scholarly journals Komplexní magmaticko-hydrotermální vývoj columbitu, mikrolitu a fersmitu z beryl-columbitového pegmatitu D6e u Maršíkova, Česká republika

2020 ◽  
Vol 28 (1) ◽  
pp. 23-34 ◽  
Author(s):  
Štěpán Chládek ◽  
Pavel Uher
Keyword(s):  
Czech Republic ◽  
Granitic Pegmatite ◽  
Accessory Minerals ◽  
Partial Dissolution ◽  
Pegmatite Body ◽  
Magmatic Fluids ◽  
Compositional Variations ◽  
Homogeneous Pattern ◽  
Oscillatory Zonation

The recently rediscovered small D6e granitic pegmatite body, enclosed in amphibole gneiss of the Sobotín amfibolite massif (Jeseníky Mountains, Czech Republic), is characterized by numerous accessory minerals, including common columbite group minerals (CGM) and minor microlite and fersmite related to blocky K-feldspar unit. The CGM show complex internal zoning. Primary magmatic columbite-(Mn) occurs as corroded domains of prevailing homogeneous pattern, followed by less evolved oscillatory zonation. Primary CGM were overprinted by extensive recrystallization controlled by late-magmatic to post-magmatic fluids and leading to a formation of complex patchy and convolute oscillatory domains of secondary (hydrothermal) CGM. Primary columbite-(Mn) shows significantly limited Ta/(Ta+Nb) and Mn/(Mn+Fe) ratios, whereas secondary columbite-(Fe) to -(Mn) show slightly wider Fe-Mn and Nb-Ta compositional variations. Complex textures and the element fluctuations indicate a partial dissolution-reprecipitation of primary CGM caused by late- to post-magmatic fluids. Moreover, late calciomicrolite I, II and fersmite precipitated on the cracks of columbite crystals. Rare U-rich calciomicrolite I was extensively replaced by fersmite and oscillatorily zoned U-poor calciomicrolite II, slightly enriched in F. Their formation sequestrated part of hydrotermally released Na, Ca, U and represents the final subsolidus fluid-driven stage of the pegmatite evolution. Textural and compositional variations of Nb-Ta mineralization point to a complex magmatic to hydrothermal evolution of the D6e beryl-columbite pegmatite similar to other pegmatites in this region.

scholarly journals The Distribution of Rare Metals in the LCT Pegmatites from the Giraúl Field, Angola

Minerals ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 580
Author(s):  
Gonçalves ◽  
Melgarejo ◽  
Alfonso ◽  
Amores ◽  
Paniagua ◽  
...  
Keyword(s):  
Grain Size ◽  
Hydrothermal Fluids ◽  
Granitic Pegmatite ◽  
Rare Metals ◽  
Accessory Minerals ◽  
Critical Elements ◽  
Incompatible Elements ◽  
Pegmatite Body ◽  
Quartz Core ◽  
Oxide Minerals

The Giraúl granitic pegmatite field in Angola is composed of five pegmatite types, the most evolved belong to the beryl-columbite, beryl-columbite-phosphate and spodumene types. Pegmatites are concentrically zoned with increased grain size toward a quartz core; the most evolved pegmatites have well-developed replacement units. These pegmatites are rich in Nb-Ta oxide minerals and the field has a moderate interest for critical elements such as Ta and Hf. Tourmaline, garnet and micas occur as accessory minerals. The abundance of Zr and Nb-Ta minerals increases with the evolution of the pegmatites, as well as the proportions of beryl and Li-rich minerals. The Ta/(Ta + Nb) ratio in Nb-Ta oxide minerals and the Hf/(Hf + Zr) ratio in zircon also increase with the evolution of the pegmatites and within each pegmatite body from border to inner zones, and especially in the late veins and subsolidus replacements. Textural patterns and occurrence of late veins with Ta-rich minerals suggest that Nb and especially Ta can be enriched in late hydrothermal fluids exsolved from the magma, along with Hf and other incompatible elements as Sn, U, Pb, Sb and Bi.

scholarly journals Minerály skupiny columbitu a mikrolitu v granitovom pegmatite pri Liešťanoch: prvý výskyt vzácnoprvkovej Nb-Ta mineralizácie v Strážovských vrchoch (Slovenská republika)

