Permian magmatism in the Carpathian–Panonnian region (Hungary and Romania): New geochronological and geochemical results

Author(s):  
Máté Szemerédi ◽  
Réka Lukács ◽  
Andrea Varga ◽  
István Dunkl ◽  
Ioan Seghedi ◽  
...  

<p>In the Carpathian–Pannonian region (Pannonian Basin, Hungary and the Apuseni Mts, Romania) several Late Paleozoic magmatic episodes were revealed by zircon U-Pb geochronology. These events were genetically controlled by a post-collisional to extensional tectonic regime and occurred along the European Variscan Orogenic Belt. Detailed geochronological and geochemical information about the products of this magmatism play crucial role in the regional correlation studies which is the main goal of our research.</p><p>In the Tisza Mega-unit, including southern Transdanubia and the eastern Pannonian Basin (Hungary) as well as the Apuseni Mts (Romania), Permian felsic (dominantly rhyodacitic-dacitic) ignimbrites are common. In the western–central part of the Apuseni Mts, they are accompanied by basaltic and subordinate andesitic lavas, corresponding to a bimodal volcanic suite. Cogenetic plutonic (granites, diorites, gabbros) and subvolcanic rocks (felsic–intermediate dykes) occur in the SW part of the Apuseni Mts, Highiş massif. Immobile element features (REE patterns and multi-element spider diagrams) are similar for all of the aforementioned rock types, suggesting fractional crystallization from a common or similar source. Zircon U-Pb ages of this cogenetic rock assemblage overlap each other and fall within a ~10 Myr long time-span (269–259 Ma, Guadalupian). In contrast to the previous assumptions, the Permian felsic volcanites in the Tisza Mega-unit are not in connection with the granitoid rocks known in the basement of the eastern Pannonian Basin (e.g., Battonya granite). Based on our new data, the granitoids represent a Variscan (~356 Ma, Mississippian) plutonic body.</p><p>The dacitic subvolcanic rocks (dykes) and lavas in the ALCAPA Mega-unit, Central Transdanubia (Hungary) represent an older (~281 Ma, Cisuralian) and geochemically distinct volcanic episode than the magmatism in the Tisza Mega-unit. Associated plutonic rocks, however, are not known in the study area.</p><p>Regarding a broader correlation, the zircon U-Pb ages of the studied Permian plutonic and volcanic rocks of the Tisza Mega-unit are significantly younger than the ages of other well-studied parts of the Central European Variscides (e.g., Intra-Sudetic Basin, NE Germany) where much older ages were identified (300–280 Ma). On the other hand, felsic volcanic rocks of the ALCAPA Mega-unit do not differ from the aforementioned parts of the European Variscides in age. Based on whole-rock geochemistry and zircon geochronology, all of the observed Permian magmatic rocks show similarity with the Permian felsic volcanites of the Western Carpathians (Slovakia). Some further assumptions have been raised: (1) felsic volcanic rocks of the Tisza Mega-unit could correlate with similar rocks of the Southern Gemeric (Vozárová et al. 2009) and Silicic Units (Ondrejka et al. 2018) of the ALCAPA Mega-unit, while (2) the studied samples of Central Transdanubia might be in relationship with the felsic volcanites of the Northern Veporic Unit, ALCAPA Mega-unit (Vozárová et al. 2016). This study was financed by NRDIF (K131690).</p><p>Ondrejka, M., Li, X.H., Vojtko, R., Putiš, M., Uher, P., Sobocký, T. (2018). Geol Carpath 69(2):187–198.</p><p>Vozárová, A., Šmelko, M., Paderin, I. (2009). Geol Carpath 60(6):439–448.</p><p>Vozárová, A., Rodionov, N., Vozár, J., Lepekhina, E., Šarinová, K. (2016). Geol Carpath 61:221–237.</p>

2019 ◽  
Vol 109 (1) ◽  
pp. 101-125 ◽  
Author(s):  
Máté Szemerédi ◽  
Réka Lukács ◽  
Andrea Varga ◽  
István Dunkl ◽  
Sándor Józsa ◽  
...  

