Dissociative single and double photoionization of biphenyl (C12H10) by soft X-rays in planetary nebulae

ABSTRACT Biphenyl (C12H10), or phenylbenzene, is an important building block of polycyclic aromatic hydrocarbons (PAHs), whose infrared spectral features are present in a variety of galactic and extragalactic sources. In this work, we use synchrotron radiation coupled with time-of-flight spectrometry to study the photoionization and photodissociation processes of biphenyl upon its interaction with soft X-ray photons at energies around the inner-shell C1s resonance. These results are compared with our previous studies with benzene (C6H6) and naphthalene (C10H8), and discussed in the context of four planetary nebulae featuring PAH infrared emission: BD+30○3639, NGC 7027, NGC 5315, and NGC 40. We show that the mass spectrum of biphenyl before the C1s resonance energy is dominated by single photoionization processes leading to C6H$_{5}^+$, C6H$_{4}\, ^{+\cdot}$, and C12H$_{10}\, ^{+\cdot}$, while after the resonance dissociation following multiple photoionization processes is dominant. The release of neutral C6H6 and C6H$_{5}\, ^\cdot$ species accounts for one of the most relevant dissociation processes starting from the doubly ionized biphenyl, indicating that heterolytic charge separation of the two phenyl rings is also achieved. By using quantum chemical calculations, we show that the biphenylic structure is a high-lying isomer of the singly and doubly ionized C12H10 species, whose minimum energy geometries are related to the acenaphthene molecule, composed of a C2-bridged naphthalene. Furthermore, we estimate the lifetime of biphenyl for 275 and 310 eV in photon-dominated regions of planetary nebulae. We discuss distinct processes that may enhance its lifetime and those of other small-sized PAHs in such astrophysical environments.

Atomic Data Assessment with PyNeb

PyNeb is a Python package widely used to model emission lines in gaseous nebulae. We take advantage of its object-oriented architecture, class methods, and historical atomic database to structure a practical environment for atomic data assessment. Our aim is to reduce the uncertainties in the parameter space (line ratio diagnostics, electron density and temperature, and ionic abundances) arising from the underlying atomic data by critically selecting the PyNeb default datasets. We evaluate the questioned radiative-rate accuracy of the collisionally excited forbidden lines of the N- and P-like ions (O ii, Ne iv, S ii, Cl iii, and Ar iv), which are used as density diagnostics. With the aid of observed line ratios in the dense NGC 7027 planetary nebula and careful data analysis, we arrive at emissivity ratio uncertainties from the radiative rates within 10%, a considerable improvement over a previously predicted 50%. We also examine the accuracy of an extensive dataset of electron-impact effective collision strengths for the carbon isoelectronic sequence recently published. By estimating the impact of the new data on the pivotal [N ii] and [O iii] temperature diagnostics and by benchmarking the collision strength with a measured resonance position, we question their usefulness in nebular modeling. We confirm that the effective-collision-strength scatter of selected datasets for these two ions does not lead to uncertainties in the temperature diagnostics larger than 10%.

First Results from a Panchromatic HST/WFC3 Imaging Study of the Young, Rapidly Evolving Planetary Nebulae NGC 7027 and NGC 6302

We present the first results from comprehensive, near-UV-to-near-IR Hubble Space Telescope Wide Field Camera 3 (WFC3) emission-line imaging studies of two young planetary nebulae (PNe), NGC 7027 and NGC 6302. These two objects represent key sources for purposes of understanding PNe shaping processes. Both nebulae feature axisymmetric and point-symmetric (bipolar) structures and, despite hot central stars and high nebular excitation states, both harbor large masses of molecular gas and dust. The sweeping wavelength coverage of our Cycle 27 Hubble Space Telescope (HST)/WFC3 imaging surveys targeting these two rapidly evolving PNe will provide a battery of essential tests for theories describing the structural and chemical evolution of evolved star ejecta. Here, we present initial color overlays for selected images, and we highlight some of the first results gleaned from the surveys.

The spectra of evolved stars at 20–25 GHz: Tracing circumstellar chemistry during the asymptotic giant branch to planetary nebula transition

We report an unbiased radio line survey towards the circumstellar envelopes of evolved stars at the frequency range from 20 to 25 GHz, aiming to obtain a more complete unbiased picture of the chemical evolution in the final stages of stellar evolution. The observation sample includes the asymptotic giant branch (AGB) star IRC +10216, the proto-planetary nebulae (PPNs) CRL 2688 and CRL 618, and the young planetary nebula (PN) NGC 7027, representing an evolutionary sequence spanning about 10000 years. Rotational transitions from cyanopolyyne chains and inversion lines from ammonia are detected in the AGB star and PPNs, while the PN displays several recombination lines. The different spectral behaviors of these evolved stars clearly reflect the evolution of circumstellar chemistry during the AGB–PPN–PN transitions.

Rings and arcs around evolved stars – II. The Carbon Star AFGL 3068 and the Planetary Nebulae NGC 6543, NGC 7009, and NGC 7027

ABSTRACT We present a detailed comparative study of the arcs and fragmented ring-like features in the haloes of the planetary nebulae (PNe) NGC 6543, NGC 7009, and NGC 7027 and the spiral pattern around the carbon star AFGL 3068 using high-quality multi-epoch HST images. This comparison allows us to investigate the connection and possible evolution between the regular patterns surrounding AGB stars and the irregular concentric patterns around PNe. The radial proper motion of these features, ≃15 km s−1, are found to be consistent with the AGB wind and their linear sizes and interlapse times (500–1900 yr) also agree with those found around AGB stars, suggesting a common origin. We find evidence using radiative-hydrodynamic simulations that regular patterns produced at the end of the AGB phase become highly distorted by their interactions with the expanding PN and the anisotropic illumination and ionization patterns caused by shadow instabilities. These processes will disrupt the regular (mostly spiral) patterns around AGB stars, plausibly becoming the arcs and fragmented rings observed in the haloes of PNe.

Probing the size and charge of polycyclic aromatic hydrocarbons

ABSTRACT We present a new method to accurately describe the ionization fraction and the size distribution of polycyclic aromatic hydrocarbons (PAHs) within astrophysical sources. To this purpose, we have computed the mid-infrared emission spectra of 308 PAH molecules of varying sizes, symmetries, and compactness, generated in a range of radiation fields. We show that the intensity ratio of the solo CH out-of-plane bending mode in PAH cations and anions (referred to as the ‘11.0’ μm band, falling in the 11.0–11.3 μm region for cations and anions) to their 3.3 μm emission scales with PAH size, similarly to the scaling of the 11.2/3.3 ratio with the number of carbon atoms (NC) for neutral molecules. Among the different PAH emission bands, it is the 3.3 μm band intensity that has the strongest correlation with NC, and drives the reported PAH intensity ratio correlations with NC for both neutral and ionized PAHs. The 6.2/7.7 intensity ratio, previously adopted to track PAH size, shows no evident scaling with NC in our large sample. We define a new diagnostic grid space to probe PAH charge and size, using the (11.2 + 11.0)/7.7 and (11.2 + 11.0)/3.3 PAH intensity ratios, respectively. We demonstrate the application of the (11.2 + 11.0)/7.7–(11.2 + 11.0)/3.3 diagnostic grid for galaxies M82 and NGC 253, for the planetary nebula NGC 7027, and the reflection nebulae NGC 2023 and NGC 7023. Finally, we provide quantitative relations for PAH size determination depending on the ionization fraction of the PAHs and the radiation field they are exposed to.