A 300,000 year record of cold-water coral mound build-up at the East Melilla Coral Province (SE Alboran Sea, western Mediterranean)

This study provides a detailed reconstruction of cold-water coral mound build-up within the East Melilla Coral Province (Southeast Alboran Sea) over the last 300 ky. Based on benthic foraminiferal assemblages, macrofaunal quantification, grain size analysis, sediment geochemistry, and foraminiferal stable isotope compositions, a reconstruction of environmental conditions having prevailed in the region is proposed. The variations in planktonic and benthic δ18O values indicate that cold-water coral mound build-up follows and records global climate variability. In contrast to northeast Atlantic counterparts, coral mound build-up in the southeast Alboran Sea occurs during glacial as well as during interglacial periods and at very low aggradation rates (between 1 and 10 cm.ky−1). Environmental conditions during glacial periods, particularly during the Last Glacial Maximum, appear to better suit the ecological requirements of the erect cheilostome bryozoan Buskea dichotoma. We propose that Buskea dichotoma has an important role in the build-up of cold-water coral mounds at the East Melilla Coral Province during glacial periods. Benthic foraminiferal assemblages suggest that important terrestrial input favoured cold-water coral proliferation during interglacial periods. The existence of strong Alboran Gyres during interglacial periods, promoting mixing between surface and intermediate water masses and bottom water turbulence, was possibly beneficial for cold-water coral development. Conversely, benthic foraminiferal assemblages indicate that the seafloor received less organic matter during glacial periods. Overall, the arid continental conditions combined to more stratified water masses resulted in limited coral proliferation during glacial times.

Geochemical Markers as a Tool for the Characterization of a Multi-Layer Urban Aquifer: The Case Study of Como (Northern Italy)

The analysis of geochemical markers is a known valid tool to explore the water sources and understand the main factors affecting natural water quality, which are known issues of interest in environmental science. This study reports the application of geochemical markers to characterize and understand the recharge areas of the multi-layer urban aquifer of Como city (northern Italy). This area presents a perfect case study to test geochemical markers: The hydrogeological setting is affected by a layered karst and fractured aquifer in bedrock, a phreatic aquifer hosted in Holocene sediments and connected with a large freshwater body (Lake Como); the aquifers recharge areas and the water geochemistry are unknown; the possible effect of the tectonic setting on water flow was overlooked. In total, 37 water samples were collected including water from two stacked aquifers and surface water to characterize hydrochemical features. Moreover, six sediment samples in the recent palustrine deposits of the Como subsurface were collected from cores and analyzed to understand the main geochemistry and mineralogy of the hosting material. The chemical analyses of water allow to observe a remarkable difference between the shallow and deep aquifers of the study area, highlighting different recharge areas, as well as a different permanence time in the aquifers. The sediment geochemistry, moreover, confirms the differences in trace elements derived from sediment-water interaction in the aquifers. Finally, an anomalous concentration of As in the Como deep aquifer was observed, suggesting the need of more detailed analyses to understand the origin of this element in water. This study confirms the potentials of geochemical markers to characterize main factors affecting natural water quality, as well as a tool for the reconstruction of recharge areas.

BACKGROUND OF U AND Th IN SEDIMENTS OF BEDROCK RIVERS

The Miño River is a good example of bedrock rivers, where sediment geochemistry is scarcely studied. Its urban reach when passing through the city of Ourense gathers some characteristics that provide interest to its sediments, like scarcity of fine sediments accumulation and the impact of several human activities. Sediments trapped by potholes and other rock cavities were considered. In order to evaluate society-nature interactions through sediment composition it is critical to determine the compositional background (in absence of human alterations), particularly when working with trace elements. This work presents an exploratory assay to determine background in sediments from bedrock rivers by using two uncommon elements, uranium (U) and thorium (Th). To determine their background different statistical techniques were applied in order to set the background composition value and calculate possible enrichments. Background was calculated by simple least squares lineal regression by using Al as independent variable (reference element) resulting in 8.7 mgU kg-1 and 5.6 mgTh kg-1. Enrichments were found in some particular samples and can be attributed to intrinsic microenvironment complexities inside rock cavities.

