Analogue Rock Characterization with MicrOmega, within the H2020/PTAL project.

Author(s):  
Damien Loizeau ◽  
Cédric Pilorget ◽  
François Poulet ◽  
Cateline Lantz ◽  
Jean-Pierre Bibring ◽  
...  

<p>The PTAL project [1] aims to build an Earth analogues database, the Planetary Terrestrial Analogues Library, to help characterizing the mineralogical evolution of terrestrial bodies, with a focus on Martian analogues (www.PTAL.eu). A set of natural Earth rock samples have been collected, compelling a variety of igneous and sedimentary rocks with variable compositions and levels of alteration. Those samples are characterized with thin section observations and XRD analysis, NIR spectroscopy, Raman spectroscopy and LIBS.</p><p>This abstract focuses on the NIR (Near Infrared) spectroscopy analysis performed using the MicrOmega instrument, a NIR hyperspectral microscope (e.g. [2]). The MicrOmega instrument used within the PTAL project is the spare model of the ExoMars rover laboratory. It has a total field of view of 5 mm x 5 mm, with resolution of 20 µm/pixel in the focal plane. It covers the spectral domain from 0.98 µm to ~3.6 µm. Its capabilities enable the identification of grains of different mineralogy in the samples [2].</p><p>Each MicrOmega observation produces >65,000 spectra, hence automatic analysis is needed as a first step. After data calibration, a quick-look data analysis based on a set of ~16 spectral parameters based on the detection of single or multiple absorption bands was performed to produce spectral indices maps and average spectra, then guiding the manual analysis in a second step. After spectral endmembers are identified, they are compared to reference spectral libraries to identify the presence of minerals species in the sample. Spectral parameter maps can then be used to map the extent of the identified mineral species on the surface of the sample. Final products of the analyses will feed the online PTAL spectral database, and a paper describing these analyses has recently been submitted to Astrobiology.</p><p>Mineral species detected with MicrOmega in the PTAL samples include: Olivine, High Calcium Pyroxene, Low Calcium Pyroxene, Amphiboles, Epidotes, Zeolites, Opals, Phyllosilicates, Oxides and Hydroxides, Carbonates, and Sulfates.</p><p>Preliminary<strong> </strong>comparisons with XRD and Raman analyses show general consistency in the identification of olivine, pyroxene and hydrated phases. As expected, quartz and plagioclase for example are challenging to be identified in NIR, but MicrOmega shows well the capacity in hydrated minerals identification and qualitative estimation of major and minor mineral species thanks to its spectral-imaging capabilities.</p><p>The PTAL spectral database will assist in particular in interpreting in situ data from the next Mars surface missions. The target-rocks in Oxia Planum and Jezero Crater, the landing sites of the next surface missions, have compositional similarities with some samples of the PTAL collection, in particular with the orbital identification of clay minerals and serpentine. The NIR spectrometers on board the rovers will be involved at multiple stages of the surface operations and will be crucial to understand the geologic history of each landing site, and in particular the context of the water alteration of the rocks.</p><p><strong>References:</strong> [1] Werner et al. (2018) Second International Mars Sample Return, No. 2071, 6060. [2] Pilorget and Bibring (2014) PSS 99, 7-18.</p><p><strong>Acknowledgements:</strong> This project is financed through the European Research Council in the H2020-COMPET-2015 program (grant 687302).</p>

2021 ◽  
Author(s):  
benjamin bultel ◽  
Agata M. Krzesinska ◽  
Damien Loizeau ◽  
François Poulet ◽  
Håkon O. Astrheim ◽  
...  

