scholarly journals EXTRACTION METHODS AND ADSORPTION KINETICS OF POTASSIUM IN CALCAREOUS SOILS OF MULTAN

2021 ◽  
Vol 37 (2) ◽  
pp. 87-96
Author(s):  
M. Aurangzeib ◽  
S. Hussain ◽  
A. Rehim ◽  
M. A. Bashir ◽  
H. M. A. Raza
Keyword(s):  
Calcium Carbonate ◽  
Pearson Correlation ◽  
Calcareous Soils ◽  
Chemical Properties ◽  
Extraction Methods ◽  
Exchange Capacity ◽  
Physico Chemical ◽  
Function Models ◽  
Kinetics Of ◽  
K Fertilization

Understanding the dynamics of potassium (K) and its availability is fundamental in its efficient use as an important nutrient. The objectives of present study were to compare standard K extraction methods for extractable K and kinetics of K adsorption on five different textured soils. The soils were analyzed for physico-chemical properties, extractable K contents and kinetics of K adsorption. The soils had variable contents of soluble (8-52mg kg-1), exchangeable (13-215mg kg-1), fixed (488-1836mg kg-1), structural (2936-26362mg kg-1) and total K (3438-28517mg kg-1). Except soluble K, the amount of K in different forms was significantly (P?0.05) correlated with clay contents, electrical conductivity (EC), cation exchange capacity (CEC) and calcium carbonate in soils. Different methods variated the extracted K in different textured soils. Mehlich-III, ammonium acetate, AB-DTPA, and calcium chloride extracted K was maximum in sandy clay loam (298mg kg-1, 267mg kg?1, 226mg kg-1, and 113mg kg-1) and lowest was in loamy sand (33mg kg-1, 24mg  kg-1, 30mg kg-1, and 24mg   kg-1) respectively. Elovich and power function models best explained the K kinetics adsorption, as rate of adsorption constants were negatively correlated with sand contents in the soil type. Pearson correlation showed that the extractability of K by different methods and kinetics of K adsorption were dependent on soil texture EC, CEC and calcium carbonate contents. Hence, soil physico-chemical properties should be considered in recommending rate of K fertilization along with crop K demand and soil extractable K.

The effect of origin and physico-chemical properties on the kinetics of reduction of mixed NiO-Fe2O3 oxides with hydrogen

1986 ◽  
Vol 51 (10) ◽  
pp. 2098-2108 ◽  
Author(s):  
Milan Pospíšil ◽  
Jan Topinka
Keyword(s):  
Mixed Oxides ◽  
Mutual Influence ◽  
Spinel Phase ◽  
Chemical Properties ◽  
Inhibitory Effect ◽  
Chemical Parameters ◽  
Physico Chemical ◽  
Preliminary Annealing ◽  
Kinetics Of ◽  
Kinetics Of Reduction

We investigated the effect of origin and some physico-chemical parameters on the kinetics of reduction with hydrogen of two series of mixed NiO-Fe2O3 oxides differing by their composition, the character of their precursors (mixed crystalline nitrates and coprecipitated hydroxides) and their decomposition temperature.This effect manifested itself by different magnitudes of specific surfaces of the mixed oxides and coherent regions of present phases as well as by different oxidizing abilities of the surface and differences in morphology and phase composition of corresponding samples in both series investigated. Nonlinear or nonmonotonous composition dependences of physico-chemical parameters investigated point to a mutual influence of individual components, which is also a function of the system origin and which modifies its reactivity during its reduction with hydrogen. The kinetics of the reduction was studied thermogravimetrically at 320-410 °C. The reduction of oxides of the hydroxide origin is catalytically accelerated by primarily reduced nickel, whereas in corresponding samples of the nitrate series, the total NiO is bound to the spinel phase and the reduction is delayed. Experimental IR spectra, the effect of preliminary annealing and DTA of the mixed oxides point to an inhibitory effect of water, which is constitutionally bound in trace admixtures of the goethite phase, on the kinetics of reduction of samples in the hydroxide series.

scholarly journals Radiation-induced Grafting of Styrene onto Polyethylene Films for Preparation of Cation Exchange Membranes: Effect of Crosslinking+

2017 ◽  
Vol 2 (1) ◽  
Author(s):  
M. M. Nasef ◽  
H. Saidi ◽  
A. H. Yahaya
Keyword(s):  
Cation Exchange ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Swelling Properties ◽  
Ion Exchange Capacity ◽  
Physico Chemical ◽  
Styrene Divinylbenzene ◽  
Radiation Induced

