scholarly journals How to most effectively expand the global surface ozone observing network

2016 ◽  
Vol 16 (3) ◽  
pp. 1445-1457 ◽  
Author(s):  
E. D. Sofen ◽  
D. Bowdalo ◽  
M. J. Evans

Abstract. Surface ozone observations with modern instrumentation have been made around the world for more than 40 years. Some of these observations have been made as one-off activities with short-term, specific science objectives and some have been made as part of wider networks which have provided a foundational infrastructure of data collection, calibration, quality control, and dissemination. These observations provide a fundamental underpinning to our understanding of tropospheric chemistry, air quality policy, atmosphere–biosphere interactions, etc. brought together eight of these networks to provide a single data set of surface ozone observations. We investigate how representative this combined data set is of global surface ozone using the output from a global atmospheric chemistry model. We estimate that on an area basis, 25 % of the globe is observed (34 % land, 21 % ocean). Whereas Europe and North America have almost complete coverage, other continents, Africa, South America, Australia, and Asia (12–17 %) show significant gaps. Antarctica is surprisingly well observed (78 %). Little monitoring occurs over the oceans, with the tropical and southern oceans particularly poorly represented. The surface ozone over key biomes such as tropical forests and savanna is almost completely unmonitored. A chemical cluster analysis suggests that a significant number of observations are made of polluted air masses, but cleaner air masses whether over the land or ocean (especially again in the tropics) are significantly under-observed. The current network is unlikely to see the impact of the El Niño–Southern Oscillation (ENSO) but may be capable of detecting other planetary-scale signals. Model assessment and validation activities are hampered by a lack of observations in regions where the models differ substantially, as is the ability to monitor likely changes in surface ozone over the next century. Using our methodology we are able to suggest new sites which would help to close the gap in our ability to measure global surface ozone. An additional 20 surface ozone monitoring sites (a 20 % increase in the World Meteorological Organization Global Atmosphere Watch (WMO GAW) ozone sites or a 1 % increase in the total background network) located on 10 islands and in 10 continental regions would almost double the area observed. The cost of this addition to the network is small compared to other expenditure on atmospheric composition research infrastructure and would provide a significant long-term benefit to our understanding of the composition of the atmosphere, information which will also be available for consideration by air quality control managers and policy makers.

2015 ◽  
Vol 15 (15) ◽  
pp. 21025-21061
Author(s):  
E. D. Sofen ◽  
D. Bowdalo ◽  
M. J. Evans

Abstract. Surface ozone observations with modern instrumentation have been made around the world for almost 50 years. Some of these observations have been made as one-off activities with short term, specific science objectives and some have been made as part of wider networks which have provided a foundational infrastructure of data collection, calibration, quality control and dissemination. These observations provide a fundamental underpinning to our understanding of tropospheric chemistry, air quality policy, atmosphere-biosphere interactions, etc. Sofen et al. (2015) brought together 8 of these networks to provide a single dataset of surface ozone observations. We investigate how representative this combined dataset is of global surface ozone using the output from a global atmospheric chemistry model. We estimate that on an area basis, 25 % of the globe is observed (34 % land, 21 % ocean). Whereas Europe and North America have almost complete coverage, other continents such as Africa, South America and Asia (12–17 %) show significant gaps. Antarctica is surprisingly well observed (78 %). Little monitoring occurs over the oceans with the tropical and southern oceans particularly poorly represented. The surface ozone over key biomes such as tropical forests and savanna is almost completely unmonitored. A chemical cluster analysis suggests that a significant number of observations are made of polluted air masses, but cleaner air masses whether over the land or ocean (especially again in the tropics) are significantly under observed. The current network is unlikely to see the impact of ENSO but may be capable of detecting other planetary scale signals. Model assessment and validation activities are hampered by a lack of observations in regions where they models differ substantially, as is the ability to monitor likely changes in surface ozone over the next century. Using our methodology we are able to suggest new sites which would help to close the gap in our ability to measure global surface ozone. An additional 20 surface ozone monitoring sites (a 20 % increase in the WMO GAW ozone sites or a 1 % increase in the total background network) located on 10 islands and in 10 continental regions would almost double the area observed. The cost of this addition to the network is small compared to other expenditure on atmospheric composition research infrastructure and would provide a significant long term benefit to our understanding of the composition of the atmosphere and in the development of policy.


