scholarly journals MATHEMATICAL MODELING SINGULARLY PERTURBED PROCESSES OF WATER SOFTENING ON SODIUM-CATIONITE FILTERS

2019 ◽  
Vol 9 (1) ◽  
pp. 37-40 ◽  
Author(s):  
Andrij Safonyk ◽  
Ihor Prysiazhniuk ◽  
Olena Prysiazhniuk ◽  
Oleksandr Naumchuk
Keyword(s):  
Ion Exchange ◽  
Asymptotic Approximation ◽  
Model Problem ◽  
Initial Boundary ◽  
Theoretical Description ◽  
Water Softening ◽  
Operational Conditions ◽  
Calcium And Magnesium ◽  
Pre Treatment ◽  
Modelling Assumptions

Mathematical model of the process of water softening using ion exchange pre-treatment of waters to desalination, with a view to removal of scale forming components, such as calcium and magnesium, are formed in the paper. In this process, no additional chemicals, except for brines formed during desalination, are required for regeneration of ion-exchanger in operation cycles. An asymptotic approximation of a solution of a corresponding model problem is constructed. Theoretical description and modelling assumptions included the set of differential equations of mass balance, initial, boundary and operational conditions. The paper deals with the development of a computer model for description and prediction of the performance of ion exchange columns.

FTIR ANALYSIS OF ION EXCHANGE RESINS WITH APPLICATION IN PERMANENT HARD WATER SOFTENING

2014 ◽  
Vol 13 (9) ◽  
pp. 2145-2152 ◽  
Author(s):  
Liliana Lazar ◽  
Laura Bulgariu ◽  
Bogdan Bandrabur ◽  
Ramona-Elena Tataru-Farmus ◽  
Mioara Drobota ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Hard Water ◽  
Ion Exchange Resins ◽  
Ftir Analysis ◽  
Water Softening ◽  
Exchange Resins

RESEARCH OF THE IMPACT DEVICE MODEL OF THE ROD TYPE BY DIFFERENCE METHOD

2020 ◽  
pp. 73-80
Author(s):  
А.М. Слиденко ◽  
В.М. Слиденко
Keyword(s):  
Boundary Value Problem ◽  
Difference Method ◽  
Model Problem ◽  
Boundary Value ◽  
Initial Boundary ◽  
Initial Boundary Value Problem ◽  
Cross Sectional ◽  
Impact Device ◽  
Initial Boundary Value ◽  
The Impact

Приводится анализ механических колебаний элементов ударного устройства с помощью модели стержневого типа. Ударник и инструмент связаны упругими и диссипативными элементами, которые имитируют их взаимодействие. Аналогично моделируется взаимодействие инструмента с рабочей средой. Сформулирована начально-краевая задача для системы двух волновых уравнений с учетом переменных поперечных сечений стержней. Площади поперечных сечений определяются параметрическими формулами при сохранении объемов стержней. Параметрические формулы позволяют получать различного вида зависимости площади поперечного сечения стержня от его длины. Начальные условия отражают физическую картину взаимодействия инструмента с ударником и рабочей средой. Краевые условия описывают контактные взаимодействия ударника с инструментом и последнего с рабочей средой. В качестве модельной задачи рассматривается соударение ударника и инструмента через элемент большой жесткости. Начально-краевая задача исследуется разностным методом. Проводится сравнение решений задачи, полученных с помощью двухслойной и трехслойной разностных схем. Такие схемы реализованы в общей компьютерной программе в системе Mathcad. Показано, что при вычислениях распределения нормальных напряжений по длине стержня лучшими свойствами относительно устойчивости обладает двухслойная схема The article gives the analysis of mechanical vibrations of the impact device elements using the model of the rod type. The hammer and the tool are connected by elastic and dissipative elements that simulate their interaction. The interaction of the tool with the processing medium is simulated in a similar way. An initial boundary-value problem is formulated for a system of two wave equations taking into account the variable cross sections of the rods. Cross-sectional areas are determined by parametric formulas maintaining the volume of the rods. Parametric formulas allow one to obtain various dependence types of the cross-sectional area of the rod on its length. The initial and boundary conditions reflect the physical phenomenon of the tool interaction with the processing medium, and also describe the contact interactions of the hammer with the tool. The impacting of the hammer and the tool through an element of high rigidity is considered as a model problem. To control the limiting values, the solution of the model problem by the Fourier method is used. The initial-boundary-value problem is investigated by the difference method. A comparison of solutions obtained for the two-layer and three-layer difference schemes is given. Such schemes are realized in a common computer program in the Mathcad. It is shown that the two-layer scheme has the best properties in relation to stability while calculating the distribution of normal voltage along the length of the rod

