scholarly journals Kinetics Modelling of Pseudomonas stutzeri strain DN2 Growth Behaviour in Tributyltin Chloride

2021 ◽  
Vol 9 (2) ◽  
pp. 13-18
Author(s):  
Abdussamad Abubakar ◽  
Garba Uba ◽  
Hadiza Aliyu Biu

A predictive model was performed to describe Pseudomonas stutzeri strain DN2 growth behaviour in tributyltin chloride, using primary Modelling and a polynomial model as a secondary predictive model. In this investigation, data predicted using the modified Logistic (ML) was the most accurate. The Bias Factor (Bf) and Accuracy Factor (Af) values for the (ML) model were 1.39 and 1.51, indicating that the predictions were within a reliable range. The low RMSE value of 0.14, R2 and adj R2 (0.99) value closer to 1, showing that modified logistics is better than the other models at describing the growth behaviour of Pseudomonas stutzeri strain DN2 in toxic tributyltin chloride. Both the Aiba and Haldane models on the other hand, among the secondary model best fit the behaviours having low RMSE and MSE values and adjR2 value closer to 1. In this study, the primary and secondary kinetics of Pseudomonas stutzeri strain DN2 growth behaviour in tributyltin chloride was explored and it was shown in this study that the modified logistic and the Haldane models better suit the growth behavior of Pseudomonas stutzeri strain DN2 in tributyltin chloride. The parameters obtained from the modelling exercise will be very valuable in transferring the laboratory results to the field.

Author(s):  
Yasser Hannachi

In this paper, removal of Ni (II) from aqueous solution by finely ground waste sludge (FGWS) was investigated. Waste sludge samples obtained from a varnishes and lacquers industry wastewater treatment plant was dried, ground and pre-treated with 1% H2O2 to improve the biosorption capacity. Kinetics of nickel biosorption onto FGWS was investigated by using the FGWS samples with particle size of 62.2 µm. The pseudo-first and second order rate expressions were used to correlate the experimental data. The kinetic constants were determined for both models and the second order rate expression was found to be more suitable. Three different biosorption isotherms were used to correlate the equilibrium biosorption data and the isotherm constants were determined. The Langmuir isotherm was found to fit the experimental data better than the other tested isotherms. The biosorption capacity (qm) and saturation constant (K) for the Langmuir isotherm showed that finely ground waste sludge has the largest capacity and affinity for removal of Ni(II) compared to the other Activated sludges. Santrauka Nagrinėjami Ni(II) šalinimo iš vandeninių tirpalų smulkiai sumaltu nuotekų dumblu (SSND) tyrimų rezultatai. Nuotekų dumblo pavyzdžiai imti iš glazūravimo ir lakavimo pramonės nuotekų valymo įrenginių, išdžiovinti, susmulkinti ir apdoroti 1% H2O2, kad padidėtų biosorbcijos tūris. Nikelio sorbcijos SSND kinetika tirta naudojant SSND bandinius, kurių dalelių dydis 62,2 µm. Pseudo pirmojo ir antrojo laipsnio greičio išraiškos buvo taikomos eksperimentinių duomenų koreliacijai apibrėžti. Kinetinė konstanta nustatyta abiejų modelių, tačiau antrojo laipsnio greičio išraiška buvo tinkamesnė. Pagal tris skirtingas biosorbcijos izotermes nustatyta biosorbcijos pusiausvyros duomenų koreliacija, rastos izotermių konstantos. Langmiuro (Langmuir) izotermė geriau atitiko eksperimentinius duomenis nei kitos tirtosios izotermės. Pagal Langmiuro izotermę biosorbcijos geba (q m) ir prisotinimo konstanta (K) rodė, kad smulkiai sumalto nuotekų dumblo geba šalinti Ni(II) yra didžiausia, palyginti su kitos rūšies aktyvintojo dumblo. Резюме Исследуется удаление Ni(II) из водных растворов мелко измельченным илом стоков (МИИС). Образцы ила стоковбыли взяты из оборудования по очистке стоков в промышленности по глазурованию и лакованию. Затем образцы были высушены, измельчены и обработаны 1-процентным H2O2, с целью увеличить объем биосорбции. Кинетика сорбции никеля МИИС исследовалась с применением образцов МИИС, величина частиц которых составляла62,2 μм. Выражения скорости псевдопервой и псевдовторой степени использовались для определения корреляции экспериментальных данных. Кинетическая константа была установлена для обеих моделей. Однако выражение скорости второй степени оказалось более приемлемым. Три разные изотермы биосорбции применялись для определения корреляции данных по равновесию биосорбции и констант изотерм. Изотерма Langmuir лучше совпала с экспериментальными данными, чем другие испытуемые изотермы. Способность биосорбции (q m) изотермы Langmuir и константа насыщения (K) показали, что мелко измельченный ил стоков обладает наибольшей способностью удалять Ni(II) по сравнению с другими видами активированного ила.


