scholarly journals Simultaneous aerosol measurements of unusual aerosol enhancement in the troposphere over Syowa Station, Antarctica

2014 ◽  
Vol 14 (8) ◽  
pp. 4169-4183 ◽  
Author(s):  
K. Hara ◽  
M. Hayashi ◽  
M. Yabuki ◽  
M. Shiobara ◽  
C. Nishita-Hara
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Sea Salt ◽  
Free Troposphere ◽  
Syowa Station ◽  
Particle Counter ◽  
Air Masses ◽  
Optical Particle Counter ◽  
Strong Winds ◽  
Storm Condition

Abstract. Unusual aerosol enhancement is often observed at Syowa Station, Antarctica, during winter and spring. Simultaneous aerosol measurements near the surface and in the upper atmosphere were conducted twice using a ground-based optical particle counter, a balloon-borne optical particle counter, and micropulse lidar (MPL) in August and September 2012. During 13–15 August, aerosol enhancement occurred immediately after a storm condition. A high backscatter ratio and high aerosol concentrations were observed from the surface to ca. 2.5 km over Syowa Station. Clouds appeared occasionally at the top of the aerosol-enhanced layer during the episode. Aerosol enhancement was terminated on 15 August by strong winds from a cyclone's approach. In the second case, on 5–7 September, aerosol number concentrations in Dp > 0.3 μm near the surface reached > 104 L−1 at about 15:00 UT (Universal Time) on 5 September despite calm wind conditions, whereas MPL measurement exhibited aerosols were enhanced at about 04:00 UT at 1000–1500 m above Syowa Station. The aerosol enhancement occurred near the surface to ca. 4 km. In both cases, air masses with high aerosol enhancement below 2.5–3 km were transported mostly from the boundary layer over the sea-ice area. In addition, air masses at 3–4 km in the second case came from the boundary layer over the open-sea area. This air mass history strongly suggests that dispersion of sea-salt particles from the sea-ice surface contributes considerably to aerosol enhancement in the lower free troposphere (about 3 km) and that the release of sea-salt particles from the ocean surface engenders high aerosol concentrations in the free troposphere (3–4 km). Continuous MPL measurements indicate that high aerosol enhancement occurred mostly in surface–lower free troposphere (3 km) during the period July–September.

scholarly journals Simultaneous aerosol measurements of unusual aerosol enhancement in troposphere over Syowa Station, Antarctica

2013 ◽  
Vol 13 (10) ◽  
pp. 26269-26303
Author(s):  
K. Hara ◽  
M. Hayashi ◽  
M. Yabuki ◽  
M. Shiobara ◽  
C. Nishita-Hara
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Sea Salt ◽  
Free Troposphere ◽  
Syowa Station ◽  
Particle Counter ◽  
Air Masses ◽  
Optical Particle Counter ◽  
Strong Winds ◽  
Storm Condition

Abstract. Unusual aerosol enhancement is often observed at Syowa Station, Antarctica during winter through spring. Simultaneous aerosol measurements near the surface and in the upper atmosphere were conducted twice using a ground-based optical particle counter, a balloon-borne optical particle counter, and micro-pulse LIDAR (MPL) in August and September 2012. During 13–15 August, aerosol enhancement occurred immediately after a storm condition. A high backscatter ratio and aerosol concentrations were observed from the surface to ca. 2.5 km over Syowa Station. Clouds appeared occasionally at the top of aerosol-enhanced layer during the episode. Aerosol enhancement was terminated on 15 August by strong winds caused by a cyclone's approach. In the second case on 5–7 September, aerosol number concentrations in Dp > 0.3 μm near the surface reached > 104 L−1 at about 15:00 UT on 5 September in spite of calm wind conditions, whereas MPL measurement exhibited aerosols were enhanced at about 04:00 UT at 1000–1500 m above Syowa Station. The aerosol enhancement occurred near the surface–ca. 4 km. In both cases, air masses with high aerosol enhancement below 2.5–3 km were transported mostly from the boundary layer over the sea-ice area. In addition, air masses at 3–4 km in the second case came from the boundary layer over the open-sea area. This air mass history strongly suggests that dispersion of sea-salt particles from the sea-ice surface contributes considerably to the aerosol enhancement in the lower free troposphere (about 3 km) and that the release of sea-salt particles from the ocean surface engenders high aerosol concentrations in the free troposphere (3–4 km).

