scholarly journals Are biogenic emissions a significant source of summertime atmospheric toluene in the rural Northeastern United States?

2009 ◽  
Vol 9 (1) ◽  
pp. 81-92 ◽  
Author(s):  
M. L. White ◽  
R. S. Russo ◽  
Y. Zhou ◽  
J. L. Ambrose ◽  
K. Haase ◽  
...  

Abstract. Summertime atmospheric toluene enhancements at Thompson Farm in the rural northeastern United States were unexpected and resulted in a toluene/benzene seasonal pattern that was distinctly different from that of other anthropogenic volatile organic compounds. Consequently, three hydrocarbon sources were investigated for potential contributions to the enhancements during 2004–2006. These included: (1) increased warm season fuel evaporation coupled with changes in reformulated gasoline (RFG) content to meet US EPA summertime volatility standards, (2) local industrial emissions and (3) local vegetative emissions. The contribution of fuel evaporation emission to summer toluene mixing ratios was estimated to range from 16 to 30 pptv d−1, and did not fully account for the observed enhancements (20–50 pptv) in 2004–2006. Static chamber measurements of alfalfa, a crop at Thompson Farm, and dynamic branch enclosure measurements of loblolly pine trees in North Carolina suggested vegetative emissions of 5 and 12 pptv d−1 for crops and coniferous trees, respectively. Toluene emission rates from alfalfa are potentially much larger as these plants were only sampled at the end of the growing season. Measured biogenic fluxes were on the same order of magnitude as the influence from gasoline evaporation and industrial sources (regional industrial emissions estimated at 7 pptv d−1 and indicated that local vegetative emissions make a significant contribution to summertime toluene enhancements. Additional studies are needed to characterize the variability and factors controlling toluene emissions from alfalfa and other vegetation types throughout the growing season.

2008 ◽  
Vol 8 (3) ◽  
pp. 12283-12311 ◽  
Author(s):  
M. L. White ◽  
R. S. Russo ◽  
Y. Zhou ◽  
J. L. Ambrose ◽  
K. Haase ◽  
...  

Abstract. Summertime atmospheric toluene enhancements at Thompson Farm in the rural northeastern United States were unexpected and resulted in a toluene/benzene seasonal pattern that was distinctly different from that of other anthropogenic volatile organic compounds. Consequentially, three hydrocarbon sources were investigated for potential contributions to the enhancements during 2004–2006. These included: 1) increased warm season fuel evaporation coupled with changes in reformulated gasoline (RFG) content to meet U.S. EPA summertime volatility standards, 2) local industrial emissions and 3) local vegetative emissions. The contribution of fuel evaporation emission to summer toluene mixing ratios was estimated to range from 16 to 30 pptv d−1, and did not fully account for the observed enhancements (20–50 pptv) in 2004–2006. Static chamber measurements of alfalfa, a crop at Thompson Farm, and dynamic branch enclosure measurements of loblolly pine trees in North Carolina suggested vegetative emissions of 5 and 12 pptv d−1 for crops and coniferous trees, respectively. Toluene emission rates from alfalfa are potentially much larger as these plants were only sampled at the end of the growing season. Measured biogenic fluxes were on the same order of magnitude as the influence from gasoline evaporation and industrial sources (regional industrial emissions estimated at 7 pptv d−1) and indicated that local vegetative emissions make a significant contribution to summertime toluene enhancements. Additional studies are needed to characterize the variability and factors controlling toluene emissions from alfalfa and other vegetation types throughout the growing season.


2020 ◽  
Author(s):  
Hélène Angot ◽  
Katelyn McErlean ◽  
Lu Hu ◽  
Dylan B. Millet ◽  
Jacques Hueber ◽  
...  

Abstract. Rapid Arctic warming, a lengthening growing season, and increasing abundance of biogenic volatile organic compounds (BVOC)-emitting shrubs are all anticipated to increase atmospheric BVOCs in the Arctic atmosphere, with implications for atmospheric oxidation processes and climate feedbacks. Quantifying these changes requires an accurate understanding of the underlying processes driving BVOC emissions in the Arctic. While boreal ecosystems have been widely studied, little attention has been paid to Arctic tundra environments. Here, we report terpenoid (isoprene, monoterpenes, and sesquiterpenes) ambient mixing ratios and emission rates from key dominant vegetation species at Toolik Field Station (TFS; 68°38' N, 149°36' W) in northern Alaska during two back-to-back field campaigns (summers 2018 and 2019) covering the entire growing season. Isoprene ambient mixing ratios observed at TFS fell within the range of values reported in the Eurasian taiga (0–500 pptv), while monoterpene and sesquiterpene ambient mixing ratios were respectively close to and below the instrumental quantification limit (~ 2 pptv). We further quantified the temperature dependence of isoprene emissions from local vegetation including Salix spp. (a known isoprene emitter), and compared the results to predictions from the Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1). Our observations suggest a 180–215 % emission increase in response to a 3–4 °C warming. The MEGAN2.1 temperature algorithm exhibits a close fit with observations for enclosure temperatures below 30 °C. Above 30 °C, MEGAN2.1 predicts an isoprene emission plateau that is not observed in the enclosure flux measurements at TFS. More studies are needed to better constrain the warming response of isoprene and other BVOCs for a wide range of Arctic species.


