Molecular Weight and Polydispersivity of Rubber by Diffusion Measurements

1947 ◽  
Vol 20 (2) ◽  
pp. 377-379
Author(s):  
A. G. Pasynskii ◽  
T. V. Gatovskaya
Keyword(s):  
Molecular Weight ◽  
Natural Rubber ◽  
Average Value ◽  
Type Iv ◽  
Average Diffusion Coefficient ◽  
Average Diffusion ◽  
The Difference ◽  
Diffusion Curves ◽  
Fair Degree

Abstract The study of diffusion in solutions of natural rubber (light crepe) by Lamm's method showed that even with a concentration of 0.1 per cent the normalized experimental diffusion curves diverge from the ideal Gaussian curve (Figure 1), in that they are characterized by a marked asymmetry and an excess of the maximal ordinate. It follows from an analysis of the experimental curves by the method of moments (up to moments of the fourth order) that they belong to Type IV Pearson curves, that is, to asymmetrical distribution curves with asymptotic branches. The determination of the perturbation multiplier enables us to calculate the course of the experimental curves with a fair degree of accuracy. The physical cause of asymmetry of the diffusion curves is the difference in the rate of diffusion to both sides of the interface (of the polymer into the solvent and back) due to a marked intermolecular interaction in the solution of the polymer at a given concentration. With a decrease of the concentration or of the molecular weight of the dissolved substance, the asymmetry of the diffusion curves becomes less pronounced. However, this asymmetry does not preclude the computation of the average diffusion coefficient D from the standard deviation of the curve. It can, indeed, be shown that the probable error does not exceed 1 per cent. The average value found for natural rubber in carbon tetrachloride is D20°=0.71×10−7 sq. cm. per sec.

Determination of Peroxides in Synthetic Rubbers

1945 ◽  
Vol 18 (4) ◽  
pp. 874-876
Author(s):  
Richard F. Robey ◽  
Herbert K. Wiese
Keyword(s):  
Molecular Weight ◽  
Natural Rubber ◽  
Quantitative Determination ◽  
High Molecular Weight ◽  
Active Oxygen ◽  
Lower Molecular Weight ◽  
Synthetic Rubber ◽  
High Molecular Weight Polymers ◽  
Methanol Solutions

Abstract Peroxides are found in synthetic rubbers either as the result of attack by oxygen, usually from the air, or as a residue from polymerization operations employing peroxide catalysts. Because of possible detrimental effects of active oxygen on the properties of the rubber, a method of quantitative determination is needed. The concentration of peroxides in substances of lower molecular weight may be determined with ferrous thiocyanate reagent, either titrimetrically as recommended by Yule and Wilson or colorimetrically as by Young, Vogt, and Nieuwland. Unfortunately, many highly polymeric substances are not soluble in the acetone and methanol solutions employed in these procedures. This is also the case with hydrocarbon monomers, such as butadiene, containing appreciable concentrations of soluble high molecular weight polymers. Bolland, Sundralingam, Sutton and Tristram recommended benzene as a solvent for natural rubber samples and the reagent made up in methanol. However, most synthetic rubbers are not readily soluble even in this combination. The following procedure employs the ferrous thiocyanate reagent in combination with a solvent capable of maintaining considerable concentrations of synthetic rubber in solution. The solvent comprises essentially 20 per cent ethanol in chloroform.

Ozonolytic Degradation of Interpolymers of Natural Rubber with Methyl Methacrylate and Styrene

1958 ◽  
Vol 31 (1) ◽  
pp. 82-85
Author(s):  
D. Barnard
Keyword(s):  
Molecular Weight ◽  
Carbon Black ◽  
Natural Rubber ◽  
Accurate Determination ◽  
Synthetic Polymers ◽  
Polymer Chains ◽  
Low Molecular Weight ◽  
Rubber Content ◽  
Tert Butyl Hydroperoxide

Abstract The preparation of graft and block interpolymers of natural rubber and synthetic polymers has made it desirable that the number and size of polymer chains attached to rubber be readily determinate. The degradation of unsaturated polymers with tert-butyl hydroperoxide in the presence of osmium tet oxide has been used for the determination of free polystyrene in SBR and carbon black in several elastomers, and has recently been applied to the present problem. The accurate determination of the rubber content of interpolymers by quantitative ozonolysis essentially according to the method of Boer and Kooyman suggested that this might be made the basis of isolation of the attached polymer, the rubber being degraded into fragments of low molecular weight, from which the polymer could be separated by conventional techniques. The method should be applicable to any interpolymer, or mixture, of a polyunsaturated and a saturated polymer and is illustrated with reference to interpolymers of natural rubber (NR)-polymethyl methacrylate (PMM) and NR-polystyrene (PS).

