Non-radiative energy transfer mechanism and optoelectronic properties of (PFO/TiO2)/Fluorol 7GA hybrid thin films

Author(s):  
Bandar Ali Al-Asbahi ◽  
Mohammad Hafizuddin Haji Jumali
2021 ◽  
Vol 4 (4) ◽  
pp. 21002201-21002215
Author(s):  
Xiaotong Fan ◽  
◽  
Tingzhu Wu ◽  
Bin Liu ◽  
Rong Zhang ◽  
...  

Nano Energy ◽  
2019 ◽  
Vol 60 ◽  
pp. 457-466 ◽  
Author(s):  
Jayraj V. Vaghasiya ◽  
Keval K. Sonigara ◽  
Lakshmi Suresh ◽  
Majid Panahandeh-Fard ◽  
Saurabh S. Soni ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2094
Author(s):  
Bandar Ali Al-Asbahi ◽  
Saif M. H. Qaid ◽  
Hamid M. Ghaithan ◽  
Abdullah S. Aldwayyan

The triplet energy transfer mechanism of novel poly(9,9-di-n-octylflourenyl-2,7-diyl) (PFO)/poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV)/CsPbBr3 perovskite quantum dot (PQD) hybrid thin films was comprehensively investigated. The concentrations of PFO and MEH-PPV in all the specimens were fixed, while the PQD content was varied with various weight ratios and premixed by a solution blending method before it was spin-coated onto glass substrates. The triplet non-radiative Förster resonance energy transfers (FRETs) in the PFO/MEH-PPV/PQDs ternary blend, the dual FRET from PFO to both PQDs and MEH-PPV, and the secondary FRET from PQDs to MEH-PPV were observed. The values of the Förster radius (Ro) of FRET from PFO to MEH-PPV in the presence of various PQD contents (Case I) increased from 92.3 to 104.7 Å, and they decreased gradually from 68.0 to 39.5 Å for FRET from PFO to PQDs in the presence of MEH-PPV (Case II). These Ro values in both cases confirmed the dominance of FRET in ternary hybrid thin films. Upon increasing the PQD content, the distance between the donor and acceptor molecules (RDA) and the conjugation length (Aπ) in both cases gradually decreased. The small values of Ro, RDA, and Aπ with a decrease in the energy transfer lifetime (τET) due to an increase in the PQD contents in both Cases I and II confirmed the efficient FRET in the hybrid. To prevent intermolecular transfer in PFO, the concentrations of MEH-PPV (Case I) and PQDs (Case II) should be decreased to a range of 0.57–0.39 mM and increased in the range of 1.42–7.25 mM.


2013 ◽  
Vol 23 ◽  
pp. 23-26
Author(s):  
Karla J. Sánchez Pérez ◽  
J. C. García-Melgarejo ◽  
J. J. Sánchez-Mondragón

Among quantum dots there is an interaction called Foerster interaction, it consists on the transfer of one exciton from a quantum dot to another in a non-radiative energy transfer mechanism. In this work, we develop a model of the interaction of a pair of coupled Quan­tum Dots (QDs), each one in its own micro cavity, interacting with its own classical field.


2013 ◽  
Vol 142 ◽  
pp. 57-65 ◽  
Author(s):  
Bandar Ali Al-Asbahi ◽  
Mohammad Hafizuddin Haji Jumali ◽  
Chi Chin Yap ◽  
Moayad Husein Flaifel ◽  
Muhamad Mat Salleh

2021 ◽  
pp. 118082
Author(s):  
Hai Ma ◽  
Xiaodan Wang ◽  
Feifei Chen ◽  
Jiafan Chen ◽  
Xionghui Zeng ◽  
...  

2014 ◽  
Vol 13 (7) ◽  
pp. 1031-1038 ◽  
Author(s):  
Rebecca Flamini ◽  
Assunta Marrocchi ◽  
Anna Spalletti

An energy transfer mechanism, useful to enhance sunlight harvesting, was found to be operative in donor arylacetylenes’ blend thin films, leading to emission only from the bathochromic species, efficiently quenched by charge transfer to [60]PCBM.


2020 ◽  
Vol 49 (11) ◽  
pp. 2801-2809
Author(s):  
Sameer Albati ◽  
Mohammad Hafizuddin Hj. Jumali ◽  
Bandar Ali Al-Asbahi ◽  
Saif M.H. Qaid ◽  
Chi Chin Yap

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 444 ◽  
Author(s):  
Bandar Ali Al-Asbahi ◽  
Saif M. H. Qaid ◽  
Abdullah S. Aldwayyan

Composite materials with different concentration ratios of a hybrid of zero-dimensional (0-D) Cs4PbBr6 perovskite, which acts as a donor (D), and poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), which acts as an acceptor (A), were successfully prepared via a solution blending method prior to being deposited onto glass substrates by a spin-coating technique. The influence of acceptor content on the structural, optical, and energy transfer properties of the donor was investigated. The perovskite nanocrystals formed thin films without any chemical interactions within a matrix of MEH-PPV in the blend. The possibility of dipole–dipole (non-radiative) energy transfer from the 0-D Cs4PbBr6 to the MEH-PPV was proven. The energy transfer parameters such as Ro (critical distance of the energy transfer), kapp (apparent quenching constant), ∅ D A (quantum yield of D in the presence of A), τ D A (lifetime of D in the presence of A), PDA (probability of energy transfer), η (efficiency of energy transfer), RDA (energy transfer radius), kET (energy transfer rate constant), TDR (total decay rate), Ao (critical concentration of A), and Aπ (conjugation length) were calculated based on the absorption and emission measurements.


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