2009 ◽  
Vol 9 (12) ◽  
pp. 4115-4129 ◽  
Author(s):  
N. Unger ◽  
S. Menon ◽  
D. M. Koch ◽  
D. T. Shindell

Abstract. The development of effective emissions control policies that are beneficial to both climate and air quality requires a detailed understanding of all the feedbacks in the atmospheric composition and climate system. We perform sensitivity studies with a global atmospheric composition-climate model to assess the impact of aerosols on tropospheric chemistry through their modification on clouds, aerosol-cloud interactions (ACI). The model includes coupling between both tropospheric gas-phase and aerosol chemistry and aerosols and liquid-phase clouds. We investigate past impacts from preindustrial (PI) to present day (PD) and future impacts from PD to 2050 (for the moderate IPCC A1B scenario) that embrace a wide spectrum of precursor emission changes and consequential ACI. The aerosol indirect effect (AIE) is estimated to be −2.0 Wm−2 for PD-PI and −0.6 Wm−2 for 2050-PD, at the high end of current estimates. Inclusion of ACI substantially impacts changes in global mean methane lifetime across both time periods, enhancing the past and future increases by 10% and 30%, respectively. In regions where pollution emissions increase, inclusion of ACI leads to 20% enhancements in in-cloud sulfate production and ~10% enhancements in sulfate wet deposition that is displaced away from the immediate source regions. The enhanced in-cloud sulfate formation leads to larger increases in surface sulfate across polluted regions (~10–30%). Nitric acid wet deposition is dampened by 15–20% across the industrialized regions due to ACI allowing additional re-release of reactive nitrogen that contributes to 1–2 ppbv increases in surface ozone in outflow regions. Our model findings indicate that ACI must be considered in studies of methane trends and projections of future changes to particulate matter air quality.


2013 ◽  
Vol 13 (24) ◽  
pp. 12215-12231 ◽  
Author(s):  
Z. S. Stock ◽  
M. R. Russo ◽  
T. M. Butler ◽  
A. T. Archibald ◽  
M. G. Lawrence ◽  
...  

Abstract. We examine the effects of ozone precursor emissions from megacities on present-day air quality using the global chemistry–climate model UM-UKCA (UK Met Office Unified Model coupled to the UK Chemistry and Aerosols model). The sensitivity of megacity and regional ozone to local emissions, both from within the megacity and from surrounding regions, is important for determining air quality across many scales, which in turn is key for reducing human exposure to high levels of pollutants. We use two methods, perturbation and tagging, to quantify the impact of megacity emissions on global ozone. We also completely redistribute the anthropogenic emissions from megacities, to compare changes in local air quality going from centralised, densely populated megacities to decentralised, lower density urban areas. Focus is placed not only on how changes to megacity emissions affect regional and global NOx and O3, but also on changes to NOy deposition and to local chemical environments which are perturbed by the emission changes. The perturbation and tagging methods show broadly similar megacity impacts on total ozone, with the perturbation method underestimating the contribution partially because it perturbs the background chemical environment. The total redistribution of megacity emissions locally shifts the chemical environment towards more NOx-limited conditions in the megacities, which is more conducive to ozone production, and monthly mean surface ozone is found to increase up to 30% in megacities, depending on latitude and season. However, the displacement of emissions has little effect on the global annual ozone burden (0.12% change). Globally, megacity emissions are shown to contribute ~3% of total NOy deposition. The changes in O3, NOx and NOy deposition described here are useful for quantifying megacity impacts and for understanding the sensitivity of megacity regions to local emissions. The small global effects of the 100% redistribution carried out in this study suggest that the distribution of emissions on the local scale is unlikely to have large implications for chemistry–climate processes on the global scale.


2020 ◽  
Vol 237 ◽  
pp. 03012
Author(s):  
Christoph Senff ◽  
Andrew Langford ◽  
Raul Alvarez ◽  
Tim Bonin ◽  
Alan Brewer ◽  
...  

