Effect of Accelerated Cooling on Linepipe Steel Mill Scale and Resulting Localized Corrosion Susceptibility

The structure and composition of mill scale on linepipe steel formed with and without accelerated cooling conditions (ACC) was investigated and correlated to localized corrosion susceptibility. The mill scale structure/composition was investigated using scanning electron microscopy equipped with X-ray energy dispersive spectroscopy and electron back scatter diffraction, as well as X-ray diffraction. Localized dissolution of the mill scale was investigated using electrochemical techniques including open circuit potential measurements, electrochemical impedance spectroscopy, and electrochemical noise measurements in a corrosive phase solution. The various surface analytical and electrochemical techniques indicated that the mill scale formed without ACC consists of a relatively crack-free, thick inner wüstite layer with a thinner magnetite outer layer. However, the mill scale formed with ACC comprised a magnetite layer containing islands of retained wüstite, with some evidence of magnetite/iron eutectoid formation and which exhibited a relatively high density of through-scale cracks. These cracks can provide direct paths that connect the corrosive solution to the steel substrate, leading to more rapid breakdown of the mill scale. Additionally, the cracks can form a crevice between the mill scale and the steel surface, providing sites for pit initiation and growth. Coefficient of thermal expansion mismatch thermal stress calculations indicate that a magnetite-based scale is more susceptible to cracking/spalling than a wüstite-based scale, resulting in the ACC plate being more susceptible to localized corrosion.

Energy power parameter effect of hot rolling on the formation of the structure and properties of low-alloy steels

The temperature and degree of hot deformation for steel 10HFTBch have been determined. This made it possible to ensure an increase in the mechanical properties of this steel, namely, the ultimate strength up to 540–560 MPa, as well as the relative elongation up to 25–29 %. As a result, it became possible to increase the service life of wheels with increased carrying capacity. This, in turn, will make it possible to increase the load of the transported cargo by motor vehicles several times. The mechanism of the influence of the energy-power parameters of rolling on the formation of the macro- and microstructure of a two-phase steel in the process of hot deformation is disclosed. The applied scheme provided an increase in the homogeneity of the structure of the developed steel, which saved the central part of the rolled section from overheating. It has been established that a decrease in the temperature of the end of deformation leads to a decrease in the size of the recrystallized austenite grain, and, consequently, to a refinement of the ferrite grain. Also an important factor in preventing the growth of ferrite grains in the upper part of the ferritic region is the abolition of cooling of the steel in coils. The recommended mode for multicomponent alloy steel 10HFTBch is as follows: the temperature of the end of rolling is 850 °C, the beginning of accelerated cooling is 750 °C, and the temperature of strip coiling into a coil is 600 °C. The basis for ensuring the increased strength of two-phase steels is the ratio and distribution of structural fractions – ferrite (initial and precipitated from austenite), as well as martensite. When hardened by such traditional "martensite formations" as manganese, the ability to control properties is limited. This is reflected in a narrow range of variation in the strength and ductility of the developed steel. The optimal combination of strength characteristics of plastic properties reduces the metal consumption of the product by 15–25 %.

Mechanical properties of wire and arc additively manufactured high-strength steel structures

Additive manufacturing with steel opens up new possibilities for the construction sector. Especially direct energy deposition processes like DED-arc, also known as wire arc additive manufacturing (WAAM), is capable of manufacturing large structures with a high degree of geometric freedom, which makes the process suitable for the manufacturing of force flow-optimized steel nodes and spaceframes. By the use of high strength steel, the manufacturing times can be reduced since less material needs to be deposited. To keep the advantages of the high strength steel, the effect of thermal cycling during WAAM needs to be understood, since it influences the phase transformation, the resulting microstructure, and hence the mechanical properties of the material. In this study, the influences of energy input, interpass temperature, and cooling rate were investigated by welding thin walled samples. From each sample, microsections were analyzed, and tensile test and Charpy-V specimens were extracted and tested. The specimens with an interpass temperature of 200 °C, low energy input and applied active cooling showed a tensile strength of ~ 860–900 MPa, a yield strength of 700–780 MPa, and an elongation at fracture between 17 and 22%. The results showed the formation of martensite for specimens with high interpass temperatures which led to low yield and high tensile strengths (Rp0.2 = 520–590 MPa, Rm = 780–940 MPa) for the specimens without active cooling. At low interpass temperatures, the increase of the energy input led to a decrease of the tensile and the yield strength while the elongation at fracture as well as the Charpy impact energy increased. The formation of upper bainite due to the higher energy input can be avoided by accelerated cooling while martensite caused by high interpass temperatures need to be counteracted by heat treatment.

New Detrital Apatite Fission Track Thermochronological Constraints on the Meso-Cenozoic Tectono-Thermal Evolution of the Micangshan-Dabashan Tectonic Belt, Central China

