Offsets among ice core derived CO2 reconstructions covering the Holocene and Last Interglacial

Author(s):  
Christoph Nehrbass-Ahles ◽  
Jochen Schmitt ◽  
Bernhard Bereiter ◽  
Sarah Eggleston ◽  
Lars Mächler ◽  
...  

<p>There is a general consensus in the scientific community that Greenlandic ice cores do not allow for reconstruction of past atmospheric carbon dioxide (CO<sub>2</sub>) concentrations due to artifacts likely caused by <em>in-situ</em> production of excess CO<sub>2</sub> from both organic and inorganic carbon compounds within the ice archive. In the case of Antarctic ice cores such processes are thought to be insignificant, making Antarctic ice cores the only direct archive of past atmospheric CO<sub>2</sub> concentrations beyond modern observations. However, with increasing numbers of high-precision CO<sub>2</sub> reconstructions from multiple Antarctic ice cores – mostly covering specific time intervals during the last 130 ka – it has become evident that offsets in CO<sub>2</sub> are not unique to Greenland ice cores. Over the last decade evidence is mounting that small systematic offsets of typically 2-10 ppm exist among different Antarctic CO<sub>2</sub> records covering the same time period. Because CO<sub>2</sub> is well-mixed within the atmosphere different ice cores should agree with each other within their measurement uncertainty, independent of the ice core drilling site. The unambiguous detection of such offsets between different ice cores is only possible in the absence of strong atmospheric trends, such as during interglacial periods. Here, we take a closer look at CO<sub>2</sub> offsets among records available for the Holocene and the Last Interglacial and investigate their long-term evolution. We present unpublished CO<sub>2</sub> data from multiple ice cores, including Talos Dome and EPICA Dome C, and discuss possible offset producing mechanisms. We speculate that Antarctic ice cores are also subject to slowly progressing <em>in-situ</em> production of CO<sub>2</sub> over many millennia, similar to Greenlandic ice cores, however to a much smaller extent and limited to about 10 ppm. We further note a tendency for higher offsets in the case of high accumulation sites. Despite all possible mechanisms that have the potential to alter CO<sub>2</sub> concentrations within the ice archive, we highlight that the overall integrity of the ice core-based CO<sub>2</sub> reconstruction is not in question, as all records generally share the same common signal. However, the absolute CO<sub>2</sub> levels should be interpreted with care and in light of such potential offsets.</p>

2013 ◽  
Vol 9 (6) ◽  
pp. 2789-2807 ◽  
Author(s):  
S. Schüpbach ◽  
U. Federer ◽  
P. R. Kaufmann ◽  
S. Albani ◽  
C. Barbante ◽  
...  

Abstract. In this study we report on new non-sea salt calcium (nssCa2+, mineral dust proxy) and sea salt sodium (ssNa+, sea ice proxy) records along the East Antarctic Talos Dome deep ice core in centennial resolution reaching back 150 thousand years (ka) before present. During glacial conditions nssCa2+ fluxes in Talos Dome are strongly related to temperature as has been observed before in other deep Antarctic ice core records, and has been associated with synchronous changes in the main source region (southern South America) during climate variations in the last glacial. However, during warmer climate conditions Talos Dome mineral dust input is clearly elevated compared to other records mainly due to the contribution of additional local dust sources in the Ross Sea area. Based on a simple transport model, we compare nssCa2+ fluxes of different East Antarctic ice cores. From this multi-site comparison we conclude that changes in transport efficiency or atmospheric lifetime of dust particles do have a minor effect compared to source strength changes on the large-scale concentration changes observed in Antarctic ice cores during climate variations of the past 150 ka. Our transport model applied on ice core data is further validated by climate model data. The availability of multiple East Antarctic nssCa2+ records also allows for a revision of a former estimate on the atmospheric CO2 sensitivity to reduced dust induced iron fertilisation in the Southern Ocean during the transition from the Last Glacial Maximum to the Holocene (T1). While a former estimate based on the EPICA Dome C (EDC) record only suggested 20 ppm, we find that reduced dust induced iron fertilisation in the Southern Ocean may be responsible for up to 40 ppm of the total atmospheric CO2 increase during T1. During the last interglacial, ssNa+ levels of EDC and EPICA Dronning Maud Land (EDML) are only half of the Holocene levels, in line with higher temperatures during that period, indicating much reduced sea ice extent in the Atlantic as well as the Indian Ocean sector of the Southern Ocean. In contrast, Holocene ssNa+ flux in Talos Dome is about the same as during the last interglacial, indicating that there was similar ice cover present in the Ross Sea area during MIS 5.5 as during the Holocene.


