scholarly journals Investigation of pumpkin pod extract as corrosion inhibitor for carbon steel in HCl Solution

2020 ◽  
Vol 39 (1) ◽  
pp. 173-181
Author(s):  
A.O. Okewale ◽  
T. Adebayo
Keyword(s):  
Response Surface Methodology ◽  
Carbon Steel ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Response Surface ◽  
Steel Corrosion ◽  
Optimal Conditions ◽  
Extract Concentration ◽  
Process Factors ◽  
Hcl Solution

This work focused on the use of natural, and eco-friendly waste material as an inhibitor for inhibiting carbon steel corrosion. In order to obtain minimum rate of corrosion on carbon steel, optimization of the process factors that affect carbon steel corrosion was undertaken using the Response Surface Methodology (RSM). Three parameters were fluctuated viz; temperature, pumpkin pod extract concentration and time of exposure and their corresponding effects on rate of corrosion of carbon steel were ascertained. The data obtained was fitted to a model that is quadratic which was subsequently validated. The predicted lowest rate of corrosion by the model is 2.5427mm/yr with optimal conditions of 178.07ppm of pumpkin extract concentration, exposure time of 2.26hrs, and 35.28oC of temperature. The conditions were validated in three replicates and corrosion rate of 2.75mm/yr was obtained. Keywords: corrosion, optimization, pumpkin pod, response surface methodology.

scholarly journals LINSEED OIL AS A NOVEL ECO-FRIENDLY CORROSION INHIBITOR OF CARBON STEEL IN 1 M HCl

2019 ◽  
Vol 26 (02) ◽  
pp. 1850148
Author(s):  
N. GHARDA ◽  
M. GALAI ◽  
L. SAQALLI ◽  
N. HABBADI ◽  
R. GHAILANE ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Inhibition Efficiency ◽  
Linseed Oil ◽  
Steel Corrosion ◽  
Effective Inhibitor ◽  
Chromatography Method ◽  
Green Corrosion Inhibitor ◽  
Hcl Solution

The extraction of linseed oil (LO) was realized by refluxing method. The extracted oil was identified by gas chromatography method coupled with mass spectrometry (GC-MS). In order to contribute to the protection of the environment, one contemplates to try on LO as a green corrosion inhibitor. The corrosion inhibition of LO was studied by weight loss and electrochemical methods. The obtained results showed that the LO is an effective inhibitor of the carbon steel corrosion in 1[Formula: see text]M HCl solution, the inhibition efficiency increased with concentration to reach 88% at 200[Formula: see text]ppm. Furthermore, the adsorption of the inhibitor on the surface of metal in 1[Formula: see text]M HCl solution was found to obey Langmuir’s adsorption isotherm. The influences of temperature were also studied in the range from 298[Formula: see text]K to 328[Formula: see text]K. The kinetic and thermodynamic data of activation dissolution process were determined and discussed.

scholarly journals Kinerja kalium metavanadat sebagai inhibitor korosi baja karbon rendah dalam lingkungan klorida dan sulfida

2018 ◽  
Vol 7 (3) ◽  
pp. 828
Author(s):  
Isdiriayani Nurdin ◽  
R Asri Pratiwi ◽  
Aditya Farhan A ◽  
Fikri Anggara P ◽  
Rennie Sari
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Low Carbon Steel ◽  
Chloride Concentration ◽  
Steel Corrosion ◽  
Low Carbon ◽  
Cyclic Voltammetry Method ◽  
The Common ◽  
Chloride Environment

