Mechanical and Water Absorption Properties of Alkaline Treated Coconut (cocosnucifera) and Sponge (acanthus montanus) Fibers Reinforced Polypropylene Composites

Author(s):  
Okikiola Ganiu Agbabiaka ◽  
Isiaka Oluwole Oladele ◽  
Oluyemi Ojo Daramola
2019 ◽  
Vol 20 (2) ◽  
pp. 188-196
Author(s):  
Noorasikin Samat ◽  
Nurul Hakimah Mohd Lazim ◽  
Zahurin Halim

The unconventional electron beam (EB) irradiation route in preparing microcrystalline cellulose (MCC) fiber reinforced recycled polypropylene (rPP) composites was studied. In this route, the rPP was first subjected to EB irradiation at various doses (10-50kGy) and was then used as a compatibilizer. Unirradiated and irradiated rPPs were blended at two different ratios (90:10; 50:50) and added with MCC at contents of 5, 20 and 40wt%. Dynamic mechanical analysis (DMA) and water absorption tests were carried out. The DMA spectra exhibited high stiffness and damping behaviour. As the content of MCC increased, the water resistance of composites dropped slightly as compared to the controlled rPP. However, some compositions (50:50/40MCC-10kGy and 50:50/5MCC-50kGy) had shown opposite results. The improvement in the studied properties proved the existence of the compatibility effect that occurred at low irradiation doses, and also depended on the ratio (unirradiated and irradiated rPP) and MCC contents. ABSTRAK: Kaedah sinaran gelombang elektron secara bukan konvensional dalam penyediaan komposit polipropilena kitar semula (rPP) bersama serat selulosa mikrohablur (MCC) telah dikaji. Dalam kaedah ini, rPP telah didedahkan kepada sinaran gelombang elektron dengan dos yang berbeza (10-50kGy) dan kemudiannya digunakan sebagai penserasi.  rPP tidak tersinar dan tersinar telah dicampur dengan nisbah  (90:10; 50:50) dan ditambah dengan MCC pada kandungan 5, 20 and 40wt%. Analisis dinamik mekanikal (DMA) dan ujian penyerapan air telah dijalankan. Spektrum DMA menunjukkan sifat kekakuan dan pengenduran yang tinggi. Apabila kandungan MCC bertambah, kerintangan komposit terhadap air berkurang sedikit berbanding rPP terkawal. Bagaimanapun sebahagian komposisi (50:50/40MCC-10kGy and 50:50/5MCC-50kGy) telah menunjukkan keputusan sebaliknya. Penambahbaikan sifat bahan dalam kajian ini membuktikan kewujudan kesan keserasian yang berlaku pada dos sinaran rendah, dan juga bergantung kepada nisbah (rPP tidak tersinar dan tersinar) dan kandungan MCC.                


2021 ◽  
Vol 36 (2) ◽  
pp. 205-212
Author(s):  
I. O. Oladele ◽  
A. D. Akinwekomi ◽  
I. O. Ibrahim ◽  
M. H. Adegun ◽  
S. I. Talabi

Abstract To harness the inherent advantages of both synthetic and natural reinforcements, mercerized bagasse fibers (BF) and particulate calcium carbonate (CaCO3) were utilized as a complementing reinforcement for the fabrication of bagasse fiber/calcium carbonate (BF/CaCO3) polypropylene composites. Two sets of composites were produced – one with mercerized BF/CaCO3 and the other with unmercerized BF/ CaCO3. The effect of reinforcement loading on the impact energy, wear behavior, thermal resistance and water absorption properties of the composites were studied. Results showed that the mercerized BF/CaCO3 hybrid reinforced polypropylene composites exhibited significant increase in impact energy and offered better resistance to weight loss during wear test. Similarly, the thermal resistance of the mercerized composites was higher than their corresponding unmercerized composites. Additionally, water absorption in mercerized composites was highly resisted than in unmercerized samples. These results indicated that mercerization treatment and reinforcement hybridization improved the impact energy, wear, thermal resistance and water ingress resistance of hybrid fiber/ particulate reinforced polypropylene composites.


Author(s):  
I.O. Oladele ◽  
J.O. Ajileye ◽  
S.R. Oke ◽  
O.O. Daramola ◽  
O.A. Adewumi

Gels ◽  
2021 ◽  
Vol 7 (1) ◽  
pp. 5
Author(s):  
Samuel Mandin ◽  
Samuel Moreau ◽  
Malika Talantikite ◽  
Bruno Novalès ◽  
Jean-Eudes Maigret ◽  
...  

Bio-based aerogels containing cellulose nanofibrils (CNFs) are promising materials due to the inherent physical properties of CNF. The high affinity of cellulose to plant hemicelluloses (xyloglucan, xylan, pectin) is also an opportunity to develop biomaterials with new properties. Here, we prepared aerogels from gelled dispersions of CNFs and xyloglucan (XG) at different ratios by using a freeze-casting procedure in unidirectional (UD) and non-directional (ND) manners. As showed by rheology analysis, CNF and CNF/XG dispersions behave as true gels. We investigated the impact of the freezing procedure and the gel’s composition on the microstructure and the water absorption properties. The introduction of XG greatly affects the microstructure of the aerogel from lamellar to cellular morphology. Bio-based aerogels showed high water absorption capacity with shape recovery after compression. The relation between morphology and aerogel compositions is discussed.


2012 ◽  
Vol 127 (2) ◽  
pp. 1295-1300 ◽  
Author(s):  
Catherine Esnaashari ◽  
Saied Nouri Khorasani ◽  
Mehdi Entezam ◽  
Shahla Khalili

2018 ◽  
Vol 33 (3) ◽  
pp. 289-304 ◽  
Author(s):  
Kuhananthan Nanthakumar ◽  
Chan Ming Yeng ◽  
Koay Seong Chun

This research covers the preparation of poly(lactic acid) (PLA)/sugarcane leaves fibre (SLF) biofilms via a solvent-casting method. The results showed that the tensile strength and Young’s modulus of PLA/SLF biofilms increased with the increasing of SLF content. Nevertheless, the elongation at break showed an opposite trend as compared to tensile strength and Young’s modulus of biofilms. Moreover, water absorption properties of PLA/SLF biofilms increased with the increasing of SLF content. In contrast, the tensile strength and Young’s modulus of biofilms were enhanced after bleaching treatment with hydrogen peroxide on SLF, but the elongation at break and water absorption properties of bleached biofilms were reduced due to the improvement of filler–matrix adhesion in biofilms. The tensile and water properties were further discussed using B-factor and Fick’s law, respectively. Furthermore, the functional groups of unbleached and bleached SLF were characterized by Fourier transform infrared analysis.


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