scholarly journals Unexpectedly high ultrafine aerosol concentrations above East Antarctic sea ice

2016 ◽  
Vol 16 (4) ◽  
pp. 2185-2206 ◽  
Author(s):  
R. S. Humphries ◽  
A. R. Klekociuk ◽  
R. Schofield ◽  
M. Keywood ◽  
J. Ward ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Southern Ocean ◽  
Sea Ice ◽  
Radiative Forcing ◽  
Free Troposphere ◽  
Radiative Balance ◽  
Air Masses ◽  
Antarctic Sea Ice ◽  
Ocean Region ◽  
The Antarctic

Abstract. Better characterisation of aerosol processes in pristine, natural environments, such as Antarctica, have recently been shown to lead to the largest reduction in uncertainties in our understanding of radiative forcing. Our understanding of aerosols in the Antarctic region is currently based on measurements that are often limited to boundary layer air masses at spatially sparse coastal and continental research stations, with only a handful of studies in the vast sea-ice region. In this paper, the first observational study of sub-micron aerosols in the East Antarctic sea ice region is presented. Measurements were conducted aboard the icebreaker Aurora Australis in spring 2012 and found that boundary layer condensation nuclei (CN3) concentrations exhibited a five-fold increase moving across the polar front, with mean polar cell concentrations of 1130 cm−3 – higher than any observed elsewhere in the Antarctic and Southern Ocean region. The absence of evidence for aerosol growth suggested that nucleation was unlikely to be local. Air parcel trajectories indicated significant influence from the free troposphere above the Antarctic continent, implicating this as the likely nucleation region for surface aerosol, a similar conclusion to previous Antarctic aerosol studies. The highest aerosol concentrations were found to correlate with low-pressure systems, suggesting that the passage of cyclones provided an accelerated pathway, delivering air masses quickly from the free troposphere to the surface. After descent from the Antarctic free troposphere, trajectories suggest that sea-ice boundary layer air masses travelled equatorward into the low-albedo Southern Ocean region, transporting with them emissions and these aerosol nuclei which, after growth, may potentially impact on the region's radiative balance. The high aerosol concentrations and their transport pathways described here, could help reduce the discrepancy currently present between simulations and observations of cloud and aerosol over the Southern Ocean.

scholarly journals Seasonal variations and vertical features of aerosol particles in the Antarctic troposphere

2011 ◽  
Vol 11 (3) ◽  
pp. 7555-7591 ◽  
Author(s):  
K. Hara ◽  
K. Osada ◽  
C. Nishita-Hara ◽  
T. Yamanouchi
Keyword(s):  
Seasonal Variations ◽  
Fine Particles ◽  
Austral Summer ◽  
Sea Salt ◽  
Coarse Particles ◽  
Free Troposphere ◽  
Syowa Station ◽  
Air Masses ◽  
Antarctic Expedition ◽  
The Antarctic

Abstract. Tethered balloon-borne aerosol measurements were conducted at Syowa Station, Antarctica during the 46th Japanese Antarctic expedition (2005–2006). The CN concentration reached a maximum in the summer, although the number concentrations of fine particles (Dp > 0.3 μm) and coarse particles (Dp > 2.0 μm) increased during the winter-spring. The CN concentration was 30–2200 cm−3 near the surface (surface – 500 m) and 7–7250 cm−3 in the lower free troposphere (>1500 m). During the austral summer, higher CN concentration was often observed in the lower free troposphere, where the number concentrations in fine and coarse modes were remarkably lower. The frequent appearance of higher CN concentrations in the free troposphere relative to continuous aerosol measurements at the ground strongly suggests that new particle formation is more likely to occur in the lower free troposphere in Antarctic regions. Seasonal variations of size distribution of fine-coarse particles show that the contribution of the coarse mode was greater in the winter-spring than in summer because of the dominance of sea-salt particles in the winter-spring. The number concentrations of fine and coarse particles were high in air masses from the ocean and mid-latitudes. Particularly, aerosol enhancement was observed not only in the boundary layer but also in the lower free troposphere during and immediately after Antarctic haze events occurring in May, July, and September.

