The Toxicity of Crude Oil and its Components to Freshwater Algae

1973 ◽  
Vol 1973 (1) ◽  
pp. 703-714 ◽  
Author(s):  
P. Kauss ◽  
T. C. Hutchinson ◽  
C. Soto ◽  
J. Hellebust ◽  
M. Griffiths

ABSTRACT Field and laboratory experiments have been conducted to determine the toxicity of crude oil to freshwater algae. In the field, experiments were continued for a two year period and changes in the abundance and species composition of phytoplankton tabulated. Species were found to differ markedly in their response to an oil spill—varying from considerable suppression of growth to stimulation. In the laboratory, the effects of aqueous extracts of seven crude oils on a selected test species, Chlorella vulgaris, were determined. Marked differences in toxicity, as indicated by reduced growth, were found to exist between oils. Work with oil extracts of different ages suggests that the short-term toxicity of oils is due to the rapid loss of volatile compounds. Differences in the toxicity of selected aromatic components of crude oils—benzene, toluene, o-xylene and naphthalene—were observed and are believed to relate to an increase in methylation. Aqueous crude oil and naphthalene depressed the 14C-NaHC03 uptake (i.e. photosynthesis) of Chlamydomonas angulosa. 14C-naphthalene was rapidly taken up by Chlamydomonas cells. However, release of this compound was much slower, and, in unwashed cells, seemingly dependent upon cell division. Possible mechanisms of crude oil toxicity are discussed.

2001 ◽  
Vol 2001 (2) ◽  
pp. 1237-1241 ◽  
Author(s):  
Dana L. Wetzel ◽  
Edward S. Van Fleet

ABSTRACT The present study was conducted to assess the toxicity of the water-accommodated fraction (WAF) and the chemically enhanced WAF (CE-WAF) of selected crude oils for both weathered and fresh oil. Test organisms included two standard test species, Mysidopsis bahia and Menidia beryllina, and a commercially important Florida marine fish, Sciaenops ocellatus. Tests ascertaining LC50 values were conducted under continuous exposure and spiked (declining exposure using flow-through toxicity chambers) conditions using Venezuelan Crude Oil (VCO), Prudhoe Bay Crude Oil (PBCO), and COREXIT® 9500 dispersant on the above species. Data suggest that the dispersant is less toxic than the WAF and CE-WAF of the tested crude oils. The toxicity of the CE-WAF of fresh VCO is similar to that of other oils under continuous exposure conditions, but may be slightly more toxic to some species under spiked exposure conditions. The CE-WAF of fresh VCO appears to be less toxic than the corresponding WAF for M. bahia, M. beryllina, and S. ocellatus. Fresh VCO appears to be much more toxic to M. bahia and M. beryllina than weathered VCO in spiked exposure tests for both the WAF and CE-WAF. The WAF of PBCO is apparently less toxic to the test organisms than the corresponding WAF of fresh VCO. The LC50 values of M. bahia with CE-WAF fractions of both fresh VCO and PBCO are similar, while the same PBCO CE-WAF fraction is less toxic for M. beryllina than fresh VCO CE-WAF. The toxicity of oils and dispersants were lowest in the spiked exposure weathered oil tests, which may be most representative of an oil spill under natural environmental conditions.


1997 ◽  
Vol 506 ◽  
Author(s):  
W. Russell Alexander ◽  
Andreas Gautschi ◽  
Piet Zuidema