The Micangshan-Dabashan tectonic belt, located in the southern Qinling-Dabie Orogen near the northeastern Tibetan Plateau, is a crucial area for understanding the processes and mechanisms of orogenesis. Previous studies have been focused on the cooling process via thermochronology and the mechanism and process of basement uplift have been investigated. However, the coupling process of basement exhumation and sedimentary cap cooling is unclear. The tectono-thermal history constrained by the detrital apatite fission track (AFT) results could provide valuable information for understanding crustal evolution and the coupling process. In this study, we provided new detrital AFT thermochronology results from the Micangshan-Dabashan tectonic belt and obtained nine high-quality tectono-thermal models revealing the Meso-Cenozoic cooling histories. The AFT ages and lengths suggest that the cooling events in the Micangshan area were gradual from north (N) to south (S) and different uplift occurred on both sides of Micangshan massif. The cooling in Dabashan tectonic zone was gradual from northeast (NS) to southwest (SW). The thermal histories show that a relatively rapid cooling since ca. 160 Ma occurred in the Micangshan-Dabashan tectonic belt, which was a response to the event of Qinling orogenic belt entered the intracontinental orogenic deformation. This cooling event may relate to the northeastward dextral compression of the Yangtze Block. The sedimentary cap of Cambriano-Ordovician strata responded positively to this rapid cooling event and entered the PAZ since ca. 63 Ma. The deep buried samples may be limited affected by climate and water erosion and the accelerated cooling was not obvious in the Late Cenozoic. Collectively, the cooling processes of basement and sedimentary cap in Micangshan-Dabashan tectonic belt were inconsistent. The uplift of the sedimentary area is not completely consistent with that of the basement under thrust and nappe action. The rigid basement was not always continuous and rapidly uplifted or mainly showed as lateral migration in a certain stage because of the different intensities and modes of thrust and nappe action, and the plastic sedimentary strata rapidly uplifted due to intense folding deformation.

Study of the Boron Effect on the Physicochemical Properties of Ligatures

One of the effective ways to improve the quality of semi-finished products made from aluminum alloys is to eliminate the columnar and fan-shaped structure in them, refine the grain and achieve homogeneity, is modification and alloying. Modification of the melt is carried out using ligatures and allows a significant increase in the casting rate without fear of an excessive increase in the degree of zonal segregation during crystallization, as well as ensuring the uniformity of the chemical composition over the section. An important role in the quality of modification is also played by the manufacturing technology of the master alloy itself, which should ensure an increase in the cooling rate during crystallization. To obtain an alloy with the required properties, the quality of the charge materials used must be considered. First of all, this concerns master alloys, which are used for alloying and modifying the alloy. The most common for the manufacture of ingots and shaped castings are master alloys containing boron or boron and titanium. The boron content in these ligatures is 1-5%. It is generally accepted that a large amount of boron (except for the rise in the cost of the alloy itself) upon accelerated cooling promotes the refinement of the internal structure of the grain, but can lead to an increase in large inclusions of TiB2.

Structure and Phase Composition of the Al-Ti System Composites after Heat Treatment

The studies results of the titanium with aluminum diffusion interaction at a temperature of 650 oC are presented. The phase and chemical composition of the diffusion interaction zone, the nature of the change in its thickness from the exposure time are determined. It is shown that accelerated cooling of explosion-welded composites from the heat treatment temperature leads to spontaneous separation of the aluminum layer with the formation of a coating based on the TiAl3 intermetallic compound on the titanium surface.

Physical Simulation Based on Dynamic Transformation Under Hot Plate Rolling of a Nb-Microalloyed Steel

In this work, the presence of dynamically formed ferrite above the Ae3 temperature during the physical simulation of hot rolling was presented. This unusual metallurgical process is known as dynamic transformation (DT). The metastable ferrite phase undergoes a reverse transformation when the temperature is held above the Ae3 by means of a diffusion process. These phenomena affect the rolling load during high-temperature plate rolling. Therefore, a linepipe X70 steel was studied under plate rolling with two-pass roughing and seven-pass finishing strains of 0.4 and 0.2, respectively, applied at strain rate of 1 s−1 and interpasses of 10, 20, and 30 s. The samples were cooling down during deformation, which mimics the actual industrial hot rolling. It was observed that the alloy softens as the hot rolling progresses, as depicted by flow curves and mean flow stress plots, which are linked to the combined effects of dynamic transformation and recrystallization. The former initially occurs at lower strains, followed by the latter at higher strains. The critical strain to DT was affected by the number of passes and temperature of deformation. Shorter interpass time allows higher amounts of ferrite to form due to higher retained work hardening. Similarly, the closer the deformation temperature to the Ae3 permits a higher DT ferrite fraction. The information from this work can be used to predict the formation of phases immediately after hot rolling and optimize models applied to the accelerated cooling.

Development and mastering of technologies of production at PJSC MMK a new generation steel rolled stock for m a in pipelines

In view of arising needs of Russian oil and gas sectors, elaboration and implementation into series production competi­tive pipe products became an actual task for domestic enterprises of metallurgical industry. Generalized results of elaboration of chemical compositions and automated technologies of sheet rolled stock of new generation production from low-alloyed pipe steels of various strength classes at PJSC MMK presented. It was shown that the selected chemical compositions ensure forming finedispersed ferrite-bainite structure with bainite of granular morphology in a wide range of cooling rates. The elaborated technological modes of sheet rolled stock production from pipe steels stipulate for elimination considerable growth of austenite grain at heating before the rolling, refinement of austenite grains due to recrystallization processes, forming of extensive subgrain structure of austenite at plastic deformation, forming disperse structures during phase transformation in the process of controlled accelerated cooling; forming of extensive fragmented structure in а-phase. The level of strength, tough-plastic properties and resistance against brittle destruction (based on results of tests with a falling weight with determination of tough component share in the break of full-thickness samples) of sheet rolled stock of pipe steels with various chemical composition of PJSC MMK production was demonstrated. Results of study of tests the sheet rolled stock of high-strength steels for pipes of large diameter presented. Objects of the elaborated pipe steels implementation indicated.