2020 ◽  
Vol 28 (2) ◽  
pp. 347-352
Author(s):  
Pavel Uher ◽  
Martin Števko ◽  
Sergii Kurylo
Keyword(s):  
Crystalline Basement ◽  
Western Carpathians ◽  
Granitic Pegmatite ◽  
Chemical Compositions ◽  
Accessory Minerals ◽  
Magmatic Origin ◽  
Euhedral Crystal ◽  
Compositional Variations ◽  
Central Western Carpathians

Accessory minerals of columbite and microlite groups were identified in granitic pegmatite dike intruded into parental Carboniferous (~350 Ma) leucogranites of the crystalline basement of the Tatric Unit, Central Western Carpathians. The pegmatite is situated on E slope of Bystrý Hill near Liešťany village, the Strážovské vrchy Mts., Slovakia. Primary columbite-(Fe) forms euhedral crystal (~3 mm across) with diffuse internal zoning reflecting a relatively small compositional variations: Mn/(Mn + Fe) = 0.40 - 0.45 and Ta/(Ta + Nb) = 0.21 - 0.24. Secondary anhedral domains of Ta-rich columbite-(Fe) to tantalite-(Fe) (≤200 μm) with Mn/(Mn + Fe) = 0.45 - 0.47 and Ta/(Ta + Nb) = 0.45 - 0.62 partly replace primary columbite-(Fe) along crystal rims. Moreover, secondary subhedral crystals of microlite-group minerals (≤25 μm) form fracture fillings in columbite-(Fe). The microlites show uniform high Ta/(Ta + Nb) ratio (0.77 - 0.80) and U content (7.7 - 10.2 wt.% UO2; 0.18 - 0.21 U apfu) but different contents of F, Ca, Na and Pb: central parts locally show fluorcalciomicrolite composition (~2 wt.% F, ~9.5 wt.% CaO, 2.2 - 2.7 wt.% Na2O), whereas main microlite mass forms zero-valent-dominant microlite with inclusions (≤8 μm) of Pb-rich zero-valent-dominant microlite (16.8 - 19.7 wt.% PbO; 0.46 - 0.56 Pb apfu). Textural relationships and chemical compositions of Nb-Ta minerals indicate primary magmatic origin of columbite-(Fe) and post-magmatic (early subsolidus to late hydrothermal) formation of secondary Ta-rich columbite-(Fe) to tantalite-(Fe) and microlite-group minerals.

Mineralogical and chemical heterogeneity of three standard clay mineral samples

Clay Minerals ◽  
1996 ◽  
Vol 31 (3) ◽  
pp. 417-422 ◽  
Author(s):  
H. M. Köster
Keyword(s):  
Particle Size ◽  
Chemical Analysis ◽  
Clay Mineral ◽  
Chemical Heterogeneity ◽  
X Ray Diffraction ◽  
Accessory Minerals ◽  
Size Fractions ◽  
X Ray ◽  
Compositional Variations

AbstractMineralogical and chemical heterogeneity within three standard clay mineral samples have been identified by X-ray diffraction and chemical analysis of various size-fractions. This heterogeneity is partly attributed to accessory minerals, but mostly to structural and compositional variations in the 2:1 layer minerals of different particle size in the same specimen.

Minerály řady bavenit-bohseit z pegmatitu Schinderhübel I v Maršíkově (silezikum, Česká republika)

2020 ◽  
Vol 28 (2) ◽  
pp. 353-358
Author(s):  
Zdeněk Dolníček ◽  
Miroslav Nepejchal ◽  
Milan Novák
Keyword(s):  
Czech Republic ◽  
Early Stage ◽  
Chemical Fractionation ◽  
Potential Importance ◽  
Pegmatite Body ◽  
Fluoride Complexation ◽  
Hydrothermal Stage ◽  
Ca 50 ◽  
Primary Minerals ◽  
Identical Behaviour