Crosslinked cation exchange membranes bearing sulfonic acid groups (PE-g-PSSA/DVB) were prepared by radiationinduced grafting of styrene/divinylbenzene (DVB) mixtures onto low density polyethylene (PE) films followed by sulfonation reactions. The effect of addition of DVB (2 and 4%) on the grafting behavior and the physico-chemical properties of the membranes such as ion exchange capacity, swelling and ionic conductivity were evaluated incorrelation with grafting yield (Y%). The structural and thermal properties of the membranes were also studied using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA), respectively. Crosslinking with DVB was found to considerably affect the properties of the membranes in a way that reduces the swelling properties and enhances the chemical stability. The ion conductivity of the crosslinked membranes recorded a level of 10–2 S/cm at sufficient grafting yield (28%) despite the reduction caused by the formation of crosslinking structure. The results of this work suggest that membranes prepared in this study are potential alternatives for various electrochemical applications.

scholarly journals Correlations between physico-chemical properties and nickel adsorption parameters in soils used in sanitary landfill liners

2020 ◽  
Vol 34 (3) ◽  
pp. 275-284
Author(s):  
Ricardo Antonio Ferreira da Silva ◽  
Danilo Brito da Costa ◽  
William de Paiva ◽  
Márcio Camargo de Melo ◽  
Veruschka Escarião Dessoles Monteiro
Keyword(s):  
Chemical Properties ◽  
Bentonite Clay ◽  
Exchange Capacity ◽  
Isotherm Models ◽  
Sanitary Landfill ◽  
Adsorption Parameters ◽  
Clayey Sand ◽  
Landfill Liners ◽  
Physico Chemical ◽  
Nickel Adsorption

The adsorption of heavy metals by sanitary landfill liners represents a measure of protection of surface and groundwaters against contamination by metals, mitigating risks to public health. Hence, this research aimed to identify, from correlations, the influence of physico-chemical properties of soils applied in landfill liners using nickel adsorption parameters. Batch equilibrium tests with initial nickel concentrations of 45 to 1440 mg.L-1 were performed in clayey sand and bentonite clay soil, as well as in mixtures. Nickel adsorption parameters from Freundlich and Langmuir isotherm models were obtained, exhibiting a better adjustment in the Freundlich model based on R² and RMSE criteria. Thus, the addition of bentonite clay improved the adsorption to nickel, and the cationic exchange capacity (CEC) was the property that considerably influenced the metal retention in the studied soils.

scholarly journals Green waste composting under GORE(R) cover membrane at industrial scale: physico-chemical properties and spectroscopic assessment

2019 ◽  
Vol 8 (S1) ◽  
pp. 385-397 ◽  
Author(s):  
Mutaz Al-Alawi ◽  
Tamas Szegi ◽  
Loubna El Fels ◽  
Mohamed Hafidi ◽  
Barbara Simon ◽  
...  
Keyword(s):  
New Technology ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Ftir Spectra ◽  
Industrial Scale ◽  
Agricultural Product ◽  
Green Waste ◽  
Physico Chemical ◽  
Mature Compost ◽  
Humification Degree

Abstract Purpose Green waste (GW) composting is of increasing importance to the waste management industry in addition being a useful agricultural product that is rich in nutrient and organic matter (OM). The combination of aerated static windrow with GORE(R) cover membrane and an air-floor aeration system is a relatively new industrial-scale composting technology that has not been previously explored. Therefore, the aim of this research study was to evaluate the effectiveness of composting GW using this new technology. Methods The composting process was monitored through changes in the physico-chemical properties, E4/6, and fourier transform infrared (FTIR) spectra. Results Disinfection requirements were met by holding composting temperature steady in the thermophilic range for 24 days. The technology greatly improved composting conditions, and final compost product in terms of temperature, pH, electrical conductivity (EC), C/N ratio, OM degradation, nitrogen transformation, humification, and cation exchange capacity (CEC). The FTIR spectra revealed that there was enrichment of aromatic compounds and reduction in aliphatic structures and easily assimilated peptide components by microorganisms, indicating the humification degree increased, the final compost stabilized, and confirming the efficiency of composting. Consequently, the new technology produced a mature compost in only 30 days compared with the standard period of 90–270 days for traditional composting. Conclusion Notably, the new technology may be a sustainable alternative for GW management that converts waste into compost and could be beneficial for agricultural uses.

scholarly journals   Potassium release kinetics and its correlation with pinto bean (Phaseolus vulgaris) plant indices

