scholarly journals Using stable isotope tracers to assess hydrological flow paths, residence times and landscape influences in a nested mesoscale catchment

2005 ◽  
Vol 9 (3) ◽  
pp. 139-155 ◽  
Author(s):  
P. Rodgers ◽  
C. Soulsby ◽  
S. Waldron ◽  
D. Tetzlaff
Keyword(s):  
Stream Water ◽  
Spatial Scales ◽  
Isotopic Signature ◽  
Residence Times ◽  
Catchment Scale ◽  
Valley Bottom ◽  
Flow Paths ◽  
Isotope Tracers ◽  
Periodic Regression ◽  
Stream Waters

Abstract. δ18O measurements in precipitation and stream waters were used to investigate hydrological flow paths and residence times at nested spatial scales in the mesoscale (233 km2) River Feugh catchment in the northeast of Scotland over the 2001-2002 hydrological year. Precipitation δ18O exhibited strong seasonal variation, which although significantly damped within the catchment, was reflected in stream water at six sampling sites. This allowed δ18O variations to be used to infer the relative influence of soil-derived storm flows with a seasonally variable isotopic signature, and groundwater of apparently more constant isotopic composition. Periodic regression analysis was then used to examine the sub-catchment difference using an exponential flow model to provide indicative estimates of mean stream water residence times, which varied between approximately 3 and 14 months. This showed that the effects of increasing scale on estimated mean stream water residence time was minimal beyond that of the smallest (ca. 1 km2) headwater catchment scale. Instead, the interaction of catchment soil cover and topography appeared to be the dominant controlling influence. Where sub-catchments had extensive peat coverage, responsive hydrological pathways produced seasonally variable δ18O signatures in runoff with short mean residence times (ca. 3 months). In contrast, areas dominated by steeper slopes, more freely draining soils and larger groundwater storage in shallow valley-bottom aquifers, deeper flow paths allow for more effective mixing and damping of δ18O indicating longer residence times (>12 months). These insights from δ18O measurements extend the hydrological understanding of the Feugh catchment gained from previous geochemical tracer studies, and demonstrate the utility of isotope tracers in investigating the interaction of hydrological processes and catchment characteristics at larger spatial scales.

scholarly journals Using stable isotope tracers to identify hydrological flow paths, residence times and landscape controls in a mesoscale catchment

2005 ◽  
Vol 2 (1) ◽  
pp. 1-35 ◽  
Author(s):  
P. Rodgers ◽  
C. Soulsby ◽  
S. Waldron ◽  
D. Tetzlaff
Keyword(s):  
Stream Water ◽  
Spatial Scales ◽  
Isotopic Signature ◽  
Residence Times ◽  
Catchment Scale ◽  
Mixing Processes ◽  
Flow Paths ◽  
Isotope Tracers ◽  
Periodic Regression ◽  
Stream Waters

Abstract. δ18O tracer measurements of precipitation and stream waters were used to investigate hydrological flow paths and residence times at nested spatial scales in the mesoscale (233 km2 River Feugh catchment in the northeast of Scotland over the 2001-2002 hydrological year. Precipitation δ18O exhibited strong seasonal variation, which although significantly damped by catchment mixing processes, was reflected in stream water outputs at six sampling sites. This allowed δ18O variations to be used to infer the relative influence of soil-derived storm flows with a seasonally variable isotopic signature, and groundwater of more constant isotopic composition. Periodic regression analysis was then used to examine the sub-catchment differences in the mixing of these two main hydrological sources processes more quantitatively, using an exponential flow model to provide preliminary estimates of mean stream water residence times, which varied between 0.4-2.9 years. This showed that the effects of increasing scale on estimated mean stream water residence time was minimal beyond the smallest (ca. 1 km2 headwater catchment scale. Instead, the interaction of catchment soil cover and topography acted as the dominant influence. Responsive hydrological pathways, associated with peat soils in the headwater sub-catchments, produced seasonally variable δ18O signatures in runoff with short mean residence times (0.4-0.8 years). In contrast, areas dominated by more freely draining soils and larger groundwater storage in shallow aquifers appear to provide effective mixing and damping of variable precipitation inputs implying longer residence times (1.4-2.9 years). These insights from δ18O measurements extend the hydrological understanding of the Feugh catchment gained from previous geochemical tracer studies, and demonstrate the utility of isotope tracers in investigating the interaction of hydrological processes and catchment characteristics at the mesoscale.