AbstractTwo distinct Permian volcanic epochs were revealed in the Pannonian Basin (eastern Central Europe) by U–Pb zircon geochronology: an older one (~ 281 Ma, Cisuralian) in the ALCAPA Mega-unit (Central Transdanubia, Hungary) and a younger volcanic episode (~ 267–260 Ma, Guadalupian) in the Tisza Mega-unit (Southern Transdanubia and the eastern Pannonian Basin, Hungary). The former is represented by dacitic subvolcanic rocks (dykes) and lavas, while the latter is dominantly by crystal-rich rhyolitic–rhyodacitic/dacitic ignimbrites and subordinate rhyodacitic/dacitic lavas. Whole-rock (major and trace element) geochemical data and zircon U–Pb ages suggest close relationship between the samples of Central Transdanubia and volcanic rocks of the Northern Veporic Unit (Western Carpathians, Slovakia), both being part of the ALCAPA Mega-unit. Such correlation was also revealed between the Permian felsic volcanic rocks of the Apuseni Mts (Romania) and the observed samples of Southern Transdanubia and the eastern Pannonian Basin that are parts of the Tisza Mega-unit. The older volcanic rocks (~ 281–265 Ma) could be linked to post-orogenic tectonic movements, however, the youngest samples (~ 260 Ma, eastern Pannonian Basin, Tisza Mega-unit) could be formed in the extensional setting succeeding the post-collisional environment. On the whole, the observed Permian magmatic rocks show significant similarity with those of the Western Carpathians.


2020 ◽  
Vol 63 (1) ◽  
pp. 1-18
Author(s):  
Máté Szemerédi ◽  
Andrea Varga ◽  
János Szepesi ◽  
Elemér Pál-Molnár ◽  
Réka Lukács

AbstractPermian felsic volcanic rocks were encountered in petroleum exploration boreholes in SE Hungary (eastern Pannonian Basin, Tisza Mega-unit, Békés–Codru Unit) during the second half of the 20th century. They were considered to be predominantly lavas (the so-called “Battonya quartz-porphyry”) and were genetically connected to the underlying “Battonya granite.” New petrographic observations, however, showed that the presumed lavas are crystal-poor (8–20 vol%) rhyolitic ignimbrites near Battonya and resedimented pyroclastic or volcanogenic sedimentary rocks in the Tótkomlós and the Biharugra areas, respectively. The studied ignimbrites are usually massive, matrix-supported, fiamme-bearing lapilli tuffs with eutaxitic texture as a result of welding processes. Some samples lack vitroclastic matrix and show low crystal breakage, but consist of oriented, devitrified fiammes as well. Textural features suggest that the latter are high-grade rheomorphic ignimbrites.Felsic volcanic rocks in SE Hungary belong to the Permian volcanic system of the Tisza Mega-unit; however, they show remarkable petrographic differences as compared to the other Permian felsic volcanic rocks of the mega-unit. In contrast to the crystal-poor rhyolitic ignimbrites of SE Hungary with rare biotite, the predominantly rhyodacitic–dacitic pyroclastic rocks of the Tisza Mega-unit are crystal-rich (40–45 vol%) and often contain biotite, pyroxene, and garnet. Additionally, some geochemical and geochronological differences between them were also observed by previous studies. Therefore, the Permian felsic volcanic rocks in SE Hungary might represent the most evolved, crystal-poor rhyolitic melt of a large-volume felsic (rhyodacitic–dacitic) volcanic system.The Permian volcanic rocks of the studied area do not show any evident correlations with either the Permian felsic ignimbrites in the Finiş Nappe (Apuseni Mts, Romania), as was supposed so far, or the similar rocks in any nappe of the Codru Nappe System. Moreover, no relevant plutonic–volcanic connection was found between the studied samples and the underlying “Battonya granite.”