2012 ◽  
Vol 58 (No. 7) ◽  
pp. 328-333 ◽  
Author(s):  
A.R. Hosseinpur ◽  
H.R. Motaghian ◽  
M.H. Salehi
Keyword(s):  
Release Kinetics ◽  
Calcareous Soils ◽  
Bean Plant ◽  
Pinto Bean ◽  
Successive Extraction ◽  
Release Studies ◽  
Function Models ◽  
Kinetics Of ◽  
Total Reaction Time ◽  
K Release

The rate of potassium (K) release from soils is a dynamic process, and it is important to the evaluation of soil K availability to plant. The objectives of this study were to determine K release characteristics and the correlation of these parameters with bean plant indices in surface soils of 15 calcareous soils. The kinetics of K release was determined by successive extraction with 0.01 mol/L CaCl<sub>2</sub> in a period of 2&ndash;2017 h at 25 &plusmn; 1&deg;C. The results showed that the cumulative K&rlm; release ranged from 111 to 411 mg/kg. A plot of cumulative amount of K released showed a discontinuity in slope at 168 h. Thus, two equations were applied to segments of the total reaction time (2 to 168 and 168 to 2017 h). The amounts of K released during 2&ndash;168 and 168&ndash;2017 h ranged from 55 to 299 and 44 to 119 mg/kg, respectively. Release kinetics of K conformed fairly well to parabolic diffusion, simplified Elovich and power function models in two segments. Potassium released after 2&ndash;168 and 168&ndash;2017 h and K release rate constants were significantly correlated (P &lt; 0.05) with bean plant indices, while correlation between K extracted by using 1 mol/L NH<sub>4</sub>OAc (ammonium acetate) and plant indices was not significant. The results of this research showed that information obtained from K release studies in laboratory and kinetics equation parameters can help to estimate the K supplying power of soils. &nbsp;

scholarly journals A rainfall simulation study of erosion of some calcareous soils

2013 ◽  
Vol 3 (3) ◽  
pp. 179-183 ◽  
Keyword(s):  
Calcium Carbonate ◽  
Cation Exchange Capacity ◽  
Soil Loss ◽  
Clay Fraction ◽  
Calcareous Soils ◽  
Exchange Capacity ◽  
Rainfall Simulation ◽  
Runoff And Soil Loss ◽  
Raindrop Impact ◽  
Rain Simulator

In order to study the erodibility characteristics of some calcareous soils from Central Greece, the instability of aggregates of 2.0-4.7 mm in water was studied. Soil loss experiments were also conducted in the laboratory using a rain simulator where soil loss was measured and the soils’ attitude was studied under the conditions of simulated rainfall. It was found that the instability of aggregates is negatively correlated with cation exchange capacity and the total specific surface of soils. Also the calcium carbonate content affects positively the aggregates instability. The process which seems to control dominantly the time that runoff occurs and the runoff and soil loss quantity, is the creation of surface seals with raindrop impact due to large calcium carbonate quantities that are met in the clay fraction.

scholarly journals Mineralogical and physico–chemical properties of bentonites from the Jastrabá Formation (Kremnické vrchy Mts., Western Carpathians)

2019 ◽  
Vol 70 (5) ◽  
pp. 433-445 ◽  
Author(s):  
Marek Osacký ◽  
Tomáš Binčík ◽  
Tomáš Paľo ◽  
Peter Uhlík ◽  
Jana Madejová ◽  
...  
Keyword(s):  
Interlayer Space ◽  
Analytical Data ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Mineral Admixtures ◽  
The Past ◽  
Physico Chemical ◽  
The Mean ◽  
Increasing Demand ◽  
Total Specific Surface Area

Abstract In the past years an increasing demand for bentonites resulted in the opening of new bentonite deposits in the Jastrabá Formation. The shortage of information, in particular analytical data, on the bentonites from the newly opened Jastrabá Fm. deposits was the motivation for the current study. Smectite is the predominant mineral in all bulk bentonites from the new deposits. Its amount varied between 43 and 90 wt. %. The bulk bentonites also contain variable amounts (10–57 wt. %) of mineral admixtures such as feldspars, mica, opal-CT, kaolinite, quartz and sometimes goethite. The smectite mineral comprising the studied bentonites was montmorillonite. The octahedral Al in the structure of montmorillonite was partially substituted by Mg, and to a lesser extent by Fe. The interlayer space of montmorillonite is occupied predominantly by divalent exchangeable cations (Ca2+ and Mg2+). The dehydroxylation temperature of smectites (>600 °C) determined on the DTG curves indicates the presence of the cis-vacant variety of montmorillonites. The mean crystallite thicknesses of smectites (TMEAN) calculated by BWA analyses ranges from 7.2 to 11.5 nm. The shape of the crystallite thickness distributions (CTDs) for smectites is lognormal in all cases. Cation exchange capacity (CEC) and total specific surface area (TSSA) increases with increasing amount of smectite. The CEC of 101 meq/100g and TSSA of 616 m2/g correspond to bulk bentonite from the Stará Kremnička III deposit containing 89 wt. % of smectite.