Improving the biological stability of drinking water by ion exchange

2011 ◽  
Vol 11 (1) ◽  
pp. 107-112 ◽  
Author(s):  
A. Grefte ◽  
M. Dignum ◽  
S. A. Baghoth ◽  
E. R. Cornelissen ◽  
L. C. Rietveld
Keyword(s):  
Drinking Water ◽  
Organic Carbon ◽  
Ion Exchange ◽  
Biofilm Formation ◽  
Formation Rate ◽  
Treatment Plant ◽  
Drinking Water Treatment ◽  
Biological Stability ◽  
Biological Activated Carbon ◽  
Pre Treatment

To guarantee a good water quality at the consumer’s tap, natural organic matter (NOM) should be (partly) removed during drinking water treatment. The objective of this research is to measure the effect of NOM removal by ion exchange on the biological stability of drinking water. Experiments were performed in two lanes of the pilot plant of Weesperkarspel in the Netherlands. The lanes consisted of ozonation, softening, biological activated carbon filtration and slow sand filtration. Ion exchange in fluidized form was used as pre-treatment in one lane and removed 50% of the dissolved organic carbon (DOC); the other lane was used as reference. Compared to the reference lane, the assimilable organic carbon (AOC) concentration of the finished water in the lane pretreated by ion exchange was 61% lower. The biofilm formation rate of the finished water was decreased with 70% to 2.0 pg ATP/cm2.day. The achieved concentration of AOC and the values of the biofilm formation rate with ion exchange pre-treatment showed that the biological stability of drinking water can be improved by extending a treatment plant with ion exchange, especially when ozonation is involved as disinfection and oxidation step.

Treatment of local scrubber wastewater for semiconductor by using photo-catalytic ozonation

2009 ◽  
Vol 59 (11) ◽  
pp. 2281-2286 ◽  
Author(s):  
Chung-Yi Chou ◽  
Chien-Pin Huang ◽  
Neng-Chou Shang ◽  
Yue-Hwa Yu
Keyword(s):  
Ion Exchange ◽  
Removal Efficiency ◽  
Removal Rate ◽  
Catalytic Ozonation ◽  
Acidic Condition ◽  
Buffer Solution ◽  
Toc Removal ◽  
Pre Treatment ◽  
Alkaline Buffer Solution

This study investigates the oxidation of local scrubber wastewater (LSW) from semiconductor manufacture by using ozonation, catalytic ozonation (ozone/Al2O3 and ozone/TiO2–Al2O3), and photo-catalytic ozonation (UV/TiO2–Al2O3, ozone/UV and ozone/UV/TiO2–Al2O3). The results show that catalyst Al2O3 and TiO2–Al2O3 promotes the TOC removal under the condition of neutral or alkaline buffer solution during catalytic ozonation of LSW. The Al2O3 induces highest promotion in TOC removal efficiency, which is higher than ozone alone by 26% TOC removal under alkaline buffer solution. However, TiO2–Al2O3 and Al2O3 cannot display the promotion in TOC removal under acidic condition. In addition, a pre-treatment of anion ion-exchange is employed and the result indicates that decreasing the anion ions concentration before AOPs can imply higher TOC removal during AOPs of LSW. In this study, ozone/UV under raw LSW acidic condition and ozone/Al2O3 under alkaline buffer solution present 95% and 88% TOC removal rate respectively and show the higher TOC removal efficiency than other AOPs. Therefore, these two kinds of AOP can serve as the very viable AOP methods in the LSW reclamation for semiconductor.

Effects of pre-treatment with magnetic ion exchange resins on coagulation/flocculation process

2008 ◽  
Vol 57 (1) ◽  
pp. 57-64 ◽  
Author(s):  
B. Sani ◽  
E. Basile ◽  
C. Lubello ◽  
L. Rossi
Keyword(s):  
Ion Exchange ◽  
Treatment Plant ◽  
Drinking Water Treatment ◽  
Water Treatment Plant ◽  
Ion Exchange Resin ◽  
Test Procedures ◽  
Aggregation State ◽  
Jar Test ◽  
Pre Treatment ◽  
Magnetic Ion

A new Magnetic Ion EXchange resin for DOC (Dissolved Organic Carbon) removal (MIEX®DOC Resin) has been evaluated as water pre-treatment at the Drinking Water Treatment Plant (DWTP) of Florence in order to reduce the oxidant demand and disinfection by-products (DBPs) formation potential. This pre-treatment leads to several effects on downstream treatment processes. In this experimental study the effects of MIEX® pre-treatment on clariflocculation process were evaluated with respect to coagulant demand reduction and characteristics of flocs formed. The analysis was conducted using traditional jar test procedures and a Photometric Dispersion Analyser (PDA2000) which provided continuous information about the aggregation state of particles during the jar tests. For a fixed turbidity goal in clarified water, ion exchange pre-treatment led to coagulant dosage reduction up to 60% and PDA results shown that flocs formed in pre-treated water were bigger and more resistant to shearing effects than those formed by conventional clariflocculation.

