Analysis of the Antarctic Ozone Hole in November

The factors responsible for the size of Antarctic ozone hole in November are analyzed. Comparing two samples of anomalously large and small November ozone hole with respect to 1980–2017 climatology in November, the results show that the anomalously large ozone hole in austral late winter is not a precondition for the anomalously large ozone hole in November. The size of Antarctic ozone hole in November is mainly influenced by dynamical processes from the end of October to mid-November. During large November ozone hole events, weaker dynamical ozone transport appears from the end of October to mid-November, which is closely related to planetary wave divergence in the stratosphere between 60°S and 90°S. Further analyses indicate that the wave divergence is partially attributed to less upward propagation of planetary waves from the troposphere, which is associated with weak baroclinic disturbances at the end of October. Subsequently, zonal wind speed in the upper stratosphere intensifies, and the distance between critical layer (U=0) and wave reflecting surfaces becomes larger. As a result, more planetary waves are reflected and then wave divergence enhances. The processes responsible for the anomalously small Antarctic ozone holes in November are almost opposite to those for the anomalously large Antarctic ozone holes.

The California Baseline Ozone Transport Study (CABOTS)

Ozone is one of the six “criteria” pollutants identified by the U.S. Clean Air Act Amendment of 1970 as particularly harmful to human health. Concentrations have decreased markedly across the United States over the past 50 years in response to regulatory efforts, but continuing research on its deleterious effects have spurred further reductions in the legal threshold. The South Coast and San Joaquin Valley Air Basins of California remain the only two “extreme” ozone nonattainment areas in the United States. Further reductions of ozone in the West are complicated by significant background concentrations whose relative importance increases as domestic anthropogenic contributions decline and the national standards continue to be lowered. These background concentrations derive largely from uncontrollable sources including stratospheric intrusions, wildfires, and intercontinental transport. Taken together the exogenous sources complicate regulatory strategies and necessitate a much more precise understanding of the timing and magnitude of their contributions to regional air pollution. The California Baseline Ozone Transport Study was a field campaign coordinated across Northern and Central California during spring and summer 2016 aimed at observing daily variations in the ozone columns crossing the North American coastline, as well as the modification of the ozone layering downwind across the mountainous topography of California to better understand the impacts of background ozone on surface air quality in complex terrain.

Vertical distribution of ozone in summer and autumn in Guangdong Province, Southern China

<p>A differential absorption lidar was used to study the vertical structure of ozone in Jiangmen city and Yangjiang city, Guangdong Province, Southern China in summer and autumn of 2019, and analyze the two typical pollution characteristics and spatial-temporal distribution characteristics of atmospheric ozone local pollution and regional transport. The results show that the vertical concentration of ozone in Jiangmen city in the summer and autumn seasons is characterized by a single peak of ozone in the afternoon. It is mainly distributed below 600 m in summer and mainly distributed within 1.0 km in autumn. There is ozone residual in Yangjiang city in summer at night. In summer, the differences between the average ozone values in Jiangmen city and Yangjiang city are small, being 92.22 μg/m<sup>3</sup> and 82 μg/m<sup>3</sup>, respectively. In autumn, the average ozone concentration in Jiangmen city is 1.58 times the ozone concentration in Yangjiang city, which is 122.27 μg/m<sup>3</sup> and 77.36 μg/m<sup>3</sup>. In the process of local pollution, high-concentration ozone is mainly concentrated near the ground, and the ozone concentration of 1.5-2km tends to be uniformly distributed. In regional transport, the transport heights of the two stations are mainly in two height intervals, ranging from 0.7 to 1.1 km and above 1.1 km. And use TrajStat to perform trajectory clustering analysis on the main airflows that affect Jiangmen city and Yangjiang city in summer and autumn, the dominant directions of ozone transport at the two cities in summer and autumn are analyzed. In addition, we studied two typical pollution processes, on August 24, the lidar of both cities detected the presence of ozone input and sedimentation at a height of about 1.5 km, and found that the ozone transport came from the northeast through the backward trajectory. During September 28-30, the two cities were locally polluted by ozone and there were obvious ozone residues at night.</p><p>Keywords: Differential absorption lidar；Ozone；Local pollution；Regional transport</p><p><strong> </strong></p>

Entrainment and Mixing of Transported Ozone Layers: Implications for Surface Air Quality in the Western U.S.

Recently, two air quality campaigns were conducted in the southwestern United States to study the impact of transported ozone, stratospheric intrusions, and fire emissions on ground-level ozone concentrations. The California Baseline Ozone Transport Study (CABOTS) took place in May – August 2016 covering the central California coast and San Joaquin Valley, and the Fires, Asian, and Stratospheric Transport Las Vegas Ozone Study (FAST-LVOS) was conducted in the greater Las Vegas, Nevada area in May – June 2017. During these studies, nearly 1000 hours of ozone and aerosol profile data were collected with the NOAA TOPAZ lidar. A Doppler wind lidar and a radar wind profiler provided continuous observations of atmospheric turbulence, horizontal winds, and mixed layer height. These measurements allowed us to directly observe the degree to which ozone transport layers aloft were entrained into the boundary layer and to quantify the resulting impact on surface ozone levels. Mixed layer heights in the San Joaquin Valley during CABOTS were generally below 1 km above ground level (AGL), while boundary layer heights in Las Vegas during FAST-LVOS routinely exceeded 3 km AGL and occasionally reached up to 4.5 km AGL. Consequently, boundary layer entrainment was more often observed during FAST-LVOS, while most elevated ozone layers passed untapped over the San Joaquin Valley during CABOTS.

A Case Study of Stratospheric Ozone Transport to the Northern San Francisco Bay Area and Sacramento Valley during CABOTS 2016

The California Baseline Ozone Transport Study (CABOTS) was a major air quality study that collected ozone measurements aloft between mid-May and mid-August of 2016. Aircraft measurements, ground-based lidar measurements, and balloon-borne ozonesondes collected precise upper-air ozone measurements across the central and Southern California valley. Utilizing daily ozonesonde data from Bodega Bay, California, and Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2), reanalysis data for 25 July to 14 August 2016, three stratospheric intrusion events are identified over Northern California influencing air masses above Bodega Bay and Sacramento simultaneously. Calculated percent daily changes in afternoon ozonesonde observations indicate increasing ozone concentrations from the point of likely stratospheric air injection with the arrival of higher potential vorticity, confirmed by ensemble back trajectories. An analysis of the onsite surface monitoring ozone data indicates ozone increases in the observations for dates of plausible low-level stratospheric air influence. Further, a comparison of Bodega Bay surface ozone observations and 14 Sacramento Valley nonattainment zone surface sites show that the surface ozone observed at the higher-elevation surface sites in the lower Sierra Nevada foothills were positively correlated with elevated ozone captured by the ozonesondes within the lowest 0.5–1 km. The strongest correlations observed (~0.61) were between elevated Bodega Bay ozonesonde data and the Placerville (~612 m) afternoon surface ozone data, an indication that these regions separated by 200 km would be influence by the same ozone source. A comparison of daily changes in afternoon ozone show that the two locales often experience similar daily ozone increases or decreases. While this study leads to a basic quantification of stratospheric influence on surface ozone in the Sacramento nonattainment zone, a future campaign that examines ozone and winds aloft at both locales is suggested to improve the quantification of stratospheric ozone.