2015 ◽  
Vol 42 (4) ◽  
pp. 437 ◽  
Author(s):  
Phillips C. Thurston

Greenstone belts are long, curvilinear accumulations of mainly volcanic rocks within Archean granite−greenstone terranes, and are subdivided into two geochemical types: komatiite−tholeiite sequences and bimodal sequences. In rare instances where basement is preserved, the basement is unconformably overlain by platform to rift sequences consisting of quartzite, carbonate, komatiite and/or tholeiite. The komatiite−tholeiite sequences consist of km-scale thicknesses of tholeiites, minor intercalated komatiites, and smaller volumes of felsic volcanic rocks. The bimodal sequences consist of basal tholeiitic flows succeeded upward by lesser volumes of felsic volcanic rocks. The two geochemical types are unconformably overlain by successor basin sequences containing alluvial–fluvial clastic metasedimentary rocks and associated calc-alkaline to alkaline volcanic rocks.   Stratigraphically controlled geochemical sampling in the bimodal sequences has shown the presence of Fe-enrichment cycles in the tholeiites, as well as monotonous thicknesses of tholeiitic flows having nearly constant MgO, which is explained by fractionation and replenishment of the magma chamber with fresh mantle-derived material. Geochemical studies reveal the presence of boninites associated with the komatiites, in part a result of alteration or contamination of the komatiites. Within the bimodal sequences there are rare occurrences of adakites, Nb-enriched basalts and magnesian andesites.    The greenstone belts are engulfed by granitoid batholiths ranging from soda-rich tonalite−trondhjemite−granodiorite to later, more potassic granitoid rocks. Archean greenstone belts exhibit a unique structural style not found in younger orogens, consisting of alternating granitoid-cored domes and volcanic-dominated keels. The synclinal keels are cut by major transcurrent shear zones.   Metamorphic patterns indicate that low pressure metamorphism of the greenstones is centred on the granitoid batholiths, suggesting a central role for the granitoid rocks in metamorphosing the greenstones. Metamorphic patterns also show that the proportion of greenstones in granite−greenstone terranes diminishes with deeper levels of exposure.   Evidence is presented on both sides of the intense controversy as to whether greenstone belts are the product of modern plate tectonic processes complete with subduction, or else the product of other, lateral tectonic processes driven by the ‘mantle wind.’ Given that numerous indicators of plate tectonic processes – structural style, rock types, and geochemical features − are unique to the Archean, it is concluded that the evidence is marginally in favour of non-actualistic tectonic processes in Archean granite−greenstone terranes.RÉSUMÉLes ceintures de roches vertes sont des accumulations longiformes et curvilinéaires, principalement composées de roches volcaniques au sein de terranes granitique archéennes,  et étant subdivisées en deux types géochimiques: des séquences à komatiite–tholéite et des séquences bimodales. En de rares occasions, lorsque le socle est préservé, ce dernier est recouvert en discordance par des séquences de plateforme ou de rift, constituées de quartzite, carbonate, komatiite et/ou de tholéiite. Les séquences de komatiite-tholéiite forment des épaisseurs kilométriques de tholéiite, des horizons mineurs de komatiites, et des volumes de moindre importance de roches volcaniques felsiques. Les séquences bimodales sont constituées à la base, de coulées tholéiitiques surmontées par des volumes mineurs de roches volcaniques felsiques. Ces deux types géochimiques sont recouverts en discordance par des séquences de bassins en succession contenant des roches métasédimentaires clastiques fluvio-alluvionnaires associées à des roches volcaniques calco-alcalines à alcalines.   Un échantillonnage à contrôle stratigraphique des séquences bimodales a révélé la présence de cycles d’enrichissement en Fe dans les tholéiites, ainsi que des épaisseurs continues d’épanchements tholéiitiques ayant des valeurs presque constante en  MgO, qui s’explique par la cristallisation fractionnée et le réapprovisionnement de la chambre magmatique par du matériel mantélique. Les études géochimiques montrent la présence de boninites associées aux komatiites, résultant en partie de l’altération ou de la contamination des komatiites. Au sein des séquences bimodales, on retrouve en de rares occasions des adakites, des basaltes enrichis en Nb et des andésites magnésiennes.   Les ceintures de roches vertes sont englouties dans des batholites granitoïdes de composition passant des tonalites−trondhjémites−granodiorites enrichies en sodium, à des roches granitoïdes tardives plus potassiques. Les ceintures de roches vertes archéennes montrent un style structural unique que l’on ne retrouve pas dans des orogènes plus jeunes, et qui est constitué d’alternances de dômes à cœur granitoïdes et d`affaissements principalement composés de roches volcaniques. Les synclinaux formant les affaissements sont recoupés par de grandes zones de cisaillement.   Les profils métamorphiques indiquent que le métamorphisme de basse pression des roches vertes est centré sur les batholites, indiquant un rôle central des roches granitoïdes durant le métamorphisme des roches vertes. Les profils métamorphiques montrent également que la proportion de roches vertes dans les terranes granitiques diminue avec l’exposition des niveaux plus profonds.   On présente les arguments des deux côtés de l’intense controverse voulant que les ceintures de roches vertes soient le produit de processus moderne de la tectonique des plaques incluant la subduction, ou alors le produit d’autres processus tectoniques découlant du « flux mantélique ». Étant donné la présence des indicateurs des processus de tectonique des plaques – style structural, les types de roches, et les caractéristiques géochimiques – ne se retrouvent qu’à l’Archéen, nous concluons que les indices favorisent légèrement l’option de processus tectoniques non-actuels dans les terranes granitiques de roches vertes à l’Archéen.