Bavenite and bohseite were found in an archive sample from Schinderhübel I granitic pegmatite, situated ca. 50 m NE from the famous chrysoberyl-bearing pegmatite body Schinderhübel III near Maršíkov (Silesicum, Czech Republic). Minerals of the bavenite-bohseite series together with minor quartz, muscovite and albite form chalky white radial aggregates up to 3.5 cm in size within a fissure cutting the pegmatite. The electron microprobe data revealed 29.0 - 65.4 mol. % of bavenite component, 0.03 - 0.12 apfu Na and 0.05 - 0.20 apfu F. Bavenite seems to be older than bohseite in the studied aggregate. The collected data suggest significant increase of Be/Al during growth of the studied aggregate, which could be explained in two ways. First, one can assume that different primary minerals with contrasting Be/Al ratios were dissolved during different stages of alteration (i.e., chrysoberyl in the early stage giving rise to bavenite-rich compositions and beryl during late stage giving rise to bohseite-rich members). Second, chemical fractionation of Be and Al due to complexation by fluoride anions is suggested from negative correlation between Al and F in the studied members of the bavenite-bohseite series. Identical behaviour is observed also in bavenite-bohseite from Piława Górna and Maršíkov D6e pegmatites, suggesting potential importance of fluoride complexation during hydrothermal stage of evolution of granitic pegmatites.

Compositional and Textural Variations of Columbite-Group Minerals from Beryl-Columbite Pegmatites in the Maršíkov District, Bohemian Massif, Czech Republic: Magmatic versus Hydrothermal Evolution

2020 ◽  
Author(s):  
Štěpán Chládek ◽  
Pavel Uher ◽  
Milan Novák
Keyword(s):  
Czech Republic ◽  
Bohemian Massif ◽  
High Mobility ◽  
Oscillatory Zoning ◽  
Hydrothermal Conditions ◽  
Magmatic Stage ◽  
Compositional Variations ◽  
Host Rocks ◽  
Crystal Volume ◽  
Residual Melt

Abstract We studied compositional variations in columbite group minerals (CGM) from several granitic pegmatites of the beryl-columbite subtype in the Maršíkov district, Silesian Domain of the Bohemian Massif, Czech Republic. The CGM are characterized by distinct zoned patterns in BSE images. Primary magmatic homogeneous to oscillatory zoning is preserved in corroded crystal cores, whereas the majority of the crystal volume is replaced by secondary complexly zoned domains formed via post-magmatic processes. The primary domains show relatively uniform evolutionary trends from core to rim, generally with steeply increasing Ta/(Ta + Nb) and negligible to slightly increasing Mn/(Mn + Fe). In contrast, the compositions of secondary CGM domains indicate a reversed evolution, with: (1) steeply decreasing Ta/(Ta + Nb) and relatively constant Mn/(Mn + Fe) characteristics for CGM in the Bienergraben and Scheibengraben pegmatites, and (2) insignificantly decreasing Ta/(Ta + Nb) and strongly decreasing Mn/(Mn + Fe) characteristics for CGM in the Schinderhübel I and Lysá Hora pegmatites. Patchy zoning and secondary evolution in CGM result from metasomatic replacement processes related to fluids. These fluids are probably late-magmatic and exsolved from the residual melt and in later stages locally mixed with external Mg-enriched fluids derived from the host rocks. The presence of volatiles (mainly H2O, F) facilitated high mobility of the elements and replacement of the early CGM. Textural characteristics and compositional variations in CGM show the complex evolution of the pegmatite system from the magmatic stage to subsolidus-hydrothermal conditions.

scholarly journals Rare-element granitic pegmatite of Miocene age emplaced in UHP rocks from Visole, Pohorje Mountains (Eastern Alps, Slovenia): accessory minerals, monazite and uraninite chemical dating

2014 ◽  
Vol 65 (2) ◽  
pp. 131-146 ◽  
Author(s):  
Pavel Uher ◽  
Marian Janák ◽  
Patrik Konečný ◽  
Mirijam Vrabec
Keyword(s):  
Late Miocene ◽  
Volcanic Rocks ◽  
Eastern Alps ◽  
Granitic Pegmatite ◽  
Fault System ◽  
Rare Element ◽  
Accessory Minerals ◽  
Precipitation Temperature ◽  
The Alps ◽  
Chemical Dating