Determination of Mercury in Biological Materials

1970 ◽  
Vol 53 (6) ◽  
pp. 1172-1175 ◽  
Author(s):  
M T Jeffus ◽  
J S Elkins ◽  
C T Kenner
Keyword(s):  
Sulfuric Acid ◽  
Standard Deviation ◽  
Nitric Acid ◽  
Biological Samples ◽  
Room Temperature ◽  
Gold Foil ◽  
Average Recovery ◽  
Average Value ◽  
The Difference

Abstract Mercury in biological samples is determined by digestion in nitric acid, sulfuric acid, and permanganate, followed by reduction and aeration for measurement by atomic absorption at room temperature. The average recovery is 95.8% with a standard deviation of 13.3%. The standard deviation, calculated from the difference between duplicates of 23 samples, is 0.063 μg mercury, which represents 9.4% of the average value of the samples. The method is simple and requires approximately 4 hr for completion. Mercury can be confirmed by adsorption on gold foil after maximum absorbance has been obtained during aeration.

MOLECULAR WEIGHTS FROM MICRO QUANTITIES OF MATERIALS

1949 ◽  
Vol 27b (3) ◽  
pp. 151-157 ◽  
Author(s):  
I. E. Puddington
Keyword(s):  
Molecular Weight ◽  
Vapor Pressure ◽  
Chemical Compounds ◽  
Unknown Compound ◽  
Molecular Weights ◽  
Pure Solvent ◽  
Unknown Substance ◽  
The Difference

A method is proposed for the determination of the molecular weight of chemical compounds in which the unknown substance may be used successfully m quantities of 1 mgm. or less. The method depends on the accurate measurement of the difference in vapor pressure between a solution of the unknown compound and the pure solvent, and this is accomplished with a modified mercury U-tube manometer. The results presented indicate that the difference between the experimental and theoretical molecular weights is of the order of 2%. Determinations require from two to three hours and the sample may be recovered.

Behavior of Different Fractions of Purified Hevea Rubber during Vulcanization

1949 ◽  
Vol 22 (4) ◽  
pp. 994-999
Author(s):  
G. T. Verghese
Keyword(s):  
Molecular Weight ◽  
Natural Rubber ◽  
The Other ◽  
Stress Strain ◽  
Strain Behavior ◽  
Other Hand ◽  
The Difference

Abstract Considerable data on the vulcanization characteristics of molecular fractions of ordinary (unpurified) natural rubber are available. There is, on the other hand, little information of any systematic work on the vulcanization of purified rubber and of its fractions. Pummerer and Pahl vulcanized the sol and gel fractions obtained from purified Hevea rubber, and also the purified whole rubber. But apart from a statement that whole rubber vulcanized much faster than the two fractions obtained from it, no details have been published. Vulcanization of purified whole rubber and of its sol and gel fractions was studied also by Smith and Holt. They concluded that the difference which they observed in the stress-strain behavior of the fractions and whole rubber was due to differences in the rubber which persisted through vulcanization. The present paper deals with a study of the vulcanization characteristics of different fractions of purified rubber prepared by a method described in a previous paper. Also, for comparative purposes a similar study was made of the corresponding fractions of unpurified rubber. As the difference in molecular weight of some of the fractions obtained by the above method was rather small, a grouping of the fractions was made as follows :

Determination of the Molecular Weight of Rubber and Polystyrene by the Methods of Light Scattering and Osmometry

1950 ◽  
Vol 23 (1) ◽  
pp. 89-97
Author(s):  
B. Dogadkin ◽  
I. Soboleva ◽  
M. Arkhangel'skaya
Keyword(s):  
Molecular Weight ◽  
Light Scattering ◽  
Natural Rubber ◽  
Satisfactory Agreement ◽  
Molecular Weights ◽  
Molecular Compounds

Abstract 1. Experiments on the determination of the molecular weights of natural rubber and other high-molecular compounds by the methods of light scattering and osmometry are reported. 2. An osmometer of new design, suitable for determining molecular weights, is described. 3. It is shown that the method of light scattering yields values for molecular weights which are in satisfactory agreement with those obtained by the method of osmometry.