Hydrodynamic disturbance controls microbial community assembly and biogeochemical processes in coastal sediments

The microbial community composition and biogeochemical dynamics of coastal permeable (sand) sediments differs from cohesive (mud) sediments. Tide- and wave-driven hydrodynamic disturbance causes spatiotemporal variations in oxygen levels, which select for microbial generalists and disrupt redox cascades. In this work, we profiled microbial communities and biogeochemical dynamics in sediment profiles from three sites varying in their exposure to hydrodynamic disturbance. Strong variations in sediment geochemistry, biogeochemical activities, and microbial abundance, composition, and capabilities were observed between the sites. Most of these variations, except for microbial abundance and diversity, significantly correlated with the relative disturbance level of each sample. In line with previous findings, metabolically flexible habitat generalists (e.g., Flavobacteriaceae, Woeseaiceae, Rhodobacteraceae) dominated in all samples. However, we present evidence that aerobic specialists such as ammonia-oxidizing archaea (Nitrosopumilaceae) were more abundant and active in more disturbed samples, whereas bacteria capable of sulfate reduction (e.g., uncultured Desulfobacterales), dissimilatory nitrate reduction to ammonium (DNRA; e.g., Ignavibacteriaceae), and sulfide-dependent chemolithoautotrophy (e.g., Sulfurovaceae) were enriched and active in less disturbed samples. These findings are supported by insights from nine deeply sequenced metagenomes and 169 derived metagenome-assembled genomes. Altogether, these findings suggest that hydrodynamic disturbance is a critical factor controlling microbial community assembly and biogeochemical processes in coastal sediments. Moreover, they strengthen our understanding of the relationships between microbial composition and biogeochemical processes in these unique environments.

Holocene geo-ecological evolution of Lower Geyser Basin, Yellowstone National Park (USA)

Changes in climate and fire regime have long been recognized as drivers of the postglacial vegetation history of Yellowstone National Park, but the effects of locally dramatic hydrothermal activity are poorly known. Multi-proxy records from Goose Lake have been used to describe the history of Lower Geyser Basin where modern hydrothermal activity is widespread. From 10,300 cal yr BP to 3800 cal yr BP, thermal waters discharged into the lake, as evidenced by the deposition of arsenic-rich sediment, fluorite mud, and relatively high δ13Csediment values. Partially thermal conditions affected the limnobiotic composition, but prevailing climate, fire regime, and rhyolitic substrate maintained Pinus contorta forest in the basin, as found throughout the region. At 3800 cal yr BP, thermal water discharge into Goose Lake ceased, as evidenced by a shift in sediment geochemistry and limnobiota. Pollen and charcoal data indicate concurrent grassland development with limited fuel biomass and less fire activity, despite late Holocene climate conditions that were conducive to expanded forest cover. The shift in hydrothermal activity at Goose Lake and establishment of the treeless geyser basin may have been the result of a tectonic event or change in hydroclimate. This record illustrates the complex interactions of geology and climate that govern the development of an active hydrothermal geo-ecosystem.

Late Quaternary Climate Reconstruction and Lead-Lag Relationships of Biotic and Sediment-Geochemical Indicators at Lake Bolshoe Toko, Siberia

Millennial-scale climate change history in eastern Siberia and relationships between diatom diversity, paleoclimate, and sediment-geochemical lake system trajectories are still poorly understood. This study investigates multi-proxy time series reaching back to the Late Pleistocene derived from radiocarbon dated Lake Bolshoe Toko sediment cores, southeastern Yakutia, Russia. We analyzed diatoms, elements (XRF), minerals (XRD), grain-size, organic carbon, and included chironomid analyses and published pollen-data for quantitative paleoclimate reconstruction. Changes in diatom species abundances reveal repeated episodes of thermal stratification indicated by shifts from euplanktonic Aulacoseira to Cyclotella species. Chironomid and pollen-inferred temperature reconstruction reveal that the main shift between these diatom species is related to the onset of Holocene Thermal Maximum (HTM) at 7.1 cal ka BP. Comparison to other paleoclimate records along a north-south transect through Yakutia shows that the HTM was delayed as far south as the Stanovoy mountains. Relationships between sediment-geochemistry, paleoclimate variability and diatom species richness (alpha diversity) was tested in a moving temporal offset approach to detect lead-lag relationships. Sediment-geochemical data, mainly uniform during the Holocene, revealed strongest positive or negative correlations ahead of species richness changes. Mean July air temperature (TJuly) reconstructions correlate with both Hill numbers and relative assemblage changes indicated by sample scores of multidimensional scaling analysis (MDS) over the entire time series. We found that sediment organic carbon revealed distinct positive correlations, i.e., centennial-scale delay to increases in diatom effective richness (Hill numbers N0 and N2). We conclude that a lag of deposited organic carbon concentrations behind changes in diatom alpha diversity reveals that species richness can augment the production and thus sequestration of organic matter in comparable lake systems.