Degradation of recalcitrant organic contaminants by solar photocatalysis

2007 ◽  
Vol 55 (12) ◽  
pp. 119-125 ◽  
Author(s):  
L. Mansouri ◽  
L. Bousselmi ◽  
A. Ghrabi
Keyword(s):  
Organic Contaminants ◽  
Order Kinetic ◽  
Biological Degradation ◽  
Solar Photocatalysis ◽  
Photocatalytic Reactor ◽  
Operational Conditions ◽  
Toc Removal ◽  
The Matrix ◽  
Pre Treatment ◽  
Refractory Organic Pollutants

Biological pre-treated landfill leachates of Djebel Chakir contains some macromolecular organic substances that are resistant to biological degradation. The aim of the present work is to assess the feasibility of removing refractory organic pollutants in biological pre-treated landfill leachate by solar photocatalyse process. Leachate pollutant contents are studied to assess their contribution to leachate pollution and their treatability by solar photocatalyse process. Phenol is chosen as model of pollutants, to evaluate its removal and the efficiency of the photocatalytic system. The experiments were carried out in suspended photocatalytic reactor, using TiO2 Degussa P25, under sunlight illumination (UV-A: 15–31 W/cm2). Under optimum operational conditions, applied to single reactant (phenol), the system presents a TOC removal of 90% (the degradation follows a first-order kinetic). Based on the TOC removal, the results shows that the degradation of biological pre-treated leachate follows a zero-order kinetic. After 5 h of sunlight exposure, 74% of COT is removed. The TOC removal is the best without any correction of the pH and at the TiO2 concentration of 2.5 g/L. The photocatalytic degradation of organic contaminants as well as the formation and disappearance of the by-products were followed by GC/MS. The solar photocatalysis processes induce several modifications of the matrix leading to more biodegradable forms: all the remaining and new compounds generated after the biological pre-treatment of leachate are degraded and other types of organics appear, mainly carboxylic acid, aliphatic hydrocarbons and phtalic acids.

Ion-exchange separation and determination of calcium and magnesium

1977 ◽  
Vol 49 (11) ◽  
pp. 1595-1598 ◽  
Author(s):  
Michael D. Arguello ◽  
James S. Fritz
Keyword(s):  
Ion Exchange ◽  
Ion Exchange Separation ◽  
Calcium And Magnesium

Impact of a severe rain event on C- and N-DBP precursor removal using IEX

2018 ◽  
Vol 18 (6) ◽  
pp. 2092-2099
Author(s):  
K. Doederer ◽  
Z. Ilieva ◽  
J. Keller
Keyword(s):  
Ion Exchange ◽  
Heavy Rain ◽  
Health Concern ◽  
Rain Event ◽  
Heavy Rain Event ◽  
Removal Capacity ◽  
C And N ◽  
Pre Treatment ◽  
Rain Events ◽  
Magnetic Ion

Abstract During disinfection, dissolved organic matter (DOM) is the major precursor to form disinfection by-products (DBPs), which may be of potential human health concern. Previous research focused on waters of continental climates and less on subtropical environments. However, water sources in subtropical climates are regularly impacted by major rain events during the summer months. This study evaluated the C- and N-DBP precursor removal capacity of two conventional ion exchange (IEX) resins and one magnetic ion exchange (MIEX) resin with a raw water at normal conditions and impacted by a heavy rain event. The rain event introduced 3 mg C/L total organic carbon (TOC) comprised mainly of low to medium molecular weight organics. All three resins were able to remove TOC and DBP precursors (>66%) but being less efficient in reducing turbidity (3–48%) and colour (9–24%). The resin with the smallest bead size was affected the most by the increased medium MW DOM loading resulting in DOM and C-DBP precursor removal performance losses of 10% and 22%. When applied as a pre-treatment for coagulation, MIEX was more efficient in DBP precursor control than coagulation in addressing the additional organic and DBP precursor loading after a heavy rain event.

scholarly journals Exploiting the ion-exchange ability of titanate nanotubes in a model water softening process

2014 ◽  
Vol 591 ◽  
pp. 161-165 ◽  
Author(s):  
Dániel Madarász ◽  
Imre Szenti ◽  
András Sápi ◽  
János Halász ◽  
Ákos Kukovecz ◽  
...  
Keyword(s):  
Ion Exchange ◽  
Titanate Nanotubes ◽  
Water Softening ◽  
Softening Process ◽  
Model Water
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