scholarly journals Silica diagenesis-driven fracturing in limestone: an example from the Ordovician of Central Pennsylvania

2020 ◽  
Author(s):  
Emily M. Hoyt ◽  
John N. Hooker
Keyword(s):  
Host Rock ◽  
Silica Content ◽  
Mechanical Anisotropy ◽  
Driving Mechanism ◽  
Point Count ◽  
Silica Diagenesis ◽  
Central Pennsylvania ◽  
Fracture Intensity ◽  
Calcite Cement ◽  
Fracturing Mechanism

Abstract. Fracture patterns, interactions, and crosscutting relationships are tools for interpretation of fractures as paleostress indicators for past tectonic events and as past or present-day fluid-flow networks. In the Appalachian Basin in Central Pennsylvania along Mount Nittany Expressway Route 322 lies a significantly stratified fracture set hosted in Ordovician age limestone. Tectonic strain is a problematic mechanism for these fractures because they are hosted in individual beds lacking apparent mechanical significance relative to other limestone beds in the outcrop. Many of the fractures are layer-parallel, a characteristic commonly observed in shales, due to shales' mechanical anisotropy and tendency to develop fluid overpressures; however, these fracture-hosting limestones lack obvious mechanical anisotropy. Fracture orientations vary, but desiccation, bentonite swelling, and dolomitization are eliminated by an interpreted transgressional paleoenvironment and a deficiency of the hypothesized minerals. X-ray diffraction determined the composition of samples collected, point-count quantification determined fracture intensity, and optical petrography recorded scaled petrographic photographs. Comparison between fracture intensity and host-rock minerals reveal that silica content is consistently depleted in fractured layers relative to unfractured layers. The diagenetic transition of biogenic silica to quartz is suggested to be the driving mechanism based on silica being present as biogenic grains, as well as cement and detrital grains, and fractures being filled with calcite cement. Silica migration explains the volume lost from fractured layers in a proposed horizontal fracturing mechanism whereby the host rock shrinks but is excluded from vertical contraction.

Lithostratigraphy, facies, mineralogy and diagenesis of the retrograding, syntectonic Neogene Barzaman Formation (Al-Khod, Sultanate of Oman)

2020 ◽  
Author(s):  
Frank Mattern ◽  
Shaima Al-Amri ◽  
Andreas Scharf
Keyword(s):  
Depositional Environment ◽  
High Energy ◽  
Silica Content ◽  
Slope Instability ◽  
Coarse Grained ◽  
Tectonic Activity ◽  
Shallow Marine ◽  
Ephemeral Ponds ◽  
Terrestrial Environments ◽  
Calcite Cement

<p>The Barzaman Formation is 150-200 m thick and subdivided into five lithostratigraphic/facies intervals recording syndepositional thrusting and changes from shallow marine to terrestrial environments and from arid/semiarid to more humid conditions.</p><p>(1) The basal lower conglomerate and sandstone unit is >36 m thick, marked by beige and gray/greenish colors, thick-bedded pebbly, calciclastic litharenites which may display parallel lamination and thick-bedded matrix-supported pebble to cobble conglomerates with subrounded clasts of chert, basalt, gabbro, quartzite and carbonates. Pores may be lined by isopachous, microcrystalline calcite cement. The depositional environment is shallow marine with one coarse-grained fill of a high-energy tidal inlet.</p><p>(2) The light-colored carbonate facies unit is 1-15 m thick, consisting of thick-bedded coral limestone, a very thick limestone coral and algae debrite and some minor beds of conglomerate and sandstone. The corals may be partly silicified by brown-stained silica. This unit was deposited in a warm, shallow marine, nearshore environment with clear water which may indicate an arid climate.</p><p>(3) The varicolored thick sandstone and conglomerate facies unit is 14-28.5 m thick. These clastic deposits are similar to those of unit 1, but more colorful, slightly coarser grained (presence of boulders) and include also thin and medium beds. The sandstones may exhibit cross-bedding. The depositional environment is shallow marine as indicated by coral debris.</p><p>(4) The claystone and conglomerate facies unit is 19 m thick. The clastic sediments are similar to those of unit 1, but pebbly sandstones are comparatively rare, and claystone beds are present, including a 20-cm-thick cellular claystone (palygorskite, vermiculite with some calcite) as well as light gray, medium-bedded claystone beds, consisting mainly of palygorskite with some saponite and/or clinochlore, associated with minute, euhedral dolomite or ankerite crystals. All claystone beds are evaporitic, lacustrine deposits of ephemeral ponds and pools on wadi floors whereas the coarser beds represent wadi conglomerates. Some beds are imbricated slide units. The paleoclimate was hot, semiarid or arid.</p><p>(5) The dolomitic conglomerate facies unit may measure >61 m in thickness. The respective pebble conglomerates consist of clasts that seem to “float” in cement. The cements of the basal >10 m are brown-stained silica and some white dolomite. The silica content gradually decreases upward. The upper part is dominated by white dolomite and some calcite. The dolomite cement may have formed under phreatic conditions (groundwater) during the Late Miocene to Pliocene when the arid/semiarid Miocene climate became more humid.    </p><p>Close to the base of unit 4, the upper part of an east-dipping syndepositional thrust is exposed (Mattern et al., 2018). Faulting approximately coincides with the change from marine to terrestrial conditions. In addition, the syndepostional tectonic activity may explain aspects of slope instability: debrite in unit 2, slide units in unit 4.</p><p> </p><p>References</p><p>Mattern, F., Scharf, A., Al-Amri, S.H.K., 2018. East-west directed Cenozoic compression in the Muscat area (NE Oman): timing and causes. Gulf Seismic Forum, 19-22 March 2018, Muscat, Oman, Book of Abstracts, p. 4-7.</p>