Inhibitor addition is one of the common corrosion control methods. Potassium metavanadate (KVO3) is the common corrosion inhibitor for Benfield solution in CO2 absorber. Former research shows that KVO3 is also able to inhibit the corrosion in seawater containing Sulphate Reducing Bacteria (SRB) due to its capacity as biocide. Chloride and Sulfide are common corrosive ions found in process fluids in industries. Therefore, this research is carried out to study the performance of KVO3 as a corrosion inhibitor for low- carbon steel in chloride and sulfide contaminated environment. The objective of this research was achieved by measuring low-carbon steel corrosion rate in various concentrations of contaminants. The corrosion rate was measured by Tafel method. The corrosion inhibition mechanisms were studied using cyclic voltammetry method. Meanwhile the corrosion products were identified by X - ray diffraction spectrometry (XRD). This research results that KVO3 is an effective corrosion inhibitor in chloride environment when the chloride concentration ranges between 20 g/L and 30 g/L. In this range of concentration, KVO3 performs more than 99% efficiency. While in sulfide environment, KVO3 is an ineffective corrosion inhibitor. On the other hand, the addition of KVO3 reduces the corrosion rate of carbon steel in seawater containing sulfide, although its performance does not meet the effective inhibitor criteria. Higher concentration of sulfide results the higher inhibition efficiency of KVO3.Keywords: Potassium metavanadate, low - carbon steel, corrosion inhibitor AbstrakPenambahan inhibitor merupakan salah satu metode pengendalian korosi. Kalium metavanadat (KVO3) sering digunakan sebagai inhibitor korosi pada absorber CO2 yang menggunakan larutan Benfield. Hasil penelitian sebelumnya menunjukkan bahwa KVO3 mampu menginhibisi korosi baja karbon rendah dalam air laut yang mengandung bakteri pereduksi sulfat (SRB) dengan bertindak sebagai biosida. Klorida dan sulfida merupakan ion-ion korosif yang umum ditemui dalam fluida proses di industri. Penelitian ini dilakukan untuk mempelajari kinerja KVO3 sebagai inhibitor korosi baja karbon rendah dalam lingkungan akuatik yang terkontaminasi klorida, ataupun sulfida. Untuk mencapai tujuan tersebut dilakukan pengukuran laju korosi baja karbon rendah dengan jenis dan konsentrasi kontaminan bervariasi. Pengukuran laju korosi dilakukan dengan metode Tafel. Mekanisme inhibisi diprediksi dengan metode voltametri siklik. Sedangkan produk korosi diidentifikasi dengan menggunakan spektrometri difraksi sinar X (XRD). Dari penelitian ini, diperoleh hasil bahwa KVO3 efektif sebagai inhibitor korosi baja karbon rendah pada lingkungan klorida berkonsentrasi antara 20 g/L hingga 30 g/L dengan efisiensi di atas 99%. Pada lingkungan sulfida, KVO3 kurang efektif menginhibisi korosi baja karbon rendah. Sedangkan pada air laut sintetik yang mengandung sulfida, walaupun belum termasuk kategori inhibitor efektif, namun KVO3 dapat menurunkan laju korosi baja karbon dengan efisiensi inhibisi yang meningkat seiring dengan kenaikan konsentrasi sulfida.Kata kunci: kalium metavanadat, baja karbon rendah, inhibitor korosi

scholarly journals EXTRACT OF COCOR BEBEK (KALANCHOE PINNATA) AS A CORROSION INHIBITOR

2017 ◽  
Vol 6 (2) ◽  
pp. 112-116
Author(s):  
Tri Reksa Saputra ◽  
Agustinus Ngatin
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Ethyl Acetate ◽  
Corrosion Inhibitor ◽  
Steel Corrosion ◽  
Metal Corrosion ◽  
Sharp Decline ◽  
Kalanchoe Pinnata ◽  
Rate Test ◽  
Corrosion Time

In this study, Cocor Bebek leaves (Kalanchoe pinnata) extract is studied for metal corrosion inhibitor. 10.3 kg of K. Pinnata leaves produce concentrated extract of methanol, n-hexane and ethyl acetate as much as 65.7442, 36.1452, and 15.2711 g respectively. The concentrated extracts were then used to determine the rate of corrosion. Corrosion rate test showed that extract of ethyl acetate can reduce corrosion rate of carbon steel in NaCl 3.5% from 2.954 mpy to 0.963 and 0.923 mpy using 500 ppm and 1000 ppm of extract consecutively. Corrosion rate of Cocor Bebek extract at addition of 500 ppm ethyl acetate in the solution of NaCl 3.5% is decreasing immediately. It was found that the carbon steel corrosion rate decrease as much 4.857 for 6 hours and continuously shows sharp decline until 24 hours of corrosion time. Corrosion rate is slowly decreasing till reach 1.694 mpy at corrosion time of 168 hours.

scholarly journals THE CORROSION PROTECTION ON STEEL PIPE ST 41 IN WATER PLUMBING ENVIRONMENTAL USING NATRIUM CARBONATE (NA2CO3) AS INHIBITOR

2016 ◽  
Vol 2 (1) ◽  
pp. 20
Author(s):  
I. G. A. Arwati ◽  
T. Izzati ◽  
Z. Arifin
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Corrosion Protection ◽  
Steel Corrosion ◽  
Steel Pipe ◽  
Steel Pipes ◽  
Potential Value

<p>This study aimed to analyze the effect of adding to the rate of steel corrosion inhibitor and comparing the rate of corrosion on steel pipes with and without inhibitors.The testing conducted in Puspitek shown that the most optimum inhibitor contained in the addition of 1% due to changes in the price of the original acidity (pH) from 7.30 to 11.80. This shows the increasing of pH occurred sizable value and followed by the declines of potential value (Ecorr) -700.53 mV to -512.39 mV. Thus, the  decreasing accured to the current corrosion value (Icorr) from 2.71 μA/cm<sup>2</sup> to 0.31 μA/cm<sup>2</sup>, while the corrosion rate of carbon steel St 41 decreased most effective after adding 1% Na<sub>2</sub>CO<sub>3</sub> as inhibitor, the corrosion rate is changed from 1.2437 mpy to 0.1427 mpy.</p>

Evaluation of 1‐Hexadecylbenzimidazole as a Corrosion Inhibitor on Low Carbon Steel 15 % HCl Solution Interface

2021 ◽  
Vol 6 (13) ◽  
pp. 3199-3217
Author(s):  
Nurudeen A. Odewunmi ◽  
Mohammad A. J. Mazumder ◽  
Shaikh A. Ali
Keyword(s):  
Carbon Steel ◽  
Corrosion Inhibitor ◽  
Low Carbon Steel ◽  
Low Carbon ◽  
Solution Interface ◽  
Hcl Solution

