scholarly journals Mechanical and Microstructural Properties of Copper Slag Based Blended Geopolymer Concrete

2021 ◽  
Author(s):  
Vijayasarathy RATHANASALAM ◽  
Jayabalan PERUMALSAMI ◽  
Karthikeyan JAYAKUMAR

This work presents a novel way to examine the characteristics of fly ash, copper slag (CPS) along with the addition of Ultrafine Ground Granulated Blast Furnace Slag (UFGGBFS) based Geopolymer Concrete (GPC) for various molarities (10M, 12M and 14M). In GPC, fly ash was replaced with UFGGBFS (5 %, 10 % and 15 %) and copper slag was used as fine aggregate. Mechanical Characterization such as split tensile, flexural strength, workability and water absorption were conducted . GPC characterization and microstructural behaviour was studied  by examining X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). From experimental results this study concludes that with a rise in molarity of GPC, along with incorporation of UFGGBFS, improved the performance, densification and strength of GPC.

2020 ◽  
Vol 44 (6) ◽  
pp. 433-439
Author(s):  
Vijayasarathy Rathanasalam ◽  
Jayabalan Perumalsami ◽  
Karthikeyan Jayakumar

This paper presents the properties of blended geopolymer concrete manufactured using fly ash and ultrafine Ground Granulated Blast Furnace Slag (UFGGBFS), along with the copper slag (CPS) as replacement of fine aggregate (crushed stone sand). Various parameters considered in this study include different sodium hydroxide concentrations (10M, 12M and 14M); 0.35 as alkaline liquid to binder ratio; 2.5 as sodium silicate to sodium hydroxide ratio and cured in ambient curing condition. Further, geopolymer concrete was manufactured using fly ash as the prime source material which is replaced with UFGGBFS (0%, 5%, 10% and 15%). Copper slag has been used as replacement of fine aggregate in this study. Properties of the fresh manufactured geopolymer concrete were studied by slump test. Compressive strength of the manufactured geopolymer concrete was tested and recorded after curing for 3, 7 and 28 days. Microstructure Characterization of Geopolymer concrete specimens was done by Scanning Electron Microscope (SEM) analysis. Experimental results revealed that the addition of UFGGBFS resulted in an increased strength performance of geopolymer concrete. Also, this study demonstrated that the strength of geopolymer concrete increased with an increase in sodium hydroxide concentration. SEM results revealed that the addition of UFGGBFS resulted in a dense structure.


2020 ◽  
Vol 8 (5) ◽  
pp. 4691-4696

This paper comprises of the experimental study of double skinned (DSCFT) Composite hollow columns using Geopolymer concrete. The diameter-thickness (D/t) ratio and the hollowness ratio were consideredas main parameters in designing the specimens. The Geopolymer Concrete used in this project is the most promising technique. It is composed of fly-ash, fine aggregate, coarse aggregate and alkaline solution. By using large volume of ordinary Portland cement (OPC) concrete, the production of cement increases 3% annually. The production of one ton of cement directly liberates about 1 ton of CO2 and indirectly liberates 0.4 ton of CO2 to atmosphere. Among the greenhouse gases, CO2 contributes about 67% of global warming. In this respect fly ash based geopolymer mortar is highly considerable. But most of the previous works on fly ash-based geopolymers concrete reveals that hardening is due to heat curing, which is considered as a limitation for cast in situ applications at low ambient temperatures. In order to overcome this situation, replacing the Ground blast furnace slag with fly ash for various proportions to achieve geopolymer concrete suitable for curing without elevated heat. The Scope of this project is to find optimization level of Ground Granulated blast furnace slag in geopolymer concrete for curing in ambient condition and to analyze the compressive Strength of optimized GGBS based Geopolymer Concrete filled double skinned steel tube by varying the size of the steel tubes.


2014 ◽  
Vol 633 ◽  
pp. 240-244 ◽  
Author(s):  
Su Ping Cui ◽  
Ling Ling Liu ◽  
Jing Chen ◽  
Ya Li Wang ◽  
Jian Feng Wang ◽  
...  

Granulated blast furnace slag (GBFS) is a by-product of manufacturing iron. Samples of GBFS with different ratio of SiO2/Al2O3 were prepared by simulating the actual process of GBFS in laboratory. This study investigated the influence of SiO2/Al2O3 content on structure and hydration activity of GBFS which were characterized by X-ray fluorescence (XRF), powder X-ray diffraction (XRD), infrared radiation (IR) and mechanical testing. It is found that the vitreous content of each sample is above 97% and the hydration activity indexes of 7d and 28d of samples significantly decrease with the increase of SiO2/Al2O3 ratio. The IR characteristic absorption spectrum shows that the silicates mainly exist in [SiO4]-tetrahedra and the aluminum atoms are in different coordination states and the bonding strengths rise with the increase of SiO2/Al2O3 ratio.


2010 ◽  
Vol 150-151 ◽  
pp. 885-889 ◽  
Author(s):  
Xiao Ming Liu ◽  
Yu Li ◽  
Ling Ling Zhang ◽  
Da Qing Cang

The disposal of circulating fluidized bed (CFB) fly ash has been a serious environmental problem in the development of our society. In this work, the feasibility of recycling CFB fly ash as a blended material incorporating blast furnace slag (BFS), clinker and gypsum for the preparation of Eco-cement has been investigated. The mechanical properties of CFB fly ash based Eco-cements, including CFB fly ash–clinker system, CFB fly ash–ground BFS system, and CFB fly ash–ground BFS–clinker system, were evaluated in this paper. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques were used to analyze the microstructural changes and the hydration products of the CFB fly ash based Eco-cement pastes. The results indicated that it is feasible to use CFB fly ash along with BFS and clinker to produce Eco-cement. The hydration products of CFB fly ash based Eco-cement are mostly ettringite and amorphous C-S-H gel, which are principally responsible for the strength and structure development of CFB fly ash based Eco-cement in the hydration process.


2020 ◽  
Vol 2 (3) ◽  
pp. 128-133
Author(s):  
Addepalli Mallinadh Kashyap ◽  
Tanimki Chandra Sekhar Rao ◽  
N.V.Ramana Rao

The utilisation of pozzolanic materials as the replacement to conventional cement material have the potentiality to mitigate the pollution caused by the émission of carbon based green house gases which are a main source for global warming problem. For every production of 1 ton of cement it was approximated that the emission of carbon based green house gases are about 1 ton. Keeping this in view, a new material called Geopolymer which was first coined by Davidovits has gained a lot of interest by the researchers. In this study, different molarity variations of NaOH in the order of 4M, 6M, 8M, 10M, 12M and 14M and also the blending of  mineral admixtures like Fly Ash and Ground Granulated Blast Furnace Slag with percentages (50%+50%) and the mechanical properties of normal M30 and high strength grade M70 binary blended Geopolymer concrete were studied after 28 days of ambient curing and were reported. The test results revealed that the effect of molar concentration of NaOH at 12 M is effective and the optimum replacement of mineral composition of source materials is (50%+50%) fly ash and ground granulated blast furnace slag.  


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