scholarly journals Unexpectedly high ultrafine aerosol concentrations above East Antarctic sea-ice

2015 ◽  
Vol 15 (20) ◽  
pp. 29125-29170 ◽  
Author(s):  
R. S. Humphries ◽  
A. R. Klekociuk ◽  
R. Schofield ◽  
M. Keywood ◽  
J. Ward ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Southern Ocean ◽  
Sea Ice ◽  
Radiative Properties ◽  
Free Troposphere ◽  
Air Masses ◽  
Antarctic Sea Ice ◽  
Ocean Region ◽  
The Antarctic ◽  
Natural Aerosol

Abstract. The effect of aerosols on clouds and their radiative properties is one of the largest uncertainties in our understanding of radiative forcing. A recent study has concluded that better characterisation of pristine, natural aerosol processes leads to the largest reduction in these uncertainties. Antarctica, being far from anthropogenic activities, is an ideal location for the study of natural aerosol processes. Aerosol measurements in Antarctica are often limited to boundary layer air-masses at spatially sparse coastal and continental research stations, with only a handful of studies in the sea ice region. In this paper, the first observational study of sub-micron aerosols in the East Antarctic sea ice region is presented. Measurements were conducted aboard the ice-breaker Aurora Australis in spring 2012 and found that boundary layer condensation nuclei (CN3) concentrations exhibited a five-fold increase moving across the Polar Front, with mean Polar Cell concentrations of 1130 cm−3 – higher than any observed elsewhere in the Antarctic and Southern Ocean region. The absence of evidence for aerosol growth suggested that nucleation was unlikely to be local. Air parcel trajectories indicated significant influence from the free troposphere above the Antarctic continent, implicating this as the likely nucleation region for surface aerosol, a similar conclusion to previous Antarctic aerosol studies. The highest aerosol concentrations were found to correlate with low pressure systems, suggesting that the passage of cyclones provided an accelerated pathway, delivering air-masses quickly from the free-troposphere to the surface. After descent from the Antarctic free troposphere, trajectories suggest that sea ice boundary layer air-masses travelled equator-ward into the low albedo Southern Ocean region, transporting with them emissions and these aerosol nuclei where, after growth, may potentially impact on the region's radiative balance. The high aerosol concentrations and their transport pathways described here, could help reduce the discrepancy currently present between simulations and observations of cloud and aerosol over the Southern Ocean.

scholarly journals Tethered balloon-borne aerosol measurements: seasonal and vertical variations of aerosol constituents over Syowa Station, Antarctica

2013 ◽  
Vol 13 (3) ◽  
pp. 8153-8211
Author(s):  
K. Hara ◽  
K. Osada ◽  
T. Yamanouchi
Keyword(s):  
Boundary Layer ◽  
Relative Abundance ◽  
Lower Troposphere ◽  
Sea Salt ◽  
Heterogeneous Reactions ◽  
Aerosol Sampling ◽  
Free Troposphere ◽  
Tethered Balloon ◽  
Syowa Station ◽  
Salt Fractionation