<p>Serpentinization and carbonation have affected ultramafic rocks on Noachian Mars in several places called here serpentinization-carbonation systems (SCS). Among the most prominent SCS revealing mineral assemblages characteristic of serpentinization/carbonation is the Nili Fossae region [1]. Jezero crater – the target of the Mars 2020 rover –hosted a paleolake which constitutes a sink for sediments from Nili Fossae [1]. Thanks to the near infrared spectrometer onboard Mars2020 [2], the mission has the potential to offer ground truth measurement for other putative serpentinization/carbonation system documented on Mars. Several important aspects that may be addressed are: Do carbonates result from primary alteration of olivine-rich lithologies or are they derived by reprocessing of previous alteration minerals [3]? What is the composition? and nature of the protolith, which appear to be constituted of considerable amounts of olivine [4]? To reveal critical information regarding the conditions of serpentinization/carbonation, accessory minerals need detailed studies [1; 5]. In case of Jezero Crater, and serpentinization on Mars in general, the main alteration minerals are identified, but little is known about the accessory minerals.</p> <p>The Nili Fossae-Jezero system has potential analogues in terrestrial serpentinized and carbonated rocks, such as the Leka Ophiolite Complex, Norway (PTAL collection, https://www.ptal.eu). Here, distinct mineral assemblages record different stages of hydration and carbonation of ultramafic rocks [6].</p> <p>We perform petrological and mineralogical analyses on thin sections to characterize the major and trace minerals and combine with Near Infrared (NIR) spectroscopy measurements. A set of spectral parameters are defined and compare to spectral parameters previously used on CRISM and OMEGA data [1, 4, 7, 8]. We study the significance of the mineralogical assemblages including nature of accessory minerals. Effect of the presence of accessory minerals on the NIR signal is investigated and their potential incidence on the amount of H<sub>2</sub>/CH<sub>4</sub> production in mafic or ultramafic system is discussed [5].</p> <p>We started to apply the newly defined spectral parameters on several SCS on Mars. Results confirm local carbonation of earlier serpentinized rocks and suggest that different protoliths could have led to diversity of mineralogical associations in SCS on Mars. Multiple detection of brucite are also suggested for the first time on Mars. Altogether our results help to better describe key geochemical conditions of the SCS on Mars for habitability potential of the martian crust and Mars’s evolution.</p> <p><strong> </strong></p> <p>References:</p> <ul> <li>Brown, A. J., et al. <em>EPSL</em>1-2 (2010): 174-182.</li> <li>Wiens, R.C., et al.  <em>Space Sci Rev</em><strong>217, </strong>4 (2021).</li> <li>Horgan, B., et al. <em>Second International Mars Sample Return</em>. Vol. 2071. 2018.</li> <li>Ody, A., et al. <em>JGR: Planets</em>2 (2013): 234-262.</li> <li>Klein, F., et al. <em>Lithos</em>178 (2013): 55-69.</li> <li>Bjerga, A., et al. <em>Lithos</em>227 (2015): 21-36.</li> <li>Viviano-Beck et al, <em>JGR: Planets 11</em>8.9 (2013)</li> <li>Viviano-Beck et al, <em>JGR: Planets 119.6</em> (2014)</li> </ul>


2004 ◽  
Vol 34 (1) ◽  
pp. 76-84 ◽  
Author(s):  
Mulualem Tigabu ◽  
Per Christer Odén ◽  
Tong Yun Shen

The use of near-infrared (NIR) spectroscopy to discriminate between uninfested seeds of Picea abies (L.) Karst and seeds infested with Plemeliella abietina Seitn (Hymenoptera, Torymidae) larva is sensitive to seed origin and year of collection. Five seed lots collected during different years from Sweden, Finland, and Belarus were used in this study. Initially, seeds were classified as infested or uninfested with X-radiography, and then, NIR spectra from single seeds were collected with a NIR spectrometer from 1100 to 2498 nm with a resolution of 2 nm. Discriminant models were derived by partial least squares regression using raw and orthogonal signal corrected spectra (OSC). The resulting OSC model developed on a pooled data set was more robust than the raw model and resulted in 100% classification accuracy. Once irrelevant spectral variations were removed by using OSC pretreatment, single-lot calibration models resulted in similar classification rates for the new samples irrespective of origin and year of collection. Dis criminant analyses performed with selected NIR absorption bands also gave nearly 100% classification rate for new samples. The origin of spectral differences between infested and uninfested seeds was attributed to storage lipids and proteins that were completely depleted in the former by the feeding larva.


2007 ◽  
Vol 61 (8) ◽  
pp. 882-888 ◽  
Author(s):  
Takaaki Fujimoto ◽  
Hiroyuki Yamamoto ◽  
Satoru Tsuchikawa

This work was undertaken to investigate the feasibility of near-infrared (NIR) spectroscopy for estimating wood mechanical properties, i.e., modulus of elasticity (MOE) and modulus of rupture (MOR) in bending tests. Two sample sets having large and limited density variation were prepared to examine the effects of wood density on estimation of MOE and MOR by the NIR technique. Partial least squares (PLS) analysis was employed and it was found that the relationships between laboratory-measured and NIR-predicted values were good in the case of sample sets having large density variation. MOE could be estimated even when density variation in the sample set was limited. It was concluded that absorption bands due to the OH group in the semi-crystalline or crystalline regions of cellulose strongly influenced the calibrations for bending stiffness of hybrid larch. This was also suggested from the result that both α-cellulose content and cellulose crystallinity showed moderate positive correlation to wood stiffness.