Structure-property relations of liquid crystalline polymers

1987 ◽  
Vol 45 ◽  
pp. 460-463
Author(s):  
Linda C. Sawyer
Keyword(s):  
Solid State ◽  
Liquid Crystalline ◽  
Structural Model ◽  
Crystalline Polymer ◽  
Liquid Crystalline Polymers ◽  
Mechanical Anisotropy ◽  
Structure Property ◽  
Preparation Methods ◽  
Crystalline Polymers ◽  
Extended Chain

Recent liquid crystalline polymer (LCP) research has sought to define structure-property relationships of these complex new materials. The two major types of LCPs, thermotropic and lyotropic LCPs, both exhibit effects of process history on the microstructure frozen into the solid state. The high mechanical anisotropy of the molecules favors formation of complex structures. Microscopy has been used to develop an understanding of these microstructures and to describe them in a fundamental structural model. Preparation methods used include microtomy, etching, fracture and sonication for study by optical and electron microscopy techniques, which have been described for polymers. The model accounts for the macrostructures and microstructures observed in highly oriented fibers and films.Rod-like liquid crystalline polymers produce oriented materials because they have extended chain structures in the solid state. These polymers have found application as high modulus fibers and films with unique properties due to the formation of ordered solutions (lyotropic) or melts (thermotropic) which transform easily into highly oriented, extended chain structures in the solid state.

Effect of furnace atmosphere and silica content on the consolidation behaviour of magnesia partially stabilised zirconia

1990 ◽  
Vol 48 (4) ◽  
pp. 1056-1057
Author(s):  
J. Drennan ◽  
R.H.J. Hannink ◽  
D.R. Clarke ◽  
T.M. Shaw
Keyword(s):  
Liquid Phase ◽  
Silica Content ◽  
Liquid Phase Sintering ◽  
Furnace Atmosphere ◽  
Boundary Phase ◽  
Analytical Electron ◽  
Analytical Electron Microscope ◽  
Series Of Experiments ◽  
Compositional Gradients ◽  
Mobile Liquid

Magnesia partially stabilised zirconia (Mg-PSZ) ceramics are renowned for their excellent nechanical properties. These are effected by processing conditions and purity of starting materials. It has been previously shown that small additions of strontia (SrO) have the effect of removing the major contaminant, silica (SiO2).The mechanism by which this occurs is not fully understood but the strontia appears to form a very mobile liquid phase at the grain boundaries. As the sintering reaches the final stages the liquid phase is expelled to the surface of the ceramic. A series of experiments, to examine the behaviour of the liquid grain boundary phase, were designed to produce compositional gradients across the ceramic bodies. To achieve this, changes in both silica content and furnace atmosphere were implemented. Analytical electron microscope techniques were used to monitor the form and composition of the phases developed. This paper describes the results of our investigation and the presentation will discuss the work with reference to liquid phase sintering of ceramics in general.

DIVERSITY AND DISTRIBUTION OF ORIBATID MITE FAUNA(ACARI: ORIBATIDA) IN THE FOREST FLOOR OF SATKOSIA BASIPALLY WILD LIFE SANCTUARY, ODISHA, INDIA

2017 ◽  
Vol 23 (1) ◽  
Author(s):  
SHELLEY ACHARYA ◽  
ADITI DUTTA
Keyword(s):  
Forest Floor ◽  
Dominant Species ◽  
Oribatid Mite ◽  
Soil Condition ◽  
Silica Content ◽  
Soil Mites ◽  
The Core ◽  
Humid Condition ◽  
Core Areas ◽  
Wild Life

The studies were mostly concentrated in Nine forest ranges of the WLS including the core areas. The soil of this region mostly is dry, red and with iron and silica content. Though the soil mites are prevalent in moist humid condition, we got a diversed population of 20 different species under 14 genera which is less than average probably due to the soil condition. Protoribates magnus is the dominant species in this study. The species with larger ranges were Scheloribates curvialatus.