Abstract. Tethered balloon-borne aerosol measurements were conducted at Syowa Station, Antarctica during the 46th Japanese Antarctic expedition (2005–2006). Direct aerosol sampling was operated from near the surface to the lower free troposphere (approximately 2500 m) using a balloon-borne aerosol impactor. Individual aerosol particles were analyzed using a scanning electron microscope equipped with an energy dispersive X-ray spectrometer. Seasonal and vertical features of aerosol constituents and their mixing states were investigated. Results show that sulfate particles were dominant in the boundary layer and lower free troposphere in the summer, whereas sea-salt particles were dominant during winter–spring. Minerals, MgSO4, and sulfate containing K were identified as minor aerosol constituents in both boundary layer and free troposphere over Syowa Station. Although sea-salt particles were dominant during winter–spring, the relative abundance of sulfate particles increased in the boundary layer when air masses fell from the free troposphere over the Antarctic coast and continent. Sea-salt particles were modified considerably through heterogeneous reactions with SO42−, CH3SO3−, and their precursors during the summer, and were modified slightly through heterogeneous reactions with NO3− and its precursors. During winter–spring, sea-salt modification was insignificant, particularly in the cases of high relative abundance of sea-salt particles and higher number concentrations. In August, NO3− and its precursors contributed greatly to sea-salt modification over Syowa Station. Because of the occurrence of sea-salt fractionation on sea-ice, Mg-rich sea-salt particles were identified during April–November. In contrast, Mg-free sea-salt particles and slightly Mg-rich sea-salt particles co-existed in the lower troposphere during summer. Thereby, Mg separation can proceed by sea-salt fractionation during summer in Antarctic regions.

scholarly journals Seasonal variations and vertical features of aerosol particles in the Antarctic troposphere

2011 ◽  
Vol 11 (11) ◽  
pp. 5471-5484 ◽  
Author(s):  
K. Hara ◽  
K. Osada ◽  
C. Nishita-Hara ◽  
T. Yamanouchi
Keyword(s):  
Seasonal Variations ◽  
Fine Particles ◽  
Austral Summer ◽  
Sea Salt ◽  
Coarse Particles ◽  
Free Troposphere ◽  
Syowa Station ◽  
Air Masses ◽  
Antarctic Expedition ◽  
The Antarctic

Abstract. Tethered balloon-borne aerosol measurements were conducted at Syowa Station, Antarctica during the 46th Japanese Antarctic expedition (2005–2006). The CN concentration reached a maximum in the summer, although the number concentrations of fine particles (Dp>0.3 μm) and coarse particles (Dp>2.0 μm) increased during the winter–spring. The CN concentration was 30–2200 cm−3 near the surface (surface – 500 m) and 7–7250 cm−3 in the lower free troposphere (>1500 m). During the austral summer, higher CN concentration was often observed in the lower free troposphere, where the number concentrations in fine and coarse modes were remarkably lower. The frequent appearance of higher CN concentrations in the free troposphere relative to continuous aerosol measurements at the ground strongly suggests that new particle formation is more likely to occur in the lower free troposphere in Antarctic regions. Seasonal variations of size distribution of fine-coarse particles show that the contribution of the coarse mode was greater in the winter–spring than in summer because of the dominance of sea-salt particles in the winter–spring. The number concentrations of fine and coarse particles were high in air masses from the ocean and mid-latitudes. Particularly, aerosol enhancement was observed not only in the boundary layer, but also in the lower free troposphere during and immediately after Antarctic haze events occurring in May, July and September.

scholarly journals Tethered balloon-borne aerosol measurements: seasonal and vertical variations of aerosol constituents over Syowa Station, Antarctica

2013 ◽  
Vol 13 (17) ◽  
pp. 9119-9139 ◽  
Author(s):  
K. Hara ◽  
K. Osada ◽  
T. Yamanouchi
Keyword(s):  
Boundary Layer ◽  
Relative Abundance ◽  
Lower Troposphere ◽  
Sea Salt ◽  
Heterogeneous Reactions ◽  
Aerosol Sampling ◽  
Free Troposphere ◽  
Tethered Balloon ◽  
Syowa Station ◽  
Salt Fractionation