2008 ◽  
Vol 16 (5) ◽  
pp. 481-486 ◽  
Author(s):  
Takayuki Fujiwara ◽  
Keiichi Murakami

The lipid content of swine manure decreases during the process of composting, and inhibitory effects of compost on root growth in germination tests are strongly correlated to lipid content. Therefore, we tested whether the determination of the lipid content of swine waste compost by near infrared (NIR) spectroscopy provided a measure by which the degree of inhibition of plant growth by immature compost could be predicted. Reflectance spectra of untreated compost samples, as well as freeze-dried and milled samples, were taken using a scanning monochromator. Second derivative spectra from 700 nm to 2500 nm and multiple regression analysis were used to develop calibration equations for lipid content and moisture. A pronounced absorption peak of lipid was found at 2310 nm, attributable to the absorption bands of the CH2 stretching–bending combination. However, calibration equations containing this absorption band were inappropriate for lipid determination, because sawdust and rice husk, which were added to the compost, influenced the spectra in this band. The standard error of prediction ( SEP) of the best calibrations for lipids in dry and untreated samples was 6.0 g kg−1 and 3.2 g kg−1, while the ratios of the standard deviation and the range in the prediction set to SEP (RPD and RER) were 5.5 and 2.8, and 13.5 and 5.0, respectively. The main wavelengths of these calibration equations were 1700 nm for dry samples and 1764 nm for untreated samples, which were attributed to the absorption bands of the CH2 stretching first overtone. In conclusion, the determination of lipid content in dry compost samples by NIR spectroscopy provided an indirect estimate of the maturity of swine waste compost. Moreover, NIR spectroscopy was found useful for the rough assessment of the maturity of untreated swine waste compost.


2020 ◽  
Vol 787 (12) ◽  
pp. 16-20
Author(s):  
D.I. Shchikaltsova ◽  
◽  
Yu.T. Platov ◽  
V.A. Rassulov ◽  
R.A. Platova ◽  
...  

Diffuse reflection UV-VIS-NIR spectroscopy was used to study changes in the color of facing bricks from the content of the additive of manganese tetraoxide (Mn3O4) into the ceramic mass. This investigation was shown that with an increase of the additive content, both the intensity of the absorption bands of colored bricks corresponding to hematite decreases, and the absorption intensity increases with a shift in the maximum of the wide absorption band from the visible to the near-infrared range of the spectrum. By changing the values of the color coordinates in the CIE L*a*b* and Mansell systems: lightness and color, and the values of the indicator-relative color ability, it is fixed that the color of a brick depends on the ratio of two pigments: yellowish-red of hematite and black, probably jacobsite in its composition.


2007 ◽  
Vol 15 (3) ◽  
pp. 169-177 ◽  
Author(s):  
C. Camps ◽  
P. Guillermin ◽  
J.C. Mauget ◽  
D. Bertrand

Improved non-destructive instrumental approaches for grading fruit during post-harvest could be an efficient way to monitor stock in the apple industry. The objective of this study was to evaluate the ability of visible-near infrared (vis-NIR) spectroscopy in reflectance mode for classifying apples left on the shelf or stored in a cooled room. The ability of NIR spectroscopy to classify the duration of storage of three apple cultivars in two storage modalities was evaluated. A total of 450 fruit, sampled after 7, 14, 28, 60, 90 and 120 days of storage in a cooled room (CR) and 7, 14 and 28 days in shelflife (SL), has been studied. The classification of these modalities was analysed by factorial discriminant analysis (FDA) pooling the spectral data of all cultivars (global models) into a common data set. Then, the cultivar effect on the classification of the same modalities was analysed by processing data from each cultivar in separate factorial descriminant analyses. A preliminary analysis showed the genetic variability of spectral data due to the three apple cultivars. We show that vis-NIR spectroscopy allowed the correct classification of the fruits of each cultivar by more than 95%. The classification relied on both vis and NIR absorption bands: 500, 680, 1400 to 1700, 1850, 1950, 2200 and 2300 nm. We show that storage modalities of global models can be classified by more than 75% and 83% for fruits stored in a cooled room and shelf, respectively. Classification of the same storage modalities was improved by cultivar models with percentage of individuals correctly classified of 86% (Gala), 89% (Elstar) and 85% (Smoothee) for fruits stored in a cooled room and 95% (Gala), 98% (Elstar) and 95% (Smoothee) for fruits left in shelflife. We conclude that despite the slight increase of efficiency of the models when we considered each apple cultivar separately, global models applicable to a set of different cultivars presents a correct level of classification and could be usefull for some commercial applications.


2000 ◽  
Vol 54 (2) ◽  
pp. 239-245 ◽  
Author(s):  
Hoeil Chung ◽  
Min-Sik Ku

Near-infrared (NIR) spectroscopy has been successfully applied to the determination of API (American Petroleum Institute) gravity of atmospheric residue (AR), which is the heaviest fraction in crude oil. This fraction is completely dark and very viscous. Preliminary studies involving Raman and infrared (IR) spectroscopies were also evaluated along with NIR spectroscopy. The Raman spectrum of AR was completely dominated by strong fluorescence from polycyclic aromatic hydrocarbons, called asphaltenes. IR spectroscopy provided reasonable spectral features; however, its spectral reproducibility was poorer and noisier than that of NIR. Although absorption bands in the NIR region were broad and less characterized, NIR provided better spectral reproducibility with higher signal-to-noise ratio (which is one of the most important parameters in quantitative calibration in comparison to Raman and IR spectroscopies). Partial least-squares (PLS) regression was utilized to develop calibration models. NIR spectra of AR samples were broad, and baselines were varying due to the strong absorption in the visible range. However, the necessary information was successfully extracted and correlated to the reference API gravity with the use of PLS regression. API gravities in the prediction set were accurately predicted with an SEP (standard error of prediction) of 0.22. Additionally NIR showed approximately three times better repeatability compared to the ASTM reference method, which directly influences the process control performance.


