scholarly journals Elemental content of PM<sub>2.5</sub> aerosol particles collected in Göteborg during the Göte-2005 campaign in February 2005

2009 ◽  
Vol 9 (7) ◽  
pp. 2597-2606 ◽  
Author(s):  
J. Boman ◽  
M. J. Gatari ◽  
S. Janhäll ◽  
A. S. Shannigrahi ◽  
A. Wagner
Keyword(s):  
Aerosol Particles ◽  
Urban Air Pollution ◽  
Trace Element Analysis ◽  
Rural Site ◽  
Elemental Content ◽  
Local Wind ◽  
Element Analysis ◽  
Air Masses ◽  
X Ray ◽  
Urban Sites

Abstract. The Göte–2005 measurement campaign aimed at studying the influence of the winter thermal inversions on urban air pollution. Elemental speciation of PM2.5 aerosol particles, collected on Teflon filters at three urban sites and one rural site in the Göteborg region, was a major part of the study. Trace element analysis was done by Energy Dispersive X-Ray Fluorescence (EDXRF) spectrometry and the concentrations of S, Cl, K, Ca, Ti, V, Mn, Fe, Ni, Cu, Zn, Br and Pb were determined. The elemental content of the particles, local wind speed and direction, and backward trajectories were used to investigate possible sources for the pollutants. We concluded that S, V, Ni, Br, and Pb had their main sources outside the central Göteborg area, since elevated concentrations of these elements were not observed during an inversion episode. Sea traffic and harbour activities were identified, primarily by the S and V content of the particles. This study showed that the elemental analysis by EDXRF presents valuable information for tracing the origin of air masses arriving at a measurement site.

scholarly journals Elemental content of PM<sub>2.5</sub> aerosol particles collected in Göteborg during the Göte-2005 campaign in February 2005

2008 ◽  
Vol 8 (2) ◽  
pp. 7703-7724 ◽  
Author(s):  
J. Boman ◽  
M. J. Gatari ◽  
S. Janhäll ◽  
A. S. Shannigrahi ◽  
A. Wagner
Keyword(s):  
Aerosol Particles ◽  
Urban Air Pollution ◽  
Trace Element Analysis ◽  
Rural Site ◽  
Elemental Content ◽  
Element Analysis ◽  
Air Masses ◽  
X Ray ◽  
The City ◽  
Urban Sites

Abstract. Göte–2005 was a measurement campaign in the city of Göteborg with the aim of studying the influence of the winter thermal inversions on urban air pollution. Elemental speciation of PM2.5 aerosol particles, collected on Teflon filters at three urban sites and one rural site in the Göteborg region, was a major part of the study. Trace element analysis was done by Energy Dispersive X-Ray Fluorescence (EDXRF) spectrometry and the concentrations of S, Cl, K, Ca, Ti, V, Mn, Fe, Ni, Cu, Zn, Br and Pb were determined. The elemental content of the particles in combination with information of local wind speed and direction and also backward trajectories were used to estimate the source areas of the pollutants. We can conclude that S, V, Ni, Br, and Pb have their main sources outside the Göteborg area, since we cannot see elevated concentrations of these elements during an inversion episode. Sea traffic and harbour activities were also identified, primarily by the S and V content of the particles. This study proves that the elemental analysis by EDXRF presents valuable information for tracing the origin of air masses arriving at a measurement site.

An improved interference correction for trace element analysis

1992 ◽  
Vol 50 (2) ◽  
pp. 1646-1647
Author(s):  
John J. Donovan ◽  
Donald A. Snyder ◽  
Mark L. Rivers
Keyword(s):  
Trace Element Analysis ◽  
Accurate Estimate ◽  
Simple Expression ◽  
Standard Reference Materials ◽  
Characteristic Line ◽  
Analytical Line ◽  
Element Analysis ◽  
Electron Probe Analysis ◽  
Calculated Concentration ◽  
X Ray

We present a simple expression for the quantitative treatment of interference corrections in x-ray analysis. WDS electron probe analysis of standard reference materials illustrate the success of the technique.For the analytical line of wavelength λ of any element A which lies near or on any characteristic line of another element B, the observed x-ray counts at We use to denote x-ray counts excited by element i in matrix j (u=unknown; s=analytical standard; ŝ=interference standard) at the wavelength of the analytical line of A, λA (Fig. 1). Quantitative analysis of A requires an accurate estimate of These counts can be estimated from the ZAF calculated concentration of B in the unknown C,Bu measured counts at λA in an interference standard of known concentration of B (and containing no A), and ZAF correction parameters for the matrices of both the unknown and the interference standard at It can be shown that:

Improvement of the Detection Sensitivity of Edxrf Trace Element Analysis by Means of Efficient X-Ray Focusing Based on Strongly Curved Hopg Crystals

1995 ◽  
Vol 39 ◽  
pp. 109-117
Author(s):  
Burkhard Beckhoff ◽  
Birgit Kanngießer
Keyword(s):  
High Intensity ◽  
Focal Plane ◽  
Bragg Reflection ◽  
Pyrolytic Graphite ◽  
Trace Element Analysis ◽  
Detection Sensitivity ◽  
Element Analysis ◽  
X Ray ◽  
Wide Range ◽  
Very High

X-ray focusing based on Bragg reflection at curved crystals allows collection of a large solid angle of incident radiation, monochromatization of this radiation, and condensation of the beam reflected at the crystal into a small spatial cross-section in a pre-selected focal plane. Thus, for the Bragg reflected radiation, one can achieve higher intensities than for the radiation passing directly to the same small area in the focal plane. In that case one can profit considerably from X-ray focusing in an EDXRF arrangement. The 00 2 reflection at Highly Oriented Pyrolytic Graphite (HOPG) crystals offers a very high intensity of the Bragg reflected beam for a wide range of photon energies. Furthermore, curvature radii smaller than 10 mm can be achieved for HOPG crystals ensuring efficient X-ray focusing in EDXRF applications. For the trace analysis of very small amounts of specimen material deposited on small areas of thin-filter backings, HOPG based X-ray focusing may be used to achieve a very high intensity of monochromatic excitation radiation.

Trace element analysis via heavy ion induced X-ray fluorescence

1976 ◽  
Vol 279 (2) ◽  
pp. 160-160 ◽  
Author(s):  
R. Zeisler ◽  
J. Cross ◽  
E. A. Schweikert
Keyword(s):  
Trace Element ◽  
Trace Element Analysis ◽  
Heavy Ion ◽  
Element Analysis ◽  
X Ray

Optimization of PIXE quantitative system to assist traceability of pearls

2017 ◽  
Vol 27 (03n04) ◽  
pp. 125-133
Author(s):  
S. Murao ◽  
K. Sera ◽  
S. Goto ◽  
C. Takahashi ◽  
L. Cartier ◽  
...  
Keyword(s):  
Supply Chain ◽  
Trace Element ◽  
Standard Method ◽  
Good Accuracy ◽  
Trace Element Analysis ◽  
Social Attention ◽  
Element Analysis ◽  
X Ray ◽  
Cultured Pearls

Recent rise of social attention towards ethical jewelry has led scientists to a challenge of how to construct analytical systems that can deliver in line with social and supply chain expectations. Of the various kinds of methods, “Proton/Particle-Induced X-ray Emission” (PIXE) seems to be robust and promising in characterizing gemstones because of its capability of trace element analysis without destruction. The authors established a non-standard method to analyze cultured pearls and applied it to test specimens from different places. The results showed that PIXE could detect important elements for pearl study with good accuracy and sensitivity and that pearl chemistry can be useful to differentiate freshwater and marine pearl products.

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