Abstract. Tethered balloon-borne aerosol measurements were conducted at Syowa Station, Antarctica, during the 46th Japanese Antarctic expedition (2005–2006). Direct aerosol sampling was operated from near the surface to the lower free troposphere (approximately 2500 m) using a balloon-borne aerosol impactor. Individual aerosol particles were analyzed using a scanning electron microscope equipped with an energy dispersive X-ray spectrometer. Seasonal and vertical features of aerosol constituents and their mixing states were investigated. Results show that sulfate particles were predominant in the boundary layer and lower free troposphere in summer, whereas sea-salt particles were predominant during winter through spring. Minerals, MgSO4, and sulfate containing K were identified as minor aerosol constituents in both boundary layer and free troposphere over Syowa Station. Although sea-salt particles were predominant during winter through spring, the relative abundance of sulfate particles increased in the boundary layer when air masses fell from the free troposphere over the Antarctic coast and continent. Sea-salt particles were modified considerably through heterogeneous reactions with SO42− CH3SO3− and their precursors during summer, and were modified slightly through heterogeneous reactions with NO3− and its precursors. During winter through spring, sea-salt modification was insignificant, particularly in the cases of high relative abundance of sea-salt particles and higher number concentrations. In August, NO3− and its precursors contributed greatly to sea-salt modification over Syowa Station. Because of the occurrence of sea-salt fractionation on sea ice, Mg-rich sea-salt particles were identified during the months of April through November. In contrast, Mg-free sea-salt particles and slightly Mg-rich sea-salt particles coexisted in the lower troposphere during summer. Thereby, Mg separation can proceed by sea-salt fractionation during summer in Antarctic regions.

scholarly journals Multivariate statistical air mass classification for the high-alpine observatory at the Zugspitze Mountain, Germany

2019 ◽  
Vol 19 (19) ◽  
pp. 12477-12494 ◽  
Author(s):  
Armin Sigmund ◽  
Korbinian Freier ◽  
Till Rehm ◽  
Ludwig Ries ◽  
Christian Schunk ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Real Time ◽  
Statistical Approach ◽  
Free Troposphere ◽  
Time Data ◽  
Detection Scheme ◽  
Air Mass ◽  
Thermally Induced ◽  
Air Masses ◽  
Mechanistic Approach

Abstract. To assist atmospheric monitoring at high-alpine sites, a statistical approach for distinguishing between the dominant air masses was developed. This approach was based on a principal component analysis using five gas-phase and two meteorological variables. The analysis focused on the Schneefernerhaus site at Zugspitze Mountain, Germany. The investigated year was divided into 2-month periods, for which the analysis was repeated. Using the 33.3 % and 66.6 % percentiles of the first two principal components, nine air mass regimes were defined. These regimes were interpreted with respect to vertical transport and assigned to the BL (recent contact with the boundary layer), UFT/SIN (undisturbed free troposphere or stratospheric intrusion), and HYBRID (influences of both the boundary layer and the free troposphere or ambiguous) air mass classes. The input data were available for 78 % of the investigated year. BL accounted for 31 % of the cases with similar frequencies in all seasons. UFT/SIN comprised 14 % of the cases but was not found from April to July. HYBRID (55 %) mostly exhibited intermediate characteristics, whereby 17 % of the HYBRID class suggested an influence from the marine boundary layer or the lower free troposphere. The statistical approach was compared to a mechanistic approach using the ceilometer-based mixing layer height from a nearby valley site and a detection scheme for thermally induced mountain winds. Due to data gaps, only 25 % of the cases could be classified using the mechanistic approach. Both approaches agreed well, except in the rare cases of thermally induced uplift. The statistical approach is a promising step towards a real-time classification of air masses. Future work is necessary to assess the uncertainty arising from the standardization of real-time data.

scholarly journals The role of open lead interactions in atmospheric ozone variability between Arctic coastal and inland sites

Elem Sci Anth ◽  
2016 ◽  
Vol 4 ◽  
Author(s):  
Peter K. Peterson ◽  
Kerri A. Pratt ◽  
William R. Simpson ◽  
Son V. Nghiem ◽  
Lemuel X. Pérez Pérez ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Sea Ice ◽  
Ozone Depletion ◽  
Surface Ozone ◽  
Optical Absorption Spectroscopy ◽  
Atmospheric Ozone ◽  
Vertical Profiles ◽  
Large Spatial Scale ◽  
Near Surface ◽  
Air Masses