2013 ◽  
Vol 9 (3) ◽  
pp. 3321-3370 ◽  
Author(s):  
S. Schüpbach ◽  
U. Federer ◽  
S. Albani ◽  
C. Barbante ◽  
T. F. Stocker ◽  
...  

Abstract. In this study we report on new non-sea salt calcium (nssCa2+, mineral dust proxy) and sea salt sodium (ssNa+, sea ice proxy) records along the East Antarctic Talos Dome deep ice core in centennial resolution reaching back 150 thousand years before present. During glacial conditions nssCa2+ fluxes in Talos Dome are strongly related to temperature as has been observed before in other deep Antarctic ice core records, and has been associated with synchronous changes in the main source region (southern South America) during climate variations in the last glacial. However, during warmer climate conditions Talos Dome mineral dust input is clearly elevated compared to other records mainly due to the contribution of additional local dust sources in the Ross Sea area. Based on a simple transport model we compare nssCa2+ fluxes of different East Antarctic ice cores. From this multi-site comparison we conclude that changes in transport efficiency or atmospheric lifetime of dust particles do have a minor effect compared to source strength changes on the large scale concentration changes observed in Antarctic ice cores during climate variations of the past 150 thousand years. Our transport model applied on ice core data only so far is further validated by climate model data. The availability of multiple East Antarctic nssCa2+ records allows for a revision of a former estimate on the atmospheric CO2 sensitivity to reduced dust induced iron fertilisation in the Southern Ocean (SO) during the transition from the Last Glacial Maximum to the Holocene (T1). While the former estimate based on the EDC record only suggested 20 ppm, we find reduced dust induced iron fertilisation in the SO to be responsible for up to 40 ppm of the total atmospheric CO2 increase during T1. During the last interglacial, ssNa+ levels of EDC and EDML are only half of the Holocene levels, in line with higher temperatures during that period, indicating much reduced sea ice extent in the Atlantic as well as the Indian Ocean sector of the SO. In contrast, Holocene ssNa+ flux in Talos Dome is about the same as during the last interglacial, indicating that there was similar ice cover present in the Ross Sea area during MIS 5.5 as during the Holocene.


1995 ◽  
Vol 43 (2) ◽  
pp. 125-132 ◽  
Author(s):  
Eiliv Larsen ◽  
Hans Petter Sejrup ◽  
Sigfus J. Johnsen ◽  
Karen Luise Knudsen

AbstractThe climatic evolution during the Eemian and the Holocene in western Europe is compared with the sea-surface conditions in the Norwegian Sea and with the oxygen-isotope-derived paleotemperature signal in the GRIP and Renland ice cores from Greenland. The records show a warm phase (ca. 3000 yr long) early in the Eemian (substage 5e). This suggests that the Greenland ice sheet, in general, recorded the climate in the region during this time. Rapid fluctuations during late stage 6 and late substage 5e in the GRIP ice core apparently are not recorded in the climatic proxies from western Europe and the Norwegian Sea. This may be due to low resolution in the terrestrial and marine records and/or long response time of the biotic changes. The early Holocene climatic optimum recorded in the terrestrial and marine records in the Norwegian Sea-NW European region is not found in the Summit (GRIP and GISP2) ice cores. However, this warm phase is recorded in the Renland ice core. Due to the proximity of Renland to the Norwegian Sea, this area is probably more influenced by changes in polar front positions which may partly explain this discrepancy. A reduction in the elevation at Summit during the Holocene may, however, be just as important. The high-amplitude shifts during substage 5e in the GRIP core could be due to Atlantic water oscillating closer to, and also reaching, the coast of East Greenland. During the Holocene, Atlantic water was generally located farther east in the Norwegian Sea than during the Eemian.