Recently, two air quality campaigns were conducted in the southwestern United States to study the impact of transported ozone, stratospheric intrusions, and fire emissions on ground-level ozone concentrations. The California Baseline Ozone Transport Study (CABOTS) took place in May – August 2016 covering the central California coast and San Joaquin Valley, and the Fires, Asian, and Stratospheric Transport Las Vegas Ozone Study (FAST-LVOS) was conducted in the greater Las Vegas, Nevada area in May – June 2017. During these studies, nearly 1000 hours of ozone and aerosol profile data were collected with the NOAA TOPAZ lidar. A Doppler wind lidar and a radar wind profiler provided continuous observations of atmospheric turbulence, horizontal winds, and mixed layer height. These measurements allowed us to directly observe the degree to which ozone transport layers aloft were entrained into the boundary layer and to quantify the resulting impact on surface ozone levels. Mixed layer heights in the San Joaquin Valley during CABOTS were generally below 1 km above ground level (AGL), while boundary layer heights in Las Vegas during FAST-LVOS routinely exceeded 3 km AGL and occasionally reached up to 4.5 km AGL. Consequently, boundary layer entrainment was more often observed during FAST-LVOS, while most elevated ozone layers passed untapped over the San Joaquin Valley during CABOTS.


2008 ◽  
Vol 8 (5) ◽  
pp. 18323-18384 ◽  
Author(s):  
S. B. Dalsøren ◽  
M. S. Eide ◽  
Ø. Endresen ◽  
A. Mjelde ◽  
G. Gravir ◽  
...  

Abstract. A reliable and up-to-date ship emission inventory is essential for atmospheric scientists quantifying the impact of shipping and for policy makers implementing regulations and incentives for emission reduction. The emission modelling in this study takes into account ship type and size dependent input data for 15 ship types and 7 size categories. Global port arrival and departure data for more than 32 000 merchant ships are used to establish operational profiles for the ship segments. The modelled total fuel consumption amounts to 217 Mt in 2004 of which 11 Mt is consumed in in-port operations. This is in agreement with international sales statistics. The modelled fuel consumption is applied to develop global emission inventories for CO2, NO2, SO2, CO, CH4, VOC (Volatile Organic Compounds), N2O, BC (Black Carbon) and OC (Organic Carbon). The global emissions from ships at sea and in ports are distributed geographically, applying extended geographical data sets covering about 2 million global ship observations and global port data for 32 000 ships. In addition to inventories for the world fleet, inventories are produced separately for the three dominating ship types, using ship type specific emission modelling and traffic distributions. A global Chemical Transport Model (CTM) was used to calculate the environmental impacts of the emissions. We find that ship emissions is a dominant contributor over much of the world oceans to surface concentrations of NO2 and SO2. The contribution is also large over some coastal zones. For surface ozone the contribution is high over the oceans but clearly also of importance over western North America (contribution 15–25%) and western Europe (5–15%). The contribution to tropospheric column ozone is up to 5–6%. The overall impact of ship emissions on global methane lifetime is large due to the high NOx emissions. With regard to acidification we find that ships contribute 11% to nitrate wet deposition and 4.5% to sulphur wet deposition globally. In certain coastal regions the contributions may be in the range 15–50%. In general we find that ship emissions have a large impact on acidic deposition and surface ozone in western North America, Scandinavia, western Europe, western North Africa and Malaysia/Indonesia. For most of these regions container traffic, the largest emitter by ship type, has the largest impact. This is the case especially for the Pacific and the related container trade routes between Asia and North America. However, the contributions from bulk ships and tank vessels are also significant in the above mentioned impact regions. Though the total ship impact at low latitudes is lower, the tank vessels have a quite large contribution at low latitudes and near the Gulf of Mexico and Middle East. The bulk ships are characterized by large impact in Oceania compared to other ship types. In Scandinavia and north-western Europe, one of the major ship impact regions, the three largest ship types have rather small relative contributions. The impact in this region is probably dominated by smaller ships operating closer to the coast. For emissions in ports impacts on NO2 and SO2 seem to be of significance. For most ports the contribution to the two components is in the range 0.5–5%, for a few ports it exceeds 10%. The approach presented provides an improvement in characterizing fleet operational patterns, and thereby ship emissions and impacts. Furthermore, the study shows where emission reductions can be applied to most effectively minimize the impacts by different ship types.


2019 ◽  
Author(s):  
Lang Wang ◽  
Amos P. K. Tai ◽  
Chi-Yung Tam ◽  
Mehliyar Sadiq ◽  
Peng Wang ◽  
...  