2010 ◽  
Vol 25 (4) ◽  
pp. 1082-1102 ◽  
Author(s):  
Peter C. Banacos ◽  
Michael L. Ekster

Abstract The occurrence of rare but significant severe weather events associated with elevated mixed-layer (EML) air in the northeastern United States is investigated herein. A total of 447 convective event days with one or more significant severe weather report [where significant is defined as hail 2 in. (5.1 cm) in diameter or greater, a convective gust of 65 kt (33 m s−1) or greater, and/or a tornado of F2 or greater intensity] were identified from 1970 through 2006 during the warm season (1 May–30 September). Of these, 34 event days (7.6%) were associated with identifiable EML air in regional rawinsondes preceding the event. Taken with two other noteworthy events in 1953 and 1969, a total of 36 significant severe weather events associated with EML air were studied via composite and trajectory analysis. Though a small percentage of the total, these 36 events compose a noteworthy list of historically significant derechos and tornadic events to affect the northeastern United States. It is demonstrated that plumes of EML air emanating from the Intermountain West in subsiding, anticyclonically curved flows can reinforce the capping inversion and maintain the integrity of the EML across the central United States over a few days. The EML plume can ultimately become entrained into a moderately fast westerly to northwesterly midtropospheric flow allowing for the plume’s advection into the northeastern United States. Resultant thermodynamic conditions in the convective storm environment are similar to those more typically observed closer to the EML source region in the Great Plains of the United States. In addition to composite and trajectory analysis, two case studies are employed to demonstrate salient and evolutionary aspects of the EML in such events. A lapse rate tendency equation is explored to put EML advection in context with other processes affecting lapse rate.


2017 ◽  
Vol 10 (2) ◽  
pp. 136-142 ◽  
Author(s):  
Antonio DiTommaso ◽  
Lindsey R. Milbrath ◽  
Scott H. Morris ◽  
Charles L. Mohler ◽  
Jeromy Biazzo

Pale swallowwort and black swallowwort are European viny milkweeds that have become invasive in many habitats in the northeastern United States and southeastern Canada. A multiyear seedbank study was initiated in fall 2011 to assess annual emergence of seedlings and longevity of seeds of pale swallowwort and black swallowwort at four different burial depths (0, 1, 5, and 10 cm) over 4 yr. One hundred swallowwort seeds were sown in seed pans buried in individual pots, and emerged seedlings were counted and removed from May through September each year. A subset of seed pans was retrieved annually in October, and recovered seeds were counted and tested for viability. The majority of seedling emergence occurred during the first year (92% in 2012), and no new seedlings emerged in the third (2014) or fourth (2015) years. Pale swallowwort had relatively poor emergence at sowing depths of 0 cm (11%), 5 cm (6%), and 10 cm (0.05%—only one seedling), while 37% of pale swallowwort seeds emerged at 1 cm. The larger-seeded black swallowwort was more successful, with two-thirds of all sown seeds emerging at depths of 1 cm (71%) and 5 cm (66%), and 26% emerging at 10 cm. Only 16% of the surface-sown black swallowwort emerged. A large portion of the seeds that germinated at 10 cm, as well as at 5 cm for pale swallowwort, died before reaching the soil surface. Of filled seeds that were recovered in 2012 (black swallowwort at the 0-cm depth), 66% were viable. No viable seeds were recovered after the second growing season. Seeds recovered following the third year had become too deteriorated to accurately assess. Swallowwort seeds do not appear to survive more than 2 yr in the soil, at least in our experiment, suggesting that the elimination of seed production over 3 yr will exhaust the local seedbank. Seeds would need to be buried at least 10 cm for pale swallowwort but more than 10 cm for black swallowwort to prevent seedling emergence. Burial of swallowwort seeds as a management strategy may, however, only be practical in natural areas where high swallowwort densities occur.


2016 ◽  
Vol 29 (12) ◽  
pp. 4327-4345 ◽  
Author(s):  
Harrison Li ◽  
Brian A. Colle

Abstract Future changes in the frequency of environmental conditions conducive for convective storm days (“CE days”) are determined for the northeastern United States (NEUS) during the warm seasons (April–September) of the twenty-first century. Statistical relationships between historical runs of seven models in phase 5 of the Coupled Model Intercomparison Project (CMIP5) and radar-classified convective storm days are developed using linear discriminant analysis (LDA), and these relationships are then applied to analyze changes in the convective environment under the high-emissions representative concentration pathway 8.5 (RCP8.5) scenario over the period 2006–99. The 1996–2007 warm seasons are used to train the LDA thresholds using convective precipitation from two reanalysis datasets and radar data, and the 1979–95 and 2008–10 warm seasons are used to verify these thresholds. For the CMIP5 historical period (1979–2005), the frequency of warm season CE days averaged across the CMIP5 models is slightly greater than that derived using reanalysis data, although both methods indicate a slight increasing trend through the historical period. Between 2006 and 2099, warm season CE day frequency is predicted to increase substantially at an average rate of 4–5 days decade−1 (50%–80% increase over the entire period). These changes are mostly attributed to a predicted 30%–40% increase in midlevel precipitable water between the historical period and the last few decades of the twenty-first century. Consistent with previous studies, there is decreasing deep-layer vertical wind shear as a result of a weakening horizontal temperature gradient, but this is outweighed by increases in instability led by the moisture increases.


