Towards verifying CH<sub>4</sub> emissions from hard coal mines using mobile sun-viewing Fourier transform spectrometry
Abstract. Methane (CH4) emissions from coal production are one of the primary sources of anthropogenic CH4 in the atmosphere. Poland is the largest hard coal producer in the European Union with the Polish side of the Upper Silesian Coal Basin (USCB) as the main part of it. Emission estimates for CH4 from the USCB for individual coal mine ventilation shafts range between 0.03 kt/a and 20 kt/a, amounting to a basin total of roughly 440 kt/a according to the European Pollutant Release and Transfer Register (E-PRTR, http://prtr.ec.europa.eu/, 2014). We mounted a ground-based, portable, sun-viewing FTS (Fourier Transform Spectrometer) on a truck for sampling coal mine ventilation plumes by driving cross-sectional stop-and-go Patterns at 1 to 3 km distance to the exhaust shafts. Using a mass balance approach, several of these transects allowed for estimating CH4 emissions based on the observed enhancements of the column-averaged dry-air mole fractions of methane (XCH4). Our resulting emission estimates range from 6 ± 1 kt/a for a single shaft up to 109 ± 33 kt/a for a subregion of the USCB, which is in broad agreement with the E-PRTR reports. Three wind lidars were deployed in the larger USCB region providing ancillary information about spatial and temporal variability of wind and turbulence in the atmospheric boundary-layer. Sensitivity studies show that, despite drawing from the three wind lidars, the uncertainty of the local wind dominates the uncertainty of the emission estimates, by far exceeding errors related to the XCH4 measurements itself. Wind-related relative errors on the emission estimates typically amount to 20 %.