Abstract. Surface ozone (O3) is an important air pollutant and greenhouse gas. Land use and land cover (LULC) is one of the critical factors influencing ozone, in addition to anthropogenic emissions and climate. LULC change can on the one hand affect ozone biogeochemically, i.e., via dry deposition and biogenic emissions of volatile organic compounds (VOCs). LULC change can on the other hand alter regional- to large-scale climate through modifying albedo and evapotranspiration, which can lead to changes in surface temperature, hydrometeorology and atmospheric circulation that can ultimately impact ozone biogeophysically over local and remote areas. Such biogeophysical effects of LULC on ozone are largely understudied. This study investigates the individual and combined biogeophysical and biogeochemical effects of LULC on ozone, and explicitly examines the critical pathway for how LULC change impacts ozone pollution. A global coupled atmosphere–chemistry–land model is driven by projected LULC changes from the present day (2000) to future (2050) under RCP4.5 and RCP8.5 scenarios, focusing on the boreal summer. Results reveal that when considering biogeochemical effects only, surface ozone is predicted to have slight changes by up to 2 ppbv maximum in some areas due to LULC changes. It is primarily driven by changes in isoprene emission and dry deposition counteracting each other in shaping ozone. In contrast, when considering the integrated effect of LULC, ozone is more substantially altered by up to 6 ppbv over several regions, reflecting the importance of biogeophysical effects on ozone changes. Furthermore, large areas of these ozone changes are found over the regions without LULC changes where the biogeophysical effect is the only pathway for such changes. The mechanism is likely that LULC change induces a regional circulation response, in particular the formation of anomalous stationary high-pressure systems, shifting of moisture transport, and near-surface warming over the middle-to-high northern latitudes in boreal summer, owing to associated changes in albedo and surface energy budget. Such temperature changes then alter ozone substantially. We conclude that the biogeophysical effect of LULC is an important pathway for the influence of LULC change on ozone air quality over both local and remote regions, even in locations without significant LULC changes. Overlooking the impact of biogeophysical effect may cause evident underestimation of the impacts of LULC change on ozone pollution.


2019 ◽  
Author(s):  
Yugo Kanaya ◽  
Kazuyuki Miyazaki ◽  
Fumikazu Taketani ◽  
Takuma Miyakawa ◽  
Hisahiro Takashima ◽  
...  

Abstract. Constraints from ozone (O3) observations over oceans are needed in addition to those from terrestrial regions to fully understand global tropospheric chemistry and its impact on the climate. Here, we provide a large data set of ozone and carbon monoxide (CO) levels observed (for 11 666 and 10 681 h, respectively) over oceans. The data set is derived from observations made during 24 research cruise legs of R/V Mirai during 2012 to 2017, in the Southern, Indian, Pacific, and Arctic Oceans, covering the region from 67° S to 75° N. The data are suitable for critical evaluation of the over-ocean distribution of ozone derived from chemical transport models. We first give an overview of the statistics in the data set and highlight key features in terms of geographical distribution and air mass type. We then use the data set to evaluate ozone concentration fields from Tropospheric Chemistry Reanalysis version 2 (TCR-2), produced by assimilating a suite of satellite observations of multiple species into a chemical transport model, namely CHASER. For long-range transport of polluted air masses from continents to the oceans, during which the effects of forest fires and fossil fuel combustion were recognized, TCR-2 gave an excellent performance in reproducing the observed temporal variations and photochemical buildup of O3 when assessed from ΔO3 / ΔCO ratios. For clean marine conditions with low and stable CO concentrations, two focused analyses were performed. The first was in the Arctic (> 70° N) in September every year from 2013 to 2016; TCR-2 underpredicted O3 levels by 6.7 ppb (21 %) on average. The observed vertical profiles from O3 soundings from R/V Mirai during September 2014 had less steep vertical gradients at low altitudes (> 850 hPa) than those obtained TCR-2. This suggests the possibilities of more efficient descent of the O3-rich air from above or less efficient dry deposition on the surface than were assumed in the model. In the second analysis, over the western Pacific equatorial region (125–165° E, 10° S to 25° N), the observed O3 level frequently decreased to less than 10 ppb in comparison to that obtained with TCR-2, and also those obtained in most of the Atmospheric Chemistry Climate Model Intercomparison Project (ACCMIP) model runs for the decade from 2000. These results imply loss processes that are unaccounted for in the models. We found that the model’s positive bias positively correlated with the daytime residence times of air masses over a particular grid, namely 165–180° E and 15–30° N; an additional loss rate of 0.25 ppb h−1 in the grid best explained the gap. Halogen chemistry, which is commonly omitted from currently used models, might be active in this region and could have contributed to additional losses. Our open data set covering wide ocean regions is complementary to the Tropospheric Ozone Assessment Report data set, which basically comprises ground-based observations, and enables a fully global study of the behavior of O3.