Author(s):  
Jennifer A Nisbet ◽  
J A Owen ◽  
Gail E Ward

Data obtained from routine analytical radioimmunoassays were processed using five curve-fitting procedures, viz. ‘Amersham’, single binding site, four parameter logistic, a linear logit-log and a polynomial logit-log. The polynomial logit-log procedure gave the best fit, but this was probably due to the inherent flexibility of this curve-fitting process since the analytical precision achieved with it was no better than what was obtained with most of the other procedures. A limited study failed to show that statistical weighting of data before curve fitting had any practical advantage.


1981 ◽  
Vol 46 (9) ◽  
pp. 2076-2082 ◽  
Author(s):  
Jan Uchytil ◽  
Eva Kočová ◽  
Miloš Kraus

Eleven C2 to C8 alkenes were hydrogenated on a reduced sulphided industrial nickel-tungsten catalyst. Kinetics of the reaction was investigated in detail for ethylene and data were correlated by different equations. Best fit was obtained by three equations of the Langmuir-Hinshelwood type and these were used to describe hydrogenation of the other alkenes. Logarithms of the rate constants obtained were correlated linearly with the sum of steric constants E0s of substituents of semihydrogenated state R1R2R3C-*. Also adsorption coefficients of alkenes were structure dependent, increased with molecular weight of alkene and correlated roughly with boiling points.


Author(s):  
A. V. Crewe

We have become accustomed to differentiating between the scanning microscope and the conventional transmission microscope according to the resolving power which the two instruments offer. The conventional microscope is capable of a point resolution of a few angstroms and line resolutions of periodic objects of about 1Å. On the other hand, the scanning microscope, in its normal form, is not ordinarily capable of a point resolution better than 100Å. Upon examining reasons for the 100Å limitation, it becomes clear that this is based more on tradition than reason, and in particular, it is a condition imposed upon the microscope by adherence to thermal sources of electrons.


Author(s):  
Maxim B. Demchenko ◽  

The sphere of the unknown, supernatural and miraculous is one of the most popular subjects for everyday discussions in Ayodhya – the last of the provinces of the Mughal Empire, which entered the British Raj in 1859, and in the distant past – the space of many legendary and mythological events. Mostly they concern encounters with inhabitants of the “other world” – spirits, ghosts, jinns as well as miraculous healings following magic rituals or meetings with the so-called saints of different religions (Hindu sadhus, Sufi dervishes),with incomprehensible and frightening natural phenomena. According to the author’s observations ideas of the unknown in Avadh are codified and structured in Avadh better than in other parts of India. Local people can clearly define if they witness a bhut or a jinn and whether the disease is caused by some witchcraft or other reasons. Perhaps that is due to the presence in the holy town of a persistent tradition of katha, the public presentation of plots from the Ramayana epic in both the narrative and poetic as well as performative forms. But are the events and phenomena in question a miracle for the Avadhvasis, residents of Ayodhya and its environs, or are they so commonplace that they do not surprise or fascinate? That exactly is the subject of the essay, written on the basis of materials collected by the author in Ayodhya during the period of 2010 – 2019. The author would like to express his appreciation to Mr. Alok Sharma (Faizabad) for his advice and cooperation.


HortScience ◽  
1998 ◽  
Vol 33 (3) ◽  
pp. 452c-452 ◽  
Author(s):  
Schuyler D. Seeley ◽  
Raymundo Rojas-Martinez ◽  
James Frisby

Mature peach trees in pots were treated with nighttime temperatures of –3, 6, 12, and 18 °C for 16 h and a daytime temperature of 20 °C for 8 h until the leaves abscised in the colder treatments. The trees were then chilled at 6 °C for 40 to 70 days. Trees were removed from chilling at 40, 50, 60, and 70 days and placed in a 20 °C greenhouse under increasing daylength, spring conditions. Anthesis was faster and shoot length increased with longer chilling treatments. Trees exposed to –3 °C pretreatment flowered and grew best with 40 days of chilling. However, they did not flower faster or grow better than the other treatments with longer chilling times. There was no difference in flowering or growth between the 6 and 12 °C pretreatments. The 18 °C pretreatment resulted in slower flowering and very little growth after 40 and 50 days of chilling, but growth was comparable to other treatments after 70 days of chilling.


