6 and 10-4. This could result in potential health risk to the consumers. The sources of these trace elements are largely from various anthropogenic activities and slightly from weathering of rocks in the study area. It is recommended that adequate and well monitored precautions need to be taken to safeguard the health of the consumers especially the children with low immunity.


2019 ◽  
Vol 20 (1) ◽  
pp. 150
Author(s):  
Chanchal Chayan Paul ◽  
Md. Abu Shamim Khan ◽  
Probir Kumar Sarkar ◽  
Abdul Hakim ◽  
Md. Waliullah ◽  
...  

Toothpaste is one of the daily essentials, and good quality control practices over it are very important to protect the oral public health from adverse effects. The current study aimed to assess the concentration of fluoride and heavy metals, physicochemical properties in ten different toothpaste samples in Bangladesh, followed by related health risk analysis. pH, moisture content, F–, As, Cu, Pb contents were measured by membrane electrode, thermogravimetric, SPADNS, HG-AAS, flame-AAS methods, respectively. The results were compared to the specification of the packet and Bangladesh Standard and Testing Institute (BSTI) standard. The physicochemical properties well-matched the formulation standard values. The moisture content was 27.18 ± 2.20 to 52.10 ± 5.01%, with 50% of the samples in permissible limit but the pH of all the samples (6.40-8.60) was within the standard limit. Available F–, Cu, Pb, and As content ranged from 803–1617, 2.78–13.10, 0.27–2.12, and 0.027–0.637 mg/Kg, respectively. F– content in 80% toothpaste did not meet the packet specification and was higher than BSTI standard, though heavy metals were within the BSTI limit. Hazard quotient (HQ) and HI (Hazard Index) analysis revealed that toothpaste safe from heavy metal related to health risk.


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