The Comparative Determination of the Molecular Weight of Rubber by the Methods of Light-Scattering and Osmometry

1956 ◽  
Vol 29 (2) ◽  
pp. 477-484
Author(s):  
B. Dogadkin ◽  
I. Soboleva ◽  
M. Arkhangelskaya
Keyword(s):  
Molecular Weight ◽  
Light Scattering ◽  
Natural Rubber ◽  
High Molecular Weight ◽  
Scattering Method ◽  
Comparative Determination

Abstract 1. An account is given of experiments to determine the molecular weight of natural rubber and other high molecular-weight compounds by light-scattering and osmometry. 2. A new design of osmometer for determining molecular weight is described. 3. It is shown that the light-scattering method gives molecular weight values which agree satisfactorily with those given by the osmotic method.

scholarly journals Comparison of the Board of Trade ampere-standard balance with the Ayrton-Jones current-weigher; with an appendix on the electromotive forces of standard cells

1908 ◽  
Vol 80 (540) ◽  
pp. 383-389 ◽  
Keyword(s):  
Technical College ◽  
National Physical Laboratory ◽  
Current Strength ◽  
Physical Laboratory ◽  
The Difference ◽  
Set Up ◽  
High Degree ◽  
A Current ◽  
Fair Degree

When the Board of Trade ampere balance was set up and verified in 1894, the platinum weight (marked A) used with the instrument was adjusted so that a current which deposited silver from a 15-per-cent. solution of silver nitrate at the rate of 1·118 milligrammes per second produced, on reversal, a change of force equal to the weight of A. At that period such a current was believed to represent the ampere , viz., 1/10 of a C. G. S. unit, with a fair degree of accuracy. During the last few years a new current weigher, designed at the Central Technical College, has been constructed at the National Physical Laboratory with a precision previously not obtained in any instrument for the absolute determination of current strength, and by means of it the electrochemical equivalent of silver has been determined to a very high degree of accuracy. We therefore considered it of interest to determine the difference between the units of current as measured by the two balances, and at the same time ascertain how nearly the ampere, as measured by the Board of Trade balance, deposits silver at the rate of 1·118 milligrammes per second.

scholarly journals Pilot study on feasibility of application of gas chromatography for the assessment of acrylamide concentration in sewage sludge.

2014 ◽  
Vol 61 (2) ◽  
Author(s):  
Elżbieta Włodarczyk ◽  
Marta Próba ◽  
Lidia Wolny ◽  
Łukasz Wojtal
Keyword(s):  
Gas Chromatography ◽  
Water Treatment ◽  
Pilot Study ◽  
Sewage Sludge ◽  
Ethyl Acetate ◽  
Toxic Substance ◽  
Average Value ◽  
Bromination Reaction ◽  
The Difference

The aim of this study was to determine the possibility of using gas chromatography to measurement of the acrylamide concentration in sewage sludge. Acrylamide, as a toxic substance, is not indifferent to human health, but it is used in the production of plastics, dyes, adhesives, cosmetics, mortar, as well as a coagulant for water treatment, wastewater or sewage sludge conditioning. Determination of acrylamide by gas chromatography was based on standard: EPA Method 8032A "Acrylamid by gas chromatography." It consists of a bromination reaction of the compound in the presence of dibromopropendial derivative, a triple extraction with the ethyl acetate, a concentration of the eluate sample up to the 1 ml volume, and an analysis by the gas chromatography using an electron capture detector (ECD). The acrylamide concentration of was calculated according to the formula presented in the mentioned standard. All samples were performed twice (the difference between the results was not greater than 10%), and the average value of the four samples was 17.64 µg/L(-1). The presence of acrylamide in sewage sludge has been confirmed.

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