2016 ◽  
Author(s):  
Carlos Ordóñez ◽  
David Barriopedro ◽  
Ricardo García-Herrera ◽  
Pedro M. Sousa ◽  
Jordan L. Schnell

Abstract. This paper analyses for the first time the impact of high-latitude blocks and subtropical ridges on near-surface ozone in Europe during a 15-year period. For this purpose, a catalogue of blocks and ridges over the Euro-Atlantic region is used together with a gridded dataset of maximum daily 8-hour running average ozone (MDA8 O3) covering the period 1998–2012. The response of ozone to the location of blocks and ridges with centres in three longitudinal sectors (Atlantic, ATL, 30º–0º W; European, EUR, 0º–30º E; Russian, RUS, 30º–60º E) is examined. The impact of blocks on ozone is regionally and seasonally dependent. In particular, blocks within the EUR sector yield positive ozone anomalies of ~ 5–10 ppb over large parts of central Europe in spring and northern Europe in summer. Over 20 % and 30 % of the days with blocks in that sector register exceedances of the 90th percentile of the seasonal ozone distribution at many European locations during spring and summer, respectively. The impacts of ridges during those seasons are subtle and more sensitive to their specific location, although they can trigger ozone anomalies of ~ 5–10 ppb in Italy and the surrounding countries in summer, eventually exceeding European air quality targets. During winter, surface ozone in the northwest of Europe presents completely opposite responses to blocks and ridges. The anticyclonic circulation associated with winter EUR blocking, and to a lesser extent with ATL blocking, yields negative ozone anomalies between −5 ppb and −10 ppb over the UK, Northern France and the Benelux. Conversely, the enhanced zonal flow around 50˚–60˚ N during the occurrence of ATL ridges favours the arrival of background air masses from the Atlantic and the ventilation of the boundary layer, producing positive ozone anomalies above 5 ppb in an area spanning from the British Isles to Germany. This work provides the first quantitative assessments of the remarkable but distinct impacts that the anticyclonic circulation and the diversion of the zonal flow associated with blocks and ridges exert on surface ozone in Europe. The findings reported here can be exploited in the future to evaluate the modelled responses of ozone to circulation changes within chemical transport models (CTMs) and chemistry-climate models (CCMs).


2016 ◽  
Vol 33 (6) ◽  
pp. 894-920 ◽  
Author(s):  
Boryana V. Dimitrova ◽  
Bert Rosenbloom ◽  
Trina Larsen Andras

Purpose The purpose of this paper is to investigate the relationship between national cultural values and retail structure. Design/methodology/approach The authors use a panel data set of 67 countries over the period 1999-2012. Findings The results demonstrate that national cultural values, measured with the World Values Survey’s traditional/secular-rational and survival/self-expression dimensions, affect retail structure. Research limitations/implications While marketing scholars have examined the relationship between demographic and competitive factors and retail structure, there has been a substantial body of anecdotal evidence showing that national culture can also drive retail structure development. In order to enhance the understanding of the relationship between national culture and retail structure, the authors empirically examine the impact of national cultural values on retail structure. Originality/value This study is the first one to empirically examine the impact of national culture on retail structure. The authors thus help advance retail structure research the primary focus of which has been on investigating the impact of demographic and competitive factors on retail structure. This study is especially relevant to international retail managers who coordinate retail operations in multiple countries around the world. These managers need insight into the impact of national cultural values on retail structure in order to devise effective retail strategies for each host market.


2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Aaqib Sarwar ◽  
Muhammad Asif Khan ◽  
Zahid Sarwar ◽  
Wajid Khan

Purpose This paper aims to investigate the critical aspect of financial development, human capital and their interactive term on economic growth from the perspective of emerging economies. Design/methodology/approach Data set ranged from 2002 to 2017 of 83 emerging countries used in this research and collected from world development indicators of the World Bank. The two-step system generalized method of moments is used to conduct this research within the endogenous growth model while controlling time and country-specific effects. Findings The findings of the study indicate that financial development has a positive and significant effect on economic growth. In emerging countries, human capital also has a positive impact on economic growth. Financial development and human capital interactively affect economic growth for emerging economies positively and significantly. Research limitations/implications The data set is limited to 83 emerging countries of the world. The time period for the study is 2002 to 2017. Originality/value This research contributes to the existing literature on human capital, financial development and economic growth. Limited research has been conducted on the impact of financial development and human capital on economic growth.


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