Reconstruction of maximum temperature on Zhegu Mountain, western Sichuan Plateau (China)

2020 ◽  
Vol 81 ◽  
pp. 1-14
Author(s):  
M Keyimu ◽  
Z Li ◽  
Y Zhao ◽  
Y Dong ◽  
B Fu ◽  
...  
Keyword(s):  
Tree Growth ◽  
Ring Width ◽  
Volcanic Eruptions ◽  
Southwestern China ◽  
Maximum Temperature ◽  
Driving Mechanism ◽  
Western Sichuan ◽  
Relationship Analysis ◽  
Decadal Scale ◽  
Thermal Variability

Historical temperature reconstructions at high altitudes are still insufficient in southwestern China, which is considered one of the most sensitive areas to climate change in the world. Here we developed a tree ring-width chronology of Faxon fir Abies fargesii var. faxoniana at the upper timber line on Zhegu Mountain, Miyaluo Scenic Area, western Sichuan, China. The climate-tree growth relationship analysis indicated temperature as the dominant regulator on radial tree growth in this region. The reconstruction of aggregated maximum temperature (TMX) of autumn and winter for the period 1856-2016 was achieved with a linear regression model that accounted for 43.6% of the actual variability in the common time series (1954-2016). The reconstruction identified 4 warm periods and 3 cold periods. Similarities of warm and cold periods with previously published reconstructions from nearby sites indicated the reliability of our reconstruction. The significant positive correlation between TMX reconstruction and the Asian-Pacific Oscillation index and the Atlantic Multi-decadal Oscillation index suggested a linkage between large-scale climate circulations and the thermal variability at a multi-decadal scale on the western Sichuan Plateau. We also found that solar activity exerted a strong influence on decadal temperature variability in this region. The cold periods were matched well with historical large volcanic eruptions. Our results strengthen the historical climatic information in southwestern China and contribute to further understanding the regional thermal variability as well as its driving mechanism.

Optimal Density Determination of Bouguer Anomaly Using Fractal Analysis (Case of study: Charak area,IRAN)

2005 ◽  
Vol 1 (1) ◽  
pp. 21-24
Author(s):  
Hamid Reza Samadi
Keyword(s):  
Surface Roughness ◽  
Fractal Dimension ◽  
Fractal Analysis ◽  
Fractal Geometry ◽  
Host Rock ◽  
Bouguer Anomaly ◽  
Research Area ◽  
Density Difference ◽  
Optimal Density

In exploration geophysics the main and initial aim is to determine density of under-research goals which have certain density difference with the host rock. Therefore, we state a method in this paper to determine the density of bouguer plate, the so-called variogram method based on fractal geometry. This method is based on minimizing surface roughness of bouguer anomaly. The fractal dimension of surface has been used as surface roughness of bouguer anomaly. Using this method, the optimal density of Charak area insouth of Hormozgan province can be determined which is 2/7 g/cfor the under-research area. This determined density has been used to correct and investigate its results about the isostasy of the studied area and results well-coincided with the geology of the area and dug exploratory holes in the text area

Fracture Modelling Using Seismic Based Fracture Intensity Volume, a Case Study in Middle East

2013 ◽  
Author(s):  
Mu Hansheng ◽  
Liu Chuanxi ◽  
Li Peng ◽  
Pang Huihua
Keyword(s):  
Middle East ◽  
Fracture Intensity

Modelling a Multi-Dimensional Model of Memory Performance in Obsessive-Compulsive Disorder: A Multi-Level Meta-Analytic Review.

2020 ◽  
Author(s):  
Sofia Persson ◽  
Alan Yates ◽  
Klaus Kessler ◽  
Ben Harkin
Keyword(s):  
Executive Function ◽  
Obsessive Compulsive Disorder ◽  
Memory Load ◽  
Memory Performance ◽  
Effect Sizes ◽  
Driving Mechanism ◽  
Obsessive Compulsive ◽  
Compulsive Disorder ◽  
Analytic Review ◽  
Multi Level

Even though memory performance is a commonly researched aspect of Obsessive-Compulsive Disorder (OCD), a coherent and unified explanation of the role of specific cognitive factors has remained elusive. To address this, the present meta-analysis examined the predictive validity of Harkin and Kessler’s (2011) Executive Function (E), Binding Complexity (B) and Memory Load (L) Classification System with regards to affected vs. unaffected memory performance in OCD. We employed a multi-level meta-analytic approach (Viechtbauer, 2010) to accommodate the interdependent nature of the EBL model and interdependency of effect sizes (305 effect sizes from 144 studies, including 4424 OCD patients). Results revealed that the EBL model predicted memory performance, i.e., as EBL demand increases, those with OCD performed progressively worse on memory tasks. Executive function was the driving mechanism behind the EBL’s impact on OCD memory performance and negated effect size differences between visual and verbal tasks in those with OCD. Comparisons of sub-task effect sizes were also generally in accord with the cognitive parameters of the EBL taxonomy. We conclude that standardised coding of tasks along individual cognitive dimensions and multi-level meta-analyses provides a new approach to examine multi-dimensional models of memory and cognitive performance in OCD and other disorders.

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