2005 ◽  
Vol 13 (1) ◽  
pp. 9-17 ◽  
Author(s):  
Szilveszter Gergely ◽  
András Salgó

The role of bread, pasta and related products produced from milled wheat seeds is important to the human diet, so monitoring changes of starch content in developing grain is essential. Immature wheat grains are also used as a functional food, particularly as a source of water-soluble carbohydrates. The amount and variation in content of different carbohydrates changes considerably during maturation and these changes were non-destructively monitored in developing grain using near infrared (NIR) spectroscopy. Characteristic changes in three carbohydrate absorption bands [1585–1595 nm (Carbohydrate I), 2270–2280 nm (Carbohydrate II) and 2325–2335 nm (Carbohydrate III)] were identified and it was concluded that the different dynamics of carbohydrates (starch accumulation as well as synthesis/decomposition of water-soluble carbohydrates) could be followed sensitively by monitoring these three different regions of NIR spectra. Carbohydrate I represents the effect of starch accumulation during maturation based on the vibrations of intermolecular hydrogen bonded O–H groups in polysaccharides. Carbohydrate II is the manifestation of O–H stretching and C–C stretching vibrations existing unengaged in water-soluble carbohydrates while Carbohydrate III describes the changes in C–H stretching and deformation band of poly- and mono-oligosaccharides. NIR spectroscopic techniques are shown to be effective in monitoring plant physiological processes and the spectra have hidden information for predicting the stage of growth in wheat seed.


Silva Fennica ◽  
2018 ◽  
Vol 52 (4) ◽  
Author(s):  
Mulualem Tigabu ◽  
Mostafa Farhadi ◽  
Lars-Göran Stener ◽  
Per Odén

The genus L. is composed of several species, which are difficult to distinguish in the field on the basis of morphological traits. The aim of this study was to evaluate the taxonomic importance of using visible + near infrared (Vis + NIR) spectra of single seeds for differentiating Roth and Ehrh. Seeds from several families (controlled crossings of known parent trees) of each species were used and Vis + NIR reflectance spectra were obtained from single seeds. Multivariate discriminant models were developed by Orthogonal Projections to Latent Structures – Discriminant Analysis (OPLS-DA). The OPLS-DA model fitted on Vis + NIR spectra recognized with 100% classification accuracy while the prediction accuracy of class membership for was 99%. However, the discriminant models fitted on NIR spectra alone resulted in 100% classification accuracies for both species. Absorption bands accounted for distinguishing between birch species were attributed to differences in color and chemical composition, presumably polysaccharides, proteins and fatty acids, of the seeds. In conclusion, the results demonstrate the feasibility of NIR spectroscopy as taxonomic tool for classification of species that have morphological resemblance.BetulaBetula pendulaBetula pubescensB. pubescensB. pendula


2000 ◽  
Vol 54 (5) ◽  
pp. 715-720 ◽  
Author(s):  
Hoeil Chung ◽  
Min-Sik Ku ◽  
Jaebum Lee ◽  
Jaebum Choo

Near-infrared (NIR) spectroscopy has been successfully used for the monitoring of important components in the p-diethylbenzene (PDEB) separation process. The process is composed of mostly diethylbenzene isomers ( ortho, meta, and para) and extractant ( p-xylene), as well as other C9–C11 aromatic hydrocarbons. Therefore, the major concern in using NIR spectroscopy in this process was the spectral resolution of NIR spectra among diethylbenzene isomers, since the molecular structures of each isomer were very similar. NIR spectral features of o-diethylbenzene (ODEB), m-diethylbenzene (MDEB), and PDEB showed considerable spectral differences in the 2100–2220 nm range. These combination bands originated from the combination of the =C–H stretch at 3100–3000 cm−1 and C=C ring stretch at 1600–1450 cm−1. Characteristic C=C ring stretches of each isomers in the IR region result in selective and identifiable spectral features in the NIR region. Partial least-squares (PLS) regression was used to build each calibration model for ODEB, MDEB, PDEB, and p-xylene (PX). PLS calibration results of the four components showed excellent correlation with gas chromatography data. The combination region (2100–2500 nm) provided the important isomeric spectral information for PLS calibration since the absorption bands in this region were the most sensitive and selective.


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