Author(s):  
Brian Marshall ◽  
Hans Kristian Schønwandt

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Marshall, B., & Schønwandt, H. K. (1999). An Archaean sill complex and associated supracrustal rocks, Arveprinsen Ejland, north-east Disko Bugt, West Greenland. Geology of Greenland Survey Bulletin, 181, 87-102. https://doi.org/10.34194/ggub.v181.5117 _______________ Archaean supracrustal rocks on Arveprinsen Ejland comprise mafic and felsic volcanic rocks overlain by an epiclastic sedimentary sequence invaded by a mafic to ultramafic sill complex. The latter has a strike-length of 7500 m and a cumulative preserved thickness of 2000–2500 m and amounts to nearly 50% of the exposed thickness of the supracrustal rocks. Chilled and locally peperitic contacts are developed between component sills and the inter-sill metasedimentary septa. The sub-alkalic sill complex and mafi c lavas and tuffs are high-magnesium tholeiites and basaltic komatiites whereas the felsic rocks are calc-alkaline rhyolites and dacites. Chondrite- and MORB-normalised spider diagrams affirm the close similarity of the mafic volcanic rocks and the sill complex; they are also consistent with a tholeiitic or komatiitic affinity. Tectonomagmatic discrimination plots suggest an ensialic arc-related setting for the sill complex and the mafic and felsic volcanic rocks. The sill complex was progressively emplaced, as an upward-younging sequence of component sills, beneath 2 to 2.5 km of seawater and substantially less than 0.5 km of wet sediment. Sills formed when the magmatic pressure exceeded the effective overburden pressure of the sediment plus the vertical tensile strength (To) of the host materials. Intrusion was probably promoted by the drop in To at the interface between contact-lithified and poorly lithified strata. The thickness of the sill complex was accommodated by dilational lifting plus the capacity of an intrusion to create space through expulsion of water from wet sediment.


2021 ◽  
Vol 62 (10) ◽  
pp. 1175-1187
Author(s):  
A.D. Nozhkin ◽  
O.M. Turkina ◽  
K.A. Savko

Abstract —The paper presents results of a petrogeochemical and isotope–geochronological study of the granite–leucogranite association of the Pavlov massif and felsic volcanics from the Elash graben (Biryusa block, southwest of the Siberian craton). A characteristic feature of the granite–leucogranites is their spatial and temporal association with vein aplites and pegmatites of the East Sayan rare-metal province. The U–Pb age of zircon from granites of the Pavlov massif (1852 ± 5 Ma) is close to the age of the pegmatites of the Vishnyakovskoe rare-metal deposit (1838 ± 3 Ma). The predominant biotite porphyritic granites and leucogranites of the Pavlov massif show variable alkali ratios (K2O/Na2O = 1.1–2.3) and ferroan (Fe*) index and a peraluminous composition; they are comparable with S-granites. The studied rhyolites of the Tagul River (SiO2 = 71–76%) show a low ferroan index, a high K2O/Na2O ratio (1.6–4.0), low (La/Yb)n values (4.3–10.5), and a clear Eu minimum (Eu/Eu* = 0.3–0.5); they are similar to highly fractionated I-granites. All coeval late Paleoproterozoic (1.88–1.85 Ga) granites and felsic volcanics of the Elash graben have distinct differences in composition, especially in the ferroan index and HREE contents, owing to variations in the source composition and melting conditions during their formation at postcollisions extension. The wide range of the isotope parameters of granites and felsic volcanic rocks (εNd from +2.0 to –3.7) and zircons (εHf from +3.0 to +0.8, granites of the Toporok massif) indicates the heterogeneity of the crustal basement of the Elash graben, which formed both in the Archean and in the Paleoproterozoic.


2010 ◽  
Vol 47 (12) ◽  
pp. 1481-1506 ◽  
Author(s):  
Vicki McNicoll ◽  
Gerry Squires ◽  
Andrew Kerr ◽  
Paul Moore

The Duck Pond Cu–Zn–Pb–Ag–Au deposit in Newfoundland is hosted by volcanic rocks of the Cambrian Tally Pond group in the Victoria Lake supergroup. In conjunction with the nearby Boundary deposit, it contains 4.1 million tonnes of ore at 3.3% Cu, 5.7% Zn, 0.9% Pb, 59 g/t Ag, and 0.9 g/t Au. The deposits are hosted by altered felsic flows, tuffs, and volcaniclastic sedimentary rocks, and the sulphide ores formed in part by pervasive replacement of unconsolidated host rocks. U–Pb geochronological studies confirm a long-suspected correlation between the Duck Pond and Boundary deposits, which appear to be structurally displaced portions of a much larger mineralizing system developed at 509 ± 3 Ma. Altered aphyric flows in the immediate footwall of the Duck Pond deposit contained no zircon for dating, but footwall stringer-style and disseminated mineralization affects rocks as old as 514 ± 3 Ma at greater depths below the ore sequence. Unaltered mafic to felsic volcanic rocks that occur structurally above the orebodies were dated at 514 ± 2 Ma, and hypabyssal intrusive rocks that cut these were dated at 512 ± 2 Ma. Some felsic samples contain inherited (xenocrystic) zircons with ages of ca. 563 Ma. In conjunction with Sm–Nd isotopic data, these results suggest that the Tally Pond group was developed upon older continental or thickened arc crust, rather than in the ensimatic (oceanic) setting suggested by previous studies.


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