ABSTRACTRepositories have to isolate radioactive waste (radwaste) and some toxic wastes from the environment for hundreds to hundreds of thousands of years. For many scientists and engineers, and especially the general public, such time spans are beyond comprehension and, consequently, they have grave doubts as to the safety of any such waste repositories. That repository performance over these long time scales can only be assessed by the use of complex mathematical models (normally called performance assessment, or PA, models) only adds to the mistrust of many. How then can people be convinced that it is possible to assess the performance (and thus ensure the safety) of a repository over the long timescales of interest? One way is to address the robustness of the PA models, by clearly indicating the form and extent of model testing carried out within the repository PA. Not only can this show that the individual component parts of the complex structure which constitutes most PA models have been checked, but also that the ‘mathematical black boxes’ constitute an acceptabe representation of the repository system.Part of the problem undoubtedly lies in the unusual nature of radwaste disposal: in most major engineering projects, such as bridge construction or aerospace engineering, the designs are tested against a range of laboratory experiments backed up by expert judgement based on experience with the same or similar systems. Here repository design deviates from standard engineering practice in that no high-level waste (and only a few low- and intermediate-level waste) repositories yet exist and, even when they do, testing their compliance to design limits will be somewhat difficult due to the time scales involved. In addition, the irrational fear of most things radioactive means that most people require some greater form of ‘proof’ that a repository is safe than they are willing to accept for other engineered systems. This being the case, significant additional effort must be expended within the radwaste industry to make it completely clear that the PA models can adequately predict the long-term behaviour of a repository.Traditionally, PA modellers have placed much weight on laboratory data for the construction and testing of PA models and, with only a few exceptions, have not integrated in their PA reports data from natural analogues and in situ experiments. The over-dependence on laboratory data is understandable in that the information is produced under well understood, fully controlled conditions and thus the modellers feel they can place a high degree of confidence in the results obtained. Unfortunately, the full complexity of a repository cannot be re-created in a laboratory and it is necessary to address processes which are influenced by natural heterogeneities, which include large degrees of uncertainty and which operate over very long timescales. In this case, it is necessary to supplement laboratory data with information from in situ field experiments and natural analogues.The advantage of natural analogues over short-term laboratory experiments is that they enable study of repository-like systems which have evolved over the geological timescales of relevance to a radwaste repository safety assessment (rather than the days to months usual in laboratory tests). However, by their very nature, natural analogues often have ill-defined boundary conditions which may be better assessed under the well constrained (if less relevant) conditions of a laboratory. Well designed, realistic in situ field experiments can bridge the gap between the laboratory and natural analogues by offering repository relevant natural conditions with some of the constraints of the laboratory (and intermediate timescales). In short, combining information from the three sources (long-term and realistic, if poorly defined, natural analogues, medium-term, better constrained, in situ field experiments and short-term, less realistic but well defined laboratory studies) can provide greater confidence in the extrapolation of laboratory derived data to repository relevant timescales and conditions.This paper will concentrate on presenting a model testing scheme which both promotes transparency (for the sake of technical peer reviewers and the general public alike) and which aims at a thorough test of PA models. In addition, several recently published PAs will be critically examined and the form, extent and transparency of testing will be discussed with a view to improving confidence in the robustness of the models and thus the perceived safety of specific radwaste repository designs.


2020 ◽  
Vol 20 (4) ◽  
pp. 332-344
Author(s):  
Douaa Hussein Ali ◽  
Muhannad A.R. Mohammed

  This research study the properties of two different crude oils . Two samples of crude oil were used, which were ( Al – Dora and Al - Ahdab )crude oil. Atmospheric distillation used to separate these two crude oils into their fractions according to boiling point. This research introduced most important characteristics and information's about these samples of crude oils and their products. ASTM distillation was converted to TPB distillation curve. It was found that the preliminary boiling point is lower than the cease point is higher than ASTM distillation for the two crude oils. Most important properties of the products of the two crude oils were calculated. These properties are API, gravity, Watson characterization factor (k), viscosity, molecular weight and refractive index. It was found that the API gravity for Al-Dora crude oil cuts is less than that of the Al-Ahdab crude oil cuts. Also , Al-Dora and Al-Ahdab crude oils cuts having more naphthenic or aromatic components since the characterization factor is less than 12.5. it was concluded that the characterization factor (K) for Al-Ahdab crude oil is less than Al-Dora crude oil for gasoline only. While the opposite happens with Kerosene and gas oil. Finally , It was conclude that the viscosity, molecular weight and refractive index of Al-Dora crude oil products were higher than that of the products of Al-Ahdab crude oil. It was found also that the viscosity of cuts for Al-Dora and Al- Ahdab crude is increase because kerosene is more viscous (heavy cut) than gasoline. Also gas oil is more viscous than gasoline and kerosene. Finally , it was concluded that the viscosity of gasoline, kerosene and gas oil for Al-Dora crude is higher than gasoline, kerosene and gas oil for Al-Ahdab crude oil. It was concluded that the molecular weights of gasoline, kerosene for Al-Dora crude is higher than gasoline, kerosene for Al-Ahdab crude oil but the gas oil is on the contrary. It was concluded that the refractive index for Al-Dora crude is higher than Al-Ahdab crude oil  


1972 ◽  
Vol 7 (1) ◽  
pp. 52-58 ◽  
Author(s):  
T.C. Hutchinson ◽  
P. Kauss ◽  
Marta Griffiths

Abstract Field and laboratory experiments have been carried out to determine the toxicity to planktonic algae of crude oil, crude oil - water extracts and also selected oil components. Field experiments were performed in a half-acre pond. Localised spills of crude oil were confined within specially constructed floating cylinders with an attached collar. Three different effects of crude oil spills were noted - 1) certain species were inhibited in their growth 2) other species did not appear to be effected and 3) a number of species showed apparent stimulation following the spill. These results emphasize the great differences in response between species and suggest the actual planktonic composition of a water body of considerable importance in predicting the effects of an oil spill. In laboratory studies the toxicity of the water soluble components of crude oil only were tested. These extracts had a significant effect in increasing acidity of the water, which by itself, reduced algal growth. However, it was found that toxic factors were present, in addition to pH effects. There toxic factors or components appeared to be volatile. Tests with benzene, toluene and xylene - three water soluble crude oil components - showes them all to be toxic, with toxicity increasing in the order indicated.