Optimization of the Ultrasonic Extraction of Gypenoside III from Gynostemma pentaphyllum by Response Surface Methodology

2012 ◽  
Vol 550-553 ◽  
pp. 1866-1870
Author(s):  
Xiao Dan Tang ◽  
Hai Yang Hang ◽  
Shao Yan Wang ◽  
Jing Xiang Cong
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Extraction Yield ◽  
Raw Material ◽  
Extraction Temperature ◽  
Optimal Conditions ◽  
Gynostemma Pentaphyllum ◽  
Bioactive Component ◽  
Yield Value ◽  
Ultrasonic Time

Gypenosides III is a major bioactive component which is rich in Gynostemma pentaphyllum. For better utilization of the native resource, response surface methodology was used to optimize the extraction conditions of gypenosides III from G. pentaphyllum. The effects of three independent variables on the extraction yield of gypenosides III were investigated and the optimal conditions were evaluated by means of Box-Behnken design. The optimal conditions are as follows: ratio of ethanol to raw material 25, extraction temperature 58°C and ultrasonic time 25min. Under these conditions, the yield of gypenoside III is 1.216±0.05%, which is agreed closely with the predicted yield value.

scholarly journals The effect of volatile organic acids and CO2 on the corrosion rate of carbon steel from a Top-of-Line-Corrosion (TLC) perspective

2021 ◽  
Vol 1201 (1) ◽  
pp. 012079
Author(s):  
S B Gjertsen ◽  
A Palencsar ◽  
M Seiersten ◽  
T H Hemmingsen
Keyword(s):  
Carbon Steel ◽  
Corrosion Rate ◽  
Organic Acid ◽  
Carbonic Acid ◽  
Acid Corrosion ◽  
Iron Concentration ◽  
Critical Factor ◽  
Steel Corrosion ◽  
Carbon Steels ◽  
Corrosion Rates

Abstract Models for predicting top-of-line corrosion (TLC) rates on carbon steels are important tools for cost-effectively designing and operating natural gas transportation pipelines. The work presented in this paper is aimed to investigate how the corrosion rates on carbon steel is affected by acids typically present in the transported pipeline fluids. This investigation may contribute to the development of improved models. In a series of experiments, the corrosion rate differences for pure CO2 (carbonic acid) corrosion and pure organic acid corrosion (acetic acid and formic acid) on X65 carbon steel were investigated at starting pH values; 4.5, 5.3, or 6.3. The experiments were conducted in deaerated low-salinity aqueous solutions at atmospheric pressure and temperature of 65 °C. The corrosion rates were evaluated from linear polarization resistance data as well as mass loss and released iron concentration. A correlation between lower pH values and increased corrosion rates was found for the organic acid experiments. However, the pH was not the most critical factor for the rates of carbon steel corrosion in these experiments. The experimental results showed that the type of acid species involved and the concentration of the undissociated acid in the solution influenced the corrosion rates considerably.

scholarly journals Response surface methodology-artificial neural network based optimization and strain improvement of cellulase production by Streptomyces sp.

2020 ◽  
Vol 36 (4) ◽  
Author(s):  
Ega Soujanya Lakshmi ◽  
Manda Rama Narasinga Rao ◽  
Muddada Sudhamani
Keyword(s):  
Neural Network ◽  
Artificial Neural Network ◽  
Response Surface Methodology ◽  
Response Surface ◽  
Wild Strain ◽  
Cellulase Activity ◽  
Cellulase Production ◽  
Optimal Conditions ◽  
Zone Formation ◽  
Artificial Neural

ABSTRACT Thirty seven different colonies were isolated from decomposing logs of textile industries. From among these, a thermotolerant, grampositive, filamentous soil bacteria Streptomyces durhamensis vs15 was selected and screened for cellulase production. The strain showed clear zone formation on CMC agar plate after Gram’s iodine staining.  Streptomyces durhamensis vs15 was further confirmed for cellulase production by estimating the reducing sugars through dinitrosalicylic acid (DNS) method. The activity was enhanced by sequential mutagenesis using three mutagens of ultraviolet irradiation (UV), N methyl-N’-nitro-N-nitrosoguanidine (NTG) and Ethyl methane sulphonate (EMS). After mutagenesis, the cellulase activity of GC23 (mutant) was improved to 1.86 fold compared to the wild strain (vs15). Optimal conditions for the production of cellulase by the GC 23 strain were evaluated using Response Surface Methodology (RSM) and Artificial Neural Network (ANN). Effect of pH, temperature, duration of incubation, , and substrate concentration on cellulase production were evaluated. Optimal conditions for the production of cellulase enzyme using Carboxy Methyl Cellulase as a substrate are 55 oC of temperature, pH of 5.0 and incubation for 40 h. The cellulase activity of the mutant Streptomyces durhamensis GC23 was further optimised to 2 fold of the activity of the wild type by RSM and ANN.  

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