Using natural strontium isotopic signatures as fish markers: methodology and application

2000 ◽  
Vol 57 (11) ◽  
pp. 2280-2292 ◽  
Author(s):  
Brian P Kennedy ◽  
Joel D Blum ◽  
Carol L Folt ◽  
Keith H Nislow
Keyword(s):  
River Basin ◽  
Stream Water ◽  
Spatial Scales ◽  
Fish Tissue ◽  
Isotopic Signature ◽  
Food Sources ◽  
Sr Isotopes ◽  
Connecticut River ◽  
Isotopic Signatures ◽  
Calcified Tissues

To distinguish Atlantic salmon (Salmo salar) populations in tributaries of the Connecticut River, we studied the incorporation and stability of Sr isotopes in juvenile salmon. We established the geologic basis for unique isotopic signatures in 29 salmon sites. Stream-specific Sr isotopic ratios (87Sr/86Sr) were found in calcified tissues of salmon parr within 3 months of stocking. We found little seasonal variation in the Sr signatures of stream water or fish tissue. There were no significant differences among the Sr signatures of otoliths, scales, and vertebrae. For mature salmon raised under constant conditions, 70% of the Sr isotopic signature in calcified tissues was derived from food sources. We developed a criterion for identifying moving fish based upon the isotopic variability of genetically marked fish. Applying this criterion to our streams, 7% of the fish in our study had incorporated Sr from multiple streams. Strontium isotopes distinguished all 8 regions in the White River basin and 7 of the 10 regions in the West River basin. When watersheds are considered together, Sr isotopes differentiated 11 unique signatures from 18 regions. We conclude that Sr isotopes are an effective marking tool and discuss ways in which they can be combined with other marking techniques over larger spatial scales.

scholarly journals Assessing the value of Cl− and δ18O data in modelling the hydrological behaviour of a small upland catchment in northeast Scotland

2008 ◽  
Vol 39 (5-6) ◽  
pp. 337-358 ◽  
Author(s):  
Sarah M. Dunn ◽  
Jeffrey R. Bacon
Keyword(s):  
Model Simulation ◽  
Shallow Groundwater ◽  
Mixed System ◽  
Residence Times ◽  
Catchment Scale ◽  
Infiltration Excess ◽  
Field Experimentation ◽  
Groundwater Source ◽  
The Uk ◽  
Stream Waters

Model simulation of Cl− and δ18O in stream waters has been investigated as a means of improving interpretation of catchment-scale hydrological processes. The procedure has been evaluated for a small upland catchment which is one of the UK Environmental Change Network sites. Precipitation and stream samples have been analysed for hydrochemical determinands since the mid 1990s and, since November 2004, measurement of δ18O has also been undertaken. A conceptual hydrological model STREAM (STorage REsidence times And Mixing) was applied to the catchment to simulate the hydrology and responses of Cl− and δ18O. Results from model simulations confirmed that the catchment generally behaves as a well-mixed system. The feasibility of flow contributions from a deep groundwater source and infiltration excess runoff was examined, in addition to the apparently dominant shallow groundwater response. The ability to estimate mean residence times and draw strong conclusions about catchment processes was limited by the range of uncertainties in the experimental data and modelling. Integration of the tracer data in the model was found to be of value for probing model sensitivities and developing hypotheses that inform the design of further field experimentation. In this way, the modelling provides key feedback within a catchment learning framework.

Nitrate removal and young stream water fractions at the catchment scale

2020 ◽  
Vol 34 (12) ◽  
pp. 2725-2738 ◽  
Author(s):  
Paolo Benettin ◽  
Ophélie Fovet ◽  
Li Li
Keyword(s):  
Stream Water ◽  
Nitrate Removal ◽  
Catchment Scale ◽  
Water Fractions

Arsenic Contamination and its Speciation in the Water System around the Abandoned Dongil Au-Ag Mine in Korea

2005 ◽  
Vol 277-279 ◽  
pp. 503-509 ◽  
Author(s):  
Ji Min Yi ◽  
Jin Soo Lee ◽  
Hyo Taek Chon
Keyword(s):  
Stream Water ◽  
Arsenic Concentration ◽  
Water System ◽  
Arsenic Species ◽  
High Concentration ◽  
Aqua Regia ◽  
Sequential Extraction Analysis ◽  
Fe Oxyhydroxides ◽  
High Level ◽  
Stream Waters