Abstract The granitic pegmatite dike intruded the Cretaceous UHP rocks at Visole, near Slovenska Bistrica, in the Pohorje Mountains (Slovenia). The rock consists mainly of K-feldspar, albite and quartz, subordinate muscovite and biotite, while the accessory minerals include spessartine-almandine, zircon, ferrocolumbite, fluorapatite, monazite- (Ce), uraninite, and magnetite. Compositions of garnet (Sps48-49Alm45-46Grs + And3-4 Prp1.5-2), metamict zircon with 3.5 to 7.8 wt. % HfO2 [atom. 100Hf/(Hf + Zr) = 3.3-7.7] and ferrocolumbite [atom. Mn/(Mn + Fe) = 0.27-0.43, Ta/(Ta + Nb) = 0.03-0.46] indicate a relatively low to medium degree of magmatic fractionation, characteristic of the muscovite - rare-element class or beryl-columbite subtype of the rare-element class pegmatites. Monazite-(Ce) reveals elevated Th and U contents (≤11 wt. % ThO2, ≤5 wt. % UO2). The monazite-garnet geothermometer shows a possible precipitation temperature of ~495 ± 30 °C at P~4 to 5 kbar. Chemical U-Th-Pb dating of the monazite yielded a Miocene age (17.2 ± 1.8 Ma), whereas uraninite gave a younger (~14 Ma) age. These ages are comtemporaneous with the main crystallization and emplacement of the Pohorje pluton and adjacent volcanic rocks (20 to 15 Ma), providing the first documented evidence of Neogene granitic pegmatites in the Eastern Alps. Consequently, the Visole pegmatite belongs to the youngest rare-element granitic pegmatite populations in Europe, together with the Paleogene pegmatite occurrences along the Periadriatic (Insubric) Fault System in the Alps and in the Rhodope Massif, as well as the Late Miocene to Pliocene pegmatites in the Tuscany magmatic province (mainly on the Island of Elba).

Fluorcaphite from hydrothermally altered teschenite at Tichá, Outer Western Carpathians, Czech Republic: compositional variations and origin

2017 ◽  
Vol 81 (6) ◽  
pp. 1485-1501 ◽  
Author(s):  
Kamil Kropáč ◽  
Zdeněk Dolníček ◽  
Pavel Uher ◽  
Tomáš Urubek
Keyword(s):  
Czech Republic ◽  
Lower Cretaceous ◽  
External Source ◽  
Hydrothermal Activity ◽  
Western Carpathians ◽  
Accessory Mineral ◽  
Alteration Zone ◽  
Hydrothermal Conditions ◽  
Outer Western Carpathians ◽  
Compositional Variations

AbstractFluorcaphite [SrCaCa3(PO4)3F] is a rare strontium-calcium member of the apatite supergroup which was previously known only from the Khibiny and Lovozero alkaline complexes. This paper presents evidence of a third fluorcaphite occurrence. It was found in hydrothermally altered Lower Cretaceous teschenite, which forms an intrusive body (probably a sill) in the Lower Cretaceous siliciclastic flysch sediments at Tichá near Frenštát pod Radhoštěm, Silesian Unit, Outer Western Carpathians (Czech Republic). Fluorcaphite occurs as an accessory mineral in hydrothermal veins and in an adjacent alteration zone within the host teschenite. Vein-hosted fluorcaphite forms euhedral crystals and skeletal crusts enclosed in analcime while the teschenite-hosted fluorcaphite forms small overgrowths on older phenocrysts of magmatic apatite. Fluorcaphite from Tichá contains 0.50–1.97 Sr apfu, 2.96–4.49 Ca apfu, 0.59–1.09 F apfu and significantly lower Na (0.01–0.05 apfu) and LREE contents (up to 0.07 apfu). Fluorcaphite formed under hydrothermal conditions after solidification of the host teschenite during post-magmatic hydrothermal activity at temperatures probably between ∼150 and 300°C. The initial 87Sr/86Sr ratio of vein-hosted analcime +fluorcaphite (0.7063) is significantly higher than those of the host teschenite (0.7041). We therefore suggest a mix of strontium sources in the vein analcime+fluorcaphite: (1) from the host teschenite plus (2) from external source(s) including the Lower Cretaceous seawater and/or surrounding sedimentary rocks of the Silesian Unit. These data indicate an open-system fluid regime and the participation of various fluid sources during the alteration event giving rise to fluorcaphite.

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