2020 ◽  
Vol 27 (3) ◽  
pp. 178-186 ◽  
Author(s):  
Ganesan Pugalenthi ◽  
Varadharaju Nithya ◽  
Kuo-Chen Chou ◽  
Govindaraju Archunan

Background: N-Glycosylation is one of the most important post-translational mechanisms in eukaryotes. N-glycosylation predominantly occurs in N-X-[S/T] sequon where X is any amino acid other than proline. However, not all N-X-[S/T] sequons in proteins are glycosylated. Therefore, accurate prediction of N-glycosylation sites is essential to understand Nglycosylation mechanism. Objective: In this article, our motivation is to develop a computational method to predict Nglycosylation sites in eukaryotic protein sequences. Methods: In this article, we report a random forest method, Nglyc, to predict N-glycosylation site from protein sequence, using 315 sequence features. The method was trained using a dataset of 600 N-glycosylation sites and 600 non-glycosylation sites and tested on the dataset containing 295 Nglycosylation sites and 253 non-glycosylation sites. Nglyc prediction was compared with NetNGlyc, EnsembleGly and GPP methods. Further, the performance of Nglyc was evaluated using human and mouse N-glycosylation sites. Results: Nglyc method achieved an overall training accuracy of 0.8033 with all 315 features. Performance comparison with NetNGlyc, EnsembleGly and GPP methods shows that Nglyc performs better than the other methods with high sensitivity and specificity rate. Conclusion: Our method achieved an overall accuracy of 0.8248 with 0.8305 sensitivity and 0.8182 specificity. Comparison study shows that our method performs better than the other methods. Applicability and success of our method was further evaluated using human and mouse N-glycosylation sites. Nglyc method is freely available at https://github.com/bioinformaticsML/ Ngly.


2019 ◽  
Vol 15 (5) ◽  
pp. 472-485 ◽  
Author(s):  
Kuo-Chen Chou ◽  
Xiang Cheng ◽  
Xuan Xiao

<P>Background/Objective: Information of protein subcellular localization is crucially important for both basic research and drug development. With the explosive growth of protein sequences discovered in the post-genomic age, it is highly demanded to develop powerful bioinformatics tools for timely and effectively identifying their subcellular localization purely based on the sequence information alone. Recently, a predictor called “pLoc-mEuk” was developed for identifying the subcellular localization of eukaryotic proteins. Its performance is overwhelmingly better than that of the other predictors for the same purpose, particularly in dealing with multi-label systems where many proteins, called “multiplex proteins”, may simultaneously occur in two or more subcellular locations. Although it is indeed a very powerful predictor, more efforts are definitely needed to further improve it. This is because pLoc-mEuk was trained by an extremely skewed dataset where some subset was about 200 times the size of the other subsets. Accordingly, it cannot avoid the biased consequence caused by such an uneven training dataset. </P><P> Methods: To alleviate such bias, we have developed a new predictor called pLoc_bal-mEuk by quasi-balancing the training dataset. Cross-validation tests on exactly the same experimentconfirmed dataset have indicated that the proposed new predictor is remarkably superior to pLocmEuk, the existing state-of-the-art predictor in identifying the subcellular localization of eukaryotic proteins. It has not escaped our notice that the quasi-balancing treatment can also be used to deal with many other biological systems. </P><P> Results: To maximize the convenience for most experimental scientists, a user-friendly web-server for the new predictor has been established at http://www.jci-bioinfo.cn/pLoc_bal-mEuk/. </P><P> Conclusion: It is anticipated that the pLoc_bal-Euk predictor holds very high potential to become a useful high throughput tool in identifying the subcellular localization of eukaryotic proteins, particularly for finding multi-target drugs that is currently a very hot trend trend in drug development.</P>


1992 ◽  
Vol 57 (11) ◽  
pp. 2302-2308
Author(s):  
Karel Mocek ◽  
Erich Lippert ◽  
Emerich Erdös

The kinetics of the reaction of solid sodium carbonate with sulfur dioxide depends on the microstructure of the solid, which in turn is affected by the way and conditions of its preparation. The active form, analogous to that obtained by thermal decomposition of NaHCO3, emerges from the dehydration of Na2CO3 . 10 H2O in a vacuum or its weathering in air at room temperature. The two active forms are porous and have approximately the same specific surface area. Partial hydration of the active Na2CO3 in air at room temperature followed by thermal dehydration does not bring about a significant decrease in reactivity. On the other hand, if the preparation of anhydrous Na2CO3 involves, partly or completely, the liquid phase, the reactivity of the product is substantially lower.


Sign in / Sign up

Export Citation Format

Share Document