2016 ◽  
Vol 12 (1) ◽  
pp. 15-30 ◽  
Author(s):  
F. Adolphi ◽  
R. Muscheler

Abstract. Investigations of past climate dynamics rely on accurate and precise chronologies of the employed climate reconstructions. The radiocarbon dating calibration curve (IntCal13) and the Greenland ice core chronology (GICC05) represent two of the most widely used chronological frameworks in paleoclimatology of the past  ∼  50 000 years. However, comparisons of climate records anchored on these chronologies are hampered by the precision and accuracy of both timescales. Here we use common variations in the production rates of 14C and 10Be recorded in tree-rings and ice cores, respectively, to assess the differences between both timescales during the Holocene. Compared to earlier work, we employ a novel statistical approach which leads to strongly reduced and yet, more robust, uncertainty estimates. Furthermore, we demonstrate that the inferred timescale differences are robust independent of (i) the applied ice core 10Be records, (ii) assumptions of the mode of 10Be deposition, as well as (iii) carbon cycle effects on 14C, and (iv) in agreement with independent estimates of the timescale differences. Our results imply that the GICC05 counting error is likely underestimated during the most recent 2000 years leading to a dating bias that propagates throughout large parts of the Holocene. Nevertheless, our analysis indicates that the GICC05 counting error is generally a robust uncertainty measurement but care has to be taken when treating it as a nearly Gaussian error distribution. The proposed IntCal13-GICC05 transfer function facilitates the comparison of ice core and radiocarbon dated paleoclimate records at high chronological precision.


2016 ◽  
Vol 62 (236) ◽  
pp. 1037-1048 ◽  
Author(s):  
F. PARRENIN ◽  
S. FUJITA ◽  
A. ABE-OUCHI ◽  
K. KAWAMURA ◽  
V. MASSON-DELMOTTE ◽  
...  

ABSTRACTDocumenting past changes in the East Antarctic surface mass balance is important to improve ice core chronologies and to constrain the ice-sheet contribution to global mean sea-level change. Here we reconstruct past changes in the ratio of surface mass balance (SMB ratio) between the EPICA Dome C (EDC) and Dome Fuji (DF) East Antarctica ice core sites, based on a precise volcanic synchronization of the two ice cores and on corrections for the vertical thinning of layers. During the past 216 000 a, this SMB ratio, denoted SMBEDC/SMBDF, varied between 0.7 and 1.1, being small during cold periods and large during warm periods. Our results therefore reveal larger amplitudes of changes in SMB at EDC compared with DF, consistent with previous results showing larger amplitudes of changes in water stable isotopes and estimated surface temperature at EDC compared with DF. Within the last glacial inception (Marine Isotope Stages, MIS-5c and MIS-5d), the SMB ratio deviates by up to 0.2 from what is expected based on differences in water stable isotope records. Moreover, the SMB ratio is constant throughout the late parts of the current and last interglacial periods, despite contrasting isotopic trends.


2021 ◽  
Vol 15 (4) ◽  
pp. 2109-2114
Author(s):  
Shugui Hou ◽  
Wangbin Zhang ◽  
Ling Fang ◽  
Theo M. Jenk ◽  
Shuangye Wu ◽  
...  

Abstract. There is considerable controversy regarding the age ranges of Tibetan ice cores. The Guliya ice core was reported to reach as far back as ∼760 ka (kiloannum, i.e. 1000 years), whereas chronologies of all other Tibetan cores cover at most the Holocene. Here we present ages for two new ice cores reaching bedrock, from the Zangser Kangri (ZK) glacier in the northwestern Tibetan Plateau and the Shulenanshan (SLNS) glacier in the western Qilian Mountains. We estimated bottom ages of 8.90±0.570.56 ka and 7.46±1.461.79 ka for the ZK and SLNS ice core respectively, further constraining the time range accessible by Tibetan ice cores to the Holocene.


1995 ◽  
Vol 21 ◽  
pp. 201-205
Author(s):  
V. N. Mikhalenko

The spatial extrapolation of data from ice cores depends on the complexity of the glacier system where the drilling site is located. The correlation between net mass balance, bn, of a specific point and of the whole glacier is different for each point. Analysis of net mass balance of Tuyuksu glacier in the Tien Shan, central Asia, confirms that the distribution of mass balance with height is more-or-less constant from year to year except in years with extreme values bn. Two types of “similarity” are described, additive and multiplicative. The “similarity” changes gradually from additive at the peripheral parts of the Tien Shan to multiplicative in the most continental central and eastern parts. Glacier mass-balance fluctuations of the frontal ridges are connected to the oscillations of accumulation and consequently to precipitation. Where the climate is more continental the mass-balance variability depends much more on the melting conditions than on accumulation. For the spatial interpretation of ice-core drilling results, a special analysis of “similarity type” is necessary. It allows the fixing of the spatial borders of the glacier system for which the dhilling site is representative.