This study was made to investigate the extent and degree of As contamination in waters and sediments influenced by previous mining activity in the abandoned Dongil Au-Ag mine. Arsenic species was also identified in surface waters and groundwater. The chemical form of As in sediments was examined using sequential extraction analysis. The major contamination source of As in the mine area is suggested to be tailings with elevated levels of 8,718 As mg/kg. This was associated with the release of high level of As into the water system in the study area. The pH values of water samples ranged from 7.7 to 10.1, which was neutral to strong alkaline due to buffering effect by high concentration of Ca and Mg dissolved from carbonate mineral and weathering of concrete. Stream waters contained high level of As within the range of 40.5 to 150.4 ㎍/L and most waters exceeded the permissible level (50 ㎍/L) of As for stream water in Korea. The concentration ratios of As(Ⅲ) to As (total), however, extended in the range of 5.8 to 75% and increased at low pH condition in stream waters. Arsenic concentration in sediments digested by aqua regia (HNO3+HCl) ranged from 162 to 2,077 mg/kg. The highest concentration of As may be due to the direct inflow of tailings. The relatively high percentage (17.1~35.3%) of As coprecipitated with amorphous Fe oxyhydroxides indicates that more severe contamination of As can occur by re-extracting due to changes of chemical environment such as reducing condition.

scholarly journals Form and function in hillslope hydrology: characterization of subsurface flow based on response observations

2017 ◽  
Vol 21 (7) ◽  
pp. 3727-3748 ◽  
Author(s):  
Lisa Angermann ◽  
Conrad Jackisch ◽  
Niklas Allroggen ◽  
Matthias Sprenger ◽  
Erwin Zehe ◽  
...  
Keyword(s):  
Preferential Flow ◽  
Explanatory Power ◽  
Subsurface Flow ◽  
Time Lapse ◽  
Storm Event ◽  
Monitoring Methods ◽  
Catchment Scale ◽  
Flow Paths ◽  
Form And Function ◽  
And Function

Abstract. The phrase form and function was established in architecture and biology and refers to the idea that form and functionality are closely correlated, influence each other, and co-evolve. We suggest transferring this idea to hydrological systems to separate and analyze their two main characteristics: their form, which is equivalent to the spatial structure and static properties, and their function, equivalent to internal responses and hydrological behavior. While this approach is not particularly new to hydrological field research, we want to employ this concept to explicitly pursue the question of what information is most advantageous to understand a hydrological system. We applied this concept to subsurface flow within a hillslope, with a methodological focus on function: we conducted observations during a natural storm event and followed this with a hillslope-scale irrigation experiment. The results are used to infer hydrological processes of the monitored system. Based on these findings, the explanatory power and conclusiveness of the data are discussed. The measurements included basic hydrological monitoring methods, like piezometers, soil moisture, and discharge measurements. These were accompanied by isotope sampling and a novel application of 2-D time-lapse GPR (ground-penetrating radar). The main finding regarding the processes in the hillslope was that preferential flow paths were established quickly, despite unsaturated conditions. These flow paths also caused a detectable signal in the catchment response following a natural rainfall event, showing that these processes are relevant also at the catchment scale. Thus, we conclude that response observations (dynamics and patterns, i.e., indicators of function) were well suited to describing processes at the observational scale. Especially the use of 2-D time-lapse GPR measurements, providing detailed subsurface response patterns, as well as the combination of stream-centered and hillslope-centered approaches, allowed us to link processes and put them in a larger context. Transfer to other scales beyond observational scale and generalizations, however, rely on the knowledge of structures (form) and remain speculative. The complementary approach with a methodological focus on form (i.e., structure exploration) is presented and discussed in the companion paper by Jackisch et al.(2017).

scholarly journals Quantification of water purification in South African palmiet wetlands

2018 ◽  
Vol 78 (5) ◽  
pp. 1199-1207
Author(s):  
Alanna J. Rebelo ◽  
Willem-Jan Emsens ◽  
Karen J. Esler ◽  
Patrick Meire
Keyword(s):  
South African ◽  
Water Purification ◽  
Large Scale ◽  
Poor Quality ◽  
Quality Parameters ◽  
Catchment Scale ◽  
Valley Bottom ◽  
Major Cations ◽  
Dissolved Silicon ◽  
Wetland Processes

Abstract Despite the importance of water purification to society, it is one of the more difficult wetland ecosystem services to quantify. It remains an issue in ecosystem service assessments where rapid estimates are needed, and poor-quality indicators are overused. We attempted to quantify the water purification service of South African palmiet wetlands (valley-bottom peatlands highly threatened by agriculture). First, we used an instantaneous catchment-scale mass balance sampling approach, which compared the fate of various water quality parameters over degraded and pristine sections of palmiet wetlands. We found that pristine palmiet wetlands acted as a sink for water, major cations, anions, dissolved silicon and nutrients, though there was relatively high variation in these trends. There are important limitations to this catchment-scale approach, including the fact that at this large scale there are multiple mechanisms (internal wetland processes as well as external inputs) at work that are impossible to untangle with limited data. Therefore, secondly, we performed a small field-scale field survey of a wetland fragment to corroborate the catchment-scale results. There was a reasonable level of agreement between the results of the two techniques. We conclude that it appears possible to estimate the water purification function of these valley-bottom wetlands using this catchment-scale approach.

scholarly journals DOC-dynamics in a small headwater catchment as driven by redox fluctuations and hydrological flow paths – are DOC exports mediated by iron reduction/oxidation cycles?