Abstract Boundary layer atmospheric ozone depletion events (ODEs) are commonly observed across polar sea ice regions following polar sunrise. During March-April 2005 in Alaska, the coastal site of Barrow and inland site of Atqasuk experienced ODEs (O3< 10 nmol mol-1) concurrently for 31% of the observations, consistent with large spatial scale ozone depletion. However, 7% of the time ODEs were exclusively observed inland at Atqasuk. This phenomenon also occurred during one of nine flights during the BRomine, Ozone, and Mercury EXperiment (BROMEX), when atmospheric vertical profiles at both sites showed near-surface ozone depletion only at Atqasuk on 28 March 2012. Concurrent in-flight BrO measurements made using nadir scanning differential optical absorption spectroscopy (DOAS) showed the differences in ozone vertical profiles at these two sites could not be attributed to differences in locally occurring halogen chemistry. During both studies, backward air mass trajectories showed that the Barrow air masses observed had interacted with open sea ice leads, causing increased vertical mixing and recovery of ozone at Barrow and not Atqasuk, where the air masses only interacted with tundra and consolidated sea ice. These observations suggest that, while it is typical for coastal and inland sites to have similar ozone conditions, open leads may cause heterogeneity in the chemical composition of the springtime Arctic boundary layer over coastal and inland areas adjacent to sea ice regions.

scholarly journals Identifying source regions of air masses sampled at the tropical high-altitude site of Chacaltaya using WRF-FLEXPART and cluster analysis

2021 ◽  
Author(s):  
Diego Aliaga ◽  
Victoria A. Sinclair ◽  
Marcos Andrade ◽  
Paulo Artaxo ◽  
Samara Carbone ◽  
...  
Keyword(s):  
Boundary Layer ◽  
High Altitude ◽  
Long Range ◽  
Diurnal Cycle ◽  
Observation Time ◽  
Particle Nucleation ◽  
Free Troposphere ◽  
Air Mass ◽  
Air Masses ◽  
Source Regions

Abstract. Observations of aerosol and trace gases in the remote troposphere are vital to quantify background concentrations and identify long term trends in atmospheric composition on large spatial scales. Measurements made at high altitude are often used to study free tropospheric air however such high-altitude sites can be influenced by boundary layer air masses. Thus, accurate information on air mass origin and transport pathways to high altitude sites is required. Here we present a new method, based on the source-receptor relationship (SRR) obtained from backwards WRF-FLEXPART simulations and a k-means clustering approach, to identify source regions of air masses arriving at measurement sites. Our method is tailored to areas of complex terrain and to stations influenced by both local and long-range sources. We have applied this method to the Chacaltaya (CHC) GAW station (5240 m a.s.l.,16.35° S, 68.13° W) for the 6-month duration of the “Southern hemisphere high altitude experiment on particle nucleation and growth” (SALTENA) to identify where sampled air masses originate and to quantify the influence of the boundary layer and the free troposphere. A key aspect of our method is that it is probabilistic and for each observation time, more than one air mass (cluster) can influence the station and the percentage influence of each air mass can be quantified. This is in contrast to binary methods, which label each observation time as influenced either by boundary layer or free troposphere air masses. We find that on average, 9% of the air sampled at CHC, at any given observation time, has been in contact with the surface within 4 days prior to arriving at CHC, 24% of the air was located below 1.5 km above ground level and consequently, 76% of the measured air masses at CHC represent free tropospheric air. However, pure free-tropospheric influences are rare and often samples are concurrently influenced by both boundary-layer and free-tropospheric air masses. A clear diurnal cycle is present with very few air masses that have been in contact with the surface being detected at night. The 6-month analysis also shows that the most dominant air mass (cluster) originates in the Amazon and is responsible for 29% of the sampled air. Furthermore, short-range clusters (origins within 100 km of CHC) have high temporal frequency modulated by local meteorology driven by the diurnal cycle whereas the mid- and long-range clusters’ (>200 km) variability occurs on timescales governed by synoptic-scale dynamics. To verify the reliability of our method, in-situ sulfate observations from CHC are combined with the SRR clusters to correctly identify the (pre-known) source of the sulfate: the Sabancaya volcano located 400 km northwest from the station.

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