2019 ◽  
Vol 41 (4) ◽  
pp. 343-364 ◽  
Author(s):  
Anthony J. Vega ◽  
Robert V. Rohli ◽  
Elina Wright

2015 ◽  
Vol 16 (5) ◽  
pp. 2065-2085 ◽  
Author(s):  
Allan Frei ◽  
Kenneth E. Kunkel ◽  
Adao Matonse

Abstract Recent analyses of extreme hydrological events across the United States, including those summarized in the recent U.S. Third National Climate Assessment (May 2014), show that extremely large (extreme) precipitation and streamflow events are increasing over much of the country, with particularly steep trends over the northeastern United States. The authors demonstrate that the increase in extreme hydrological events over the northeastern United States is primarily a warm season phenomenon and is caused more by an increase in frequency than magnitude. The frequency of extreme warm season events peaked during the 2000s; a secondary peak occurred during the 1970s; and the calmest decade was the 1960s. Cold season trends during the last 30–50 yr are weaker. Since extreme precipitation events in this region tend to be larger during the warm season than during the cold season, trend analyses based on annual precipitation values are influenced more by warm season than by cold season trends. In contrast, the magnitude of extreme streamflow events at stations used for climatological analyses tends to be larger during the cold season: therefore, extreme event analyses based on annual streamflow values are overwhelmingly influenced by cold season, and therefore weaker, trends. These results help to explain an apparent discrepancy in the literature, whereby increasing trends in extreme precipitation events appear to be significant and ubiquitous across the region, while trends in streamflow appear less dramatic and less spatially coherent.


2000 ◽  
Vol 14 ◽  
pp. 43-55 ◽  
Author(s):  
DJ Leathers ◽  
AJ Grundstein ◽  
AW Ellis

2013 ◽  
Vol 23 (5) ◽  
pp. 575-580 ◽  
Author(s):  
Thomas Björkman ◽  
Joseph W. Shail

Establishment of a weed-suppressive cover crop after vegetables harvested early in the season is important in the northeastern United States because of the short growing season. Buckwheat (Fagopyrum esculentum) is an effective cover crop in vegetable production because of its short growing season, ability to outcompete many weeds, resistance to damage by insects and disease, and requirement for only moderate soil fertility. In two separate 3-year field experiments, we determined the best tillage techniques and the optimal timing for use of buckwheat as a cover crop after early vegetables in the northeastern United States. Incorporating crop residue with a disk was necessary and provided sufficient tillage to obtain a weed-suppressive buckwheat stand. Buckwheat growth was stunted when direct seeded with a no-till drill immediately after pea (Pisum sativum) harvest because of poor soil penetration by buckwheat roots. Planting buckwheat after incorporating the pea crop was successful; waiting 1 week to plant was optimal, whereas a 2-week wait produced a weaker stand. We determined that optimal timing for sowing buckwheat in central New York was late June to early August. Generalizing to other geographical regions in the United States, we calculated that a minimum accumulation of 700 growing degree days is necessary to reach 1 to 1.5 tons/acre of buckwheat dry matter at the appropriate growth stage for incorporation (6 weeks after sowing).


HortScience ◽  
1996 ◽  
Vol 31 (4) ◽  
pp. 611b-611
Author(s):  
Angela M. O'Callaghan

Garlic (Allium sativum L.) has been cultivated in much of the world for millennia. Little scientific research, however, has focused on improving cultural conditions for production in the temperate regions of the northeastern United States, where garlic is gaining importance as a horticultural crop. To study the effectiveness of wheat straw (Triticum aestivum) mulch on garlic, experiments were conducted at the Cornell Univ. research facilities in East Ithaca, N.Y., during the 1993–94 (year 1) and 1994–95 (year 2) growing seasons and at the Homer C. Thompson Vegetable Research Farm, Freeville, N.Y., during the 1994–95 growing season. Two clones, one bolting and one nonbolting, were studied in year 1, and four varieties, three bolting and one non bolting, in year 2. All were fall-planted (mid-October), and mulch treatments were covered with wheat straw early in the following December. Control plots were not covered. The mulch either remained on the crop throughout the growing season or was removed early in the spring to expedite soil warming. This is the common practice among growers who use mulch only for winter protection. The presence of mulch during the winter increased the survival rate. Soil temperatures under the wheat straw were significantly lower during the summer than soil temperatures in unmulched plots, which could have contributed to the increase found in the yield and average bulb size of several of the cultivars. Maintaining the mulch through the entire growing season reduced weed pressure >30%. We found no significant increase in the amount of basal fungal infection. The results indicate that using straw mulch can improve garlic produced in the northeastern United States.


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