1993 ◽  
Vol 39 (132) ◽  
pp. 303-315 ◽  
Author(s):  
J. -L Tison ◽  
J. -R. Petit ◽  
J. -M. Barnola ◽  
W. C. Mahaney

AbstractThe debris-rich ice from the bottom 6 m of the 82 m deep CAROLINE (Coastal Antarctic Record of Last Interglacial Natural Environment) ice core reaching bedrock, and from five 2 m long surface cores at Moraine Prudhomme in Terre Adélie (Antarctica) is described and compared to debris-laden ice from the core-drilling site DIO. Isotopic, total-gas content, CO2concentration and SEM investigations of embedded particles, together with ice textures and fabrics, rule out “pressure-melting” regelation around bed obstacles or “freezing-on” as possible mechanisms for the debris entrainment at the ice-bedrock interface. It is suggested that the debris entrapment by purely mechanical means (e.g. shearing) is an efficient process in forming basal ice layers (BIL) at sub-freezing temperatures. This process might be dominant at the margin of the Antarctic ice sheet where no ice shelf exists and where a ramp terminus or a buttressing coastal relief induces compressive flow.


1997 ◽  
Vol 43 (143) ◽  
pp. 90-97 ◽  
Author(s):  
Roy M. Koerner

AbstractPoor consideration has been given in many Arctic circum-polar ice-core studies to the effect of summer snow melt on chemistry, stable-isotope concentrations and time-scales. Many of these corps are drilled close to the firn line where melt is intense. Some come from below the firn line where accumulation is solely in the form of super-imposed ice. In all cases, seasonal signals are reduced or removed and, in some, time gaps develop during periods of excessive melting which situate the drill site in the ablation zone. Consequently, cross correlations of assumed synchronous events among the cores are invalid, so that time-scales along the same cores differ between authors by factors of over 2. Many so-called climatic signals are imaginary rather than real. By reference to published analyses of cores from the superimposed ice zone on Devon Ice Cap (Koerner, 1970) and Meighen Ice Cap (Koerner and Paterson, 1974), it is shown how melt affects all the normally well-established ice-core proxies and leads to their misinterpretation. Despite these limitations, the cores can give valuable low-resolution records for all or part of the Holocene. They show that the thermal maximum in the circum-polar Arctic occurred in the early Holocene. This maximum, effected negative balances on all the ice caps and removed the smaller ones. Cooler conditions in the second half of the Holocene have caused the regrowth of these same ice caps.


1991 ◽  
Vol 37 (125) ◽  
pp. 11-22 ◽  
Author(s):  
E. Mosley-Thompson ◽  
J. Dai ◽  
L. G. Thompson ◽  
P. M. Grootes ◽  
James K. Arbogast ◽  
...  

Abstract The quality and utility of the records of oxygen-isotopic abundances, dust concentrations and anionic concentrations preserved in the ice at Siple Station (75°55′ S, 84° 15′ W) are assessed from four shallow (20 m) cores. The combination of high accumulation (0.56 m a−1 w.e.) and low mean annual temperature (—24°C) preserves the prominent seasonal variations in δ18Ο which are very spatially coherent. Sulfate concentrations vary seasonally and, in conjunction with δ18Ο, will allow accurate dating of deeper cores from Siple Station. The concentrations of insoluble dust are the lowest measured in Antarctica, making Siple Station an excellent location to examine large increases in atmospheric tubidity. The seasonal variations and annual fluxes of the anions are examined for the last two decades (AD 1966–85) with regard to probable sources. An unusually high sulfate flux in 1976 may reflect the February 1975 eruption of Mount Ngauruhoe, New Zealand. No annual signal in nitrate concentration is confirmed and no unusually high nitrate fluxes support the suggestion of nitrate production by large solar flares. However, nitrate flux is higher for the latter half of the 1970s and early 1980s, possibly reflecting the recent loss of stratospheric ozone. Finally, comparison of the δ18O record with available surface-temperature data (AD 1957–85) reveals that multi-year trends along the western coast of the Antarctic Peninsula are recorded at Siple. More importantly, comparison with areally weighted temperature reconstructions suggests that the δ18Ο record may reflect larger-scale, persistent trends in the high southern latitudes. The strong spatial coherence of the preserved records, the potential for accurate dating, and possible relevance to larger-scale processes make Siple Station an excellent site for paleoenvironmental reconstruction from ice cores.


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