2019 ◽  
Vol 118 (3) ◽  
pp. 110-122
Author(s):  
Johnson Clement Madathil ◽  
Velmurugan P. S

Crude oil is known to have an impact on people’s life of both producers and consumers of crude oil countries. A producer country’s socio-political impact will be different from a consumer country’s socio-political impact. This paper aims to show that crude oil price has a socio-political impact on global countries through descriptive analysis. The study found that there were similarities in the movement of crude oil price and change in GDP of both India and United States and further Russia and Venezuela have had crude oil impact on their respective GDP’s, which has made them take policy reforms. The paper identifies changes in the policy framework due to influence of crude oil price and eventual changes in existing socio-political environment. Taking oil producing countries such as Russia and Venezuela as examples, this paper suggests that policy reforms are the key to having a stable socio-political environment. Russia shows us that having a flexible monetary policy can keep the budget dependence on crude oil reduced in the short term. On the other hand, for oil consuming countries, having a stable supply and moving to new energy sources is the key to tackle the influence of crude oil price on the socio-political environment of global countries.


2018 ◽  
Vol 5 (1) ◽  
pp. 43-54
Author(s):  
Suresh Aluvihara ◽  
Jagath K Premachandra

Corrosion is a severe matter regarding the most of metal using industries such as the crude oil refining. The formation of the oxides, sulfides or hydroxides on the surface of metal due to the chemical reaction between metals and surrounding is the corrosion that  highly depended on the corrosive properties of crude oil as well as the chemical composition of ferrous metals since it was expected to investigate the effect of Murban and Das blend crude oils on the rate of corrosion of seven different ferrous metals which are used in the crude oil refining industry and investigate the change in hardness of metals. The sulfur content, acidity and salt content of each crude oil were determined. A series of similar pieces of seven different types of ferrous metals were immersed in each crude oil separately and their rates of corrosion were determined by using their relative weight loss after 15, 30 and 45 days. The corroded metal surfaces were observed under the microscope. The hardness of each metal piece was tested before the immersion in crude oil and after the corrosion with the aid of Vicker’s hardness tester. The metallic concentrations of each crude oil sample were tested using atomic absorption spectroscopy (AAS). The Das blend crude oil contained higher sulfur content and acidity than Murban crude oil. Carbon steel metal pieces showed the highest corrosion rates whereas the stainless steel metal pieces showed the least corrosion rates in both crude oils since that found significant Fe and Cu concentrations from some of crude oil samples. The mild steel and the Monel showed relatively intermediate corrosion rates compared to the other types of ferrous metal pieces in both crude oils. There was a slight decrease in the initial hardness of all the ferrous metal pieces due to corrosion.


1986 ◽  
Vol 18 (2) ◽  
pp. 151-156 ◽  
Author(s):  
R. Zapf-Gilje ◽  
S. O. Russell ◽  
D. S. Mavinic

When snow is made from sewage effluent, the impurities become concentrated in the early melt leaving the later runoff relatively pure. This could provide a low cost method of separating nutrients from secondary sewage effluent. Laboratory experiments showed that the degree of concentration was largely independent of the number of melt freeze cycles or initial concentration of impurity in the snow. The first 20% of melt removed with it 65% of the phosphorus and 90% of the nitrogen from snow made from sewage effluent; and over 90% of potassium chloride from snow made from potassium chloride solution. Field experiments with a salt solution confirmed the laboratory results.


Resources ◽  
2021 ◽  
Vol 10 (8) ◽  
pp. 75
Author(s):  
Ivelina K. Shishkova ◽  
Dicho S. Stratiev ◽  
Mariana P. Tavlieva ◽  
Rosen K. Dinkov ◽  
Dobromir Yordanov ◽  
...  

Thirty crude oils, belonging to light, medium, heavy, and extra heavy, light sulfur, and high sulfur have been characterized and compatibility indices defined. Nine crude oil compatibility indices have been employed to evaluate the compatibility of crude blends from the thirty individual crude oils. Intercriteria analysis revealed the relations between the different compatibility indices, and the different petroleum properties. Tetra-plot was employed to model crude blend compatibility. The ratio of solubility blending number to insolubility number was found to best describe the desalting efficiency, and therefore could be considered as the compatible index that best models the crude oil blend compatibility. Density of crude oil and the n-heptane dilution test seem to be sufficient to model, and predict the compatibility of crude blends.


Chemosphere ◽  
2021 ◽  
pp. 131563
Author(s):  
Laurens van Gelderen ◽  
Kristoffer Gulmark Poulsen ◽  
Jan H. Christensen ◽  
Grunde Jomaas

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