The foraminiferal record in the Holocene evolution of the Mecklenburg Bay (south-western Baltic Sea)

Foraminiferal assemblages were analyzed in a 620-cm long core retrieved from the central part of the Mecklenburg Bay (MB, south-western Baltic Sea) to aid in the reconstruction of environmental changes occurring in the area during the Holocene and to complement a set of previously investigated palaeoenvironmental proxies. A total of five foraminifera-based stratigraphic units were identified, including an initial 80-cm thick layer devoid of foraminifera. The next two units featured an increasing abundance of the foraminiferal assemblage dominated by the calcareous Ammonia group species. Nearly all the calcareous foraminifera found in the core were decalcified. Following the maximum abundance within the 470–410 cm layer, the foraminiferal abundance declined sharply and the assemblage’s dominance structure changed to domination of the agglutinated foraminiferal species, Eggerelloides scaber, which continued up to the top of the core and marked a pronounced shift in environmental conditions (shallower depth, lower salinity, more dynamic sedimentation conditions). The foraminifera-based stratigraphy of the core proved to be complementary to that emerging from previous analyses of diatoms and sediment geochemistry.

Eksplorasi Geokimia untuk Menentukan Daerah Prospek Mineralisasi Emas Tipe Urat Epitermal: Studi Kasus di Daerah Tompaso, Kabupaten Minahasa Selatan, Sulawesi Utara

ABSTRAK Sulawesi Utara termasuk daerah Tompaso, Kabupaten Minahasa Selatan merupakan jalur magmatik yang potensial menghasilkan endapan bijih hidrotermal. Penelitian ini bertujuan menentukan daerah prospek mineralisasi emas khususnya tipe urat epitermal berdasarkan eksplorasi geokimia meliputi geokimia batuan dan sedimen sungai, khususnya metode BLEG (Bulk Leach Extractable Gold). Metode penelitian meliputi pemetaan geologi, alterasi dan jalur urat, percontoan (bijih/batuan dan sedimen sungai), dan analisis geokimia. Sampel bijih dianalisis dengan metode FA/AAS untuk emas dan metode AAS untuk unsur lain, sedangkan analisis sampel sedimen sungai dilakukan dengan metode cyanide leach dan AAS. Hasil penelitian menunjukkan batuan induk mineralisasi berupa lava andesit dan intrusi diorit. Batuan ini mengalami alterasi silica-clay, argilik, dan propilitik. Perpaduan antara pemetaan geologi, zona alterasi, dan jalur urat dengan eksplorasigeokimia batuan dapat menentukan daerah prospek mineralisasi yaitu Prospek Asam dan Polangkok. Pada Prospek Asam, sampel bijih memiliki kandungan emas sampai 0,03 ppm dengan anomali emas pada sampel BLEG menunjukkan nilai threshold 13,52 ppb Au. Pada Prospek Polangkok ditemukan 2 jalur urat (P1 dan P2) berarah baratlaut-tenggara dengan lebar sampai 5 m. Urat P1 memiliki kadar Au mencapai 0,31 ppm dan pada urat P2 mencapai 0,16 ppm Au. Mineralisasi pada Prospek Polangkok didukung oleh anomali Ag pada sampel BLEG dengan nilai threshold 67,18 ppb. Kedua daerah prospek tersebut direkomendasikan untuk eksplorasi lanjut (follow-up exploration). ABSTRACT North Sulawesi, including the Tompaso region, South Minahasa district, is a part of the magmatic belts hosting potential hydrothermal ore deposits. This study is aimed to determine the prospect area for epithermal vein-type gold mineralization, based on geochemical exploration including rock and BLEG (Bulk Leach Extractable Gold) stream sediment geochemistry. Mapping of geology, alteration and vein direction, sampling (ore/rock and stream sediment), and geochemical analysis were performed. Gold in rock samples was analyzed by FA/AAS, and other elements were detected by AAS, while BLEG samples were analyzed using the cyanide leach and AAS methods. The study area is occupied by andesitic lava and diorite, which are suffered by silica-clay, argillic and propylitic alteration. An integration of geological mapping, alteration zones and vein direction with lithogeochemical survey enables to determine the prospect areas, which consist of Asam and Polangkok prospects. At the Asam prospect, the ore sample contains gold up to 0.03 ppm, where the gold anomaly in BLEG samples show a threshold of 13.52 ppb Au. At the Polangkok prospect, two NW-SE trending veins (P1 and P2 Veins) were discovered with a width of up to 5 m. Vein P1 and P2 contains of up to 0.31 and 0.16 ppm Au, respectively. Mineralization at the Polangkok prospect coincides with Ag anomaly of BLEG samples with a threshold of 67.18 ppb. The two prospect areas are recommended for follow-up exploration.