2013 ◽  
Vol 10 (2) ◽  
pp. 891-904 ◽  
Author(s):  
K.-H. Knorr
Keyword(s):  
Ionic Strength ◽  
Pore Water ◽  
Surface Waters ◽  
Iron Reduction ◽  
Stream Water ◽  
Riparian Wetlands ◽  
Pore Waters ◽  
Flow Paths ◽  
Discharge Patterns ◽  
Iron Concentrations

Abstract. Dissolved organic carbon (DOC) exports from many catchments in Europe and North-America are steadily increasing. Several studies have sought to explain this observation. As possible causes, a decrease in acid rain or sulfate deposition, concomitant reductions in ionic strength and increasing temperatures were identified. DOC often originates from riparian wetlands; but here, despite higher DOC concentrations, ionic strength in pore waters usually exceeds that in surface waters. In the catchment under study, DOC concentrations were synchronous with dissolved iron concentrations in pore and stream water. This study aims at testing the hypothesis that DOC exports are mediated by iron reduction/oxidation cycles. Following the observed hydrographs, δ18O of water and DOC fluorescence, the wetlands were identified as the main source of DOC. Antecedent biogeochemical conditions, i.e., water table levels in the wetlands, influenced the discharge patterns of nitrate, iron and DOC during an event. The correlation of DOC with pH was positive in pore waters, but negative in surface waters; it was negative for DOC with sulfate in pore waters, but only weak in surface waters. Though, the positive correlation of DOC with iron was universal for pore and surface water. The decline of DOC and iron concentrations in transition from anoxic wetland pore water to oxic stream water suggests a flocculation of DOC with oxidising iron, leading to a drop in pH in the stream during high DOC fluxes. The pore water did not per se differ in pH. There is, thus, a need to consider processes more thoroughly of DOC mobilisation in wetlands when interpreting DOC exports from catchments. The coupling of DOC with iron fluxes suggested that increased DOC exports could at least, in part, be caused by increasing activities in iron reduction, possibly due to increases in temperature, increasing wetness of riparian wetlands, or by a shift from sulfate dominated to iron reduction dominated biogeochemical regimes.

scholarly journals The impact of conifer harvesting on stream water quality: the Afon Hafren, mid-Wales

2004 ◽  
Vol 8 (3) ◽  
pp. 503-520 ◽  
Author(s):  
C. Neal ◽  
B. Reynolds ◽  
M. Neal ◽  
H. Wickham ◽  
L. Hill ◽  
...  
Keyword(s):  
Water Quality ◽  
Stream Water ◽  
Strong Support ◽  
Shallow Groundwater ◽  
Water Quality Monitoring ◽  
Quality Data ◽  
Stream Water Quality ◽  
Catchment Scale ◽  
Water Quality Data ◽  
The Impact

Abstract. Results for long term water quality monitoring are described for the headwaters of the principal headwater stream of the River Severn, the Afon Hafren. The results are linked to within-catchment information to describe the influence of conifer harvesting on stream and shallow groundwater quality. A 19-year record of water quality data for the Hafren (a partially spruce forested catchment with podzolic soil) shows the classic patterns of hydrochemical change in relation to concentration and flow responses for upland forested systems. Progressive felling of almost two-thirds of the forest over the period of study resulted in little impact from harvesting and replanting in relation to stream water quality. However, at the local scale, a six years’ study of felling indicated significant release of nitrate into both surface and groundwater; this persisted for two or three years before declining. The study has shown two important features. Firstly, phased felling has led to minimal impacts on stream water. This contrasts with the results of an experimental clear fell for the adjacent catchment of the Afon Hore where a distinct water quality deterioration was observed for a few years. Secondly, there are localised zones with varying hydrology that link to groundwater sources with fracture flow properties. This variability makes extrapolation to the catchment scale difficult without very extensive monitoring. The implications of these findings are discussed in relation to strong support for the use of phased felling-based management of catchments and the complexities of within catchment processes. Keywords: deforestation, water quality, acidification, pH, nitrate, alkalinity, ANC, aluminium, dissolved organic carbon, Plynlimon, forest, spruce, Afon Hafren, podzol

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