scholarly journals Physico-chemical characteristics of the seasonally flooded soils of Bangladesh and their management implications

1970 ◽  
Vol 20 (2) ◽  
pp. 173-182
Author(s):  
KF Akhter ◽  
ZH Khan ◽  
MS Hussain ◽  
AR Mazumder
Keyword(s):  
Organic Matter ◽  
Organic Matter Content ◽  
Chemical Properties ◽  
Exchange Capacity ◽  
Matter Content ◽  
Flooded Soils ◽  
Management Implications ◽  
Available N ◽  
Physico Chemical ◽  
Seasonally Flooded

The seasonally flooded soils of Bangladesh are unique in respect of several specific characteristics and contribute toward producing bulk of its staple food - mainly rice. Having fine texture these soils are similar to the “paddy soils” of Southeast Asian floodplains and have high production potential under proper management. Six representative soil series, viz. Arial, Debidwar, Naraibag, Jalkundi, Siddirganj and Tippera from the central region of Bangladesh have been studied to evaluate some of their intrinsic physico-chemical properties and their sustainable management requirements. These soils are slightly acidic to neutral and are negatively charged with ΔpH values ranging between –0.2 and –1.2. The organic matter content in the surface soil is relatively low that decreases steadily with depth. The cation exchange capacity (CEC) of the soils varies on the basis of their clay and organic matter contents while base saturation per cent (BSP) is high. The contents of available N, P, K and S and DTPA-extractable Fe, Mn, Cu and Zn in soils are moderate and are commensurate with the contents of colloidal fractions. These soils receive several mineral nutrients annually with the sediments deposited during the monsoon floods. The characteristics like organic matter content, particle size distribution, CEC, pH and BSP that have important management implications have been discussed. Key words: Seasonally flooded soils; Physical and chemical attributes; Management implications DOI: http://dx.doi.org/10.3329/dujbs.v20i2.8978 DUJBS 2011; 20(2): 173-182

scholarly journals Physicochemical Parameters and Heavy Metals Content of Soil Samples from Farms in Minna

2015 ◽  
Vol 58 ◽  
pp. 154-163
Author(s):  
Z. Abdulhamid ◽  
E.B. Agbaji ◽  
C.E. Gimba ◽  
A.S. Agbaji
Keyword(s):  
Heavy Metals ◽  
Cation Exchange Capacity ◽  
Physicochemical Parameters ◽  
Chemical Properties ◽  
Absorption Spectrometry ◽  
Exchange Capacity ◽  
Average Concentration ◽  
Soil Samples ◽  
Ph Values ◽  
Physico Chemical

Physico-chemical properties and heavy metals content of soils were determined from seven farms in Minna, central Nigeria. Conventional analytical methods were employed to determine the physico-chemical properties and the heavy metals were analysed by atomic absorption spectrometry. The result showed that pH values ranged from 6.64 - 7.70 indicating slight acidity to slight alkalinity of the soils. The total organic carbon values ranged from 0.95-2.25 % resulting in the presence of organic matter (1.63-3.87). The electrical conductivity values ranged from 17-37 μS/cm. The cation exchange capacity of the soil samples ranged from 3.68-5.15 cmol/kg. The heavy metals levels were in the following range: Cd (0.00018-0.00134 mg/g), Cu (0.0069-0.0476 mg/g), Fe (1.942-2.2059 mg/g), Mn (0.1825-0.3696 mg/g), Ni (0.0065-0.0069 mg/g) and Zn (0.0157-0.2252 mg/g). The concentration of the metals in the soil samples varied according to the following trend: Fe>Mn>Zn> Cu>Ni>Cd. The average concentration of all the metals in each farm also gave the trend Farm B>Farm G>Farm E>Farm C>Farm F>Farm D>Farm A. The findings indicate the presence of heavy metals in all the farms but only Fe was above the FAO/WHO standards.

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