Superhydrophobic PDMS-pCA@CNWF Composite with UV-Resistant and Self-Cleaning Properties for Oil/Water Separation

Oil separation is crucial for avoiding environmental pollution originating from industrial wastewater and oil spillage; therefore, it is essential to develop techniques for oil separation. Herein, a new membrane with superhydrophilicity was synthesized by a facile, green, and low-cost method. First, cellulose non-woven fabric (CNWF) was modified by poly (catechin) (pCA), which has good antioxidant and antibacterial activities, to make it unaffected by ultraviolet light and to improve the stability of the structure. Then, hydrolyzed polydimethylsiloxane (PDMS) was coated on the pCA@CNWF surface via chemical bonding to make the composite hydrophobic. This durable superhydrophobic fabric can be used to separate various oil/water mixtures by gravity-driven forces with high separation efficiency (over 98.9%). Additionally, the PDMS-pCA@CNWF possesses the advantages of flexibility, high efficiency, and an outstanding self-cleaning performance, and demonstrates significant potential for applications in various environments, even under various harsh conditions, which make it very promising for the treatment of oil pollution in practical applications.

Restoring Well Productivity Through a Fit-for-Purpose Sludge Cleanout Job

Sludge formation could significantly impair well productivity if deposited in the wellbore or surface flow lines. In a field where sludge formation is not common, an oil production well showed a sudden deterioration in well productivity. Thorough investigation of abnormal well performance, from surface and sub-surface perspective, indicated that the deposition of a thick layer of a tight emulsion across the surface choke has resulted in ceasing the oil flow to the gas oil separation plant. Extensive lab analysis indicated that the obstruction material was a sludge deposition promoted by the presence of asphaltene, high amount of iron and low pH brine. It is noteworthy to mention that the analytical results of lab prepared emulsion samples elucidate the rule of low pH aqueous solution, asphaltene and iron ions in inducing tight emulsion formation which helps to understand the root causes of sludge deposition. To come up with a cost-effective remedial treatment considering health, safety and environment (HSE), different emulsion breaking formulations, including different de-emulsifiers and anti-sludge agents, were examined in this study. An effective diesel-based formulation including proper de-emulsifier and anti-sludging agent was used during the execution of the field job. The design of the field job took into consideration a minimal footprint to the environment through the flowback of the well to the neighboring gas oil separation plant. This paper summarizes the joint efforts by production engineers and lab scientists to systemically tackle such major flow assurance issues which could significantly jeopardize wells productivity. The systemic approach starts with problem detection through well intervention and sample collection. It also includes the lab work which was carried out to identify the type and composition of deposition and evaluate/optimize a proper formulation for sludge deposition removal. The paper discusses in detail the design and execution of a successful field treatment, which has resulted in restoring and maintaining the well potential.

Troubleshooting Gas Dehydration Systems Using Data Analysis

The objective of this paper is to showcase the successful and innovative troubleshooting data analysis techniques to operate a TEG dehydration system optimally and reduce glycol loss and to meet the product specifications in one of the gas dehydration systems in an upstream gas oil separation plant (GOSP). The gas dehydration system using Triethylene Glycol (TEG) is the most widely used and reliable gas dehydration system in upstream operation. These proven data analysis techniques were used to tackle major and chronic issues associated with gas dehydration system operation that lead to excessive glycol losses, glycol degradation, and off-specification products. Glycol loss is the most important operating problem in the gas dehydration system and it represents a concern to the operation personnel. Most dehydration units are designed for a loss of less than 1 pound of glycol per million standard cubic feet of natural gas treated, depending on the TEG contactor operating temperature. In this paper, comprehensive data analysis of the potential root causes that aggravate undesired glycol losses degradation and off-specification products will be discussed along with solutions to minimize the expected impact. For example, operating the absorption vessel (contactor) or still column at high temperature will increase the glycol loss by vaporization. Also, the glycol losses occurring in the glycol regenerator section are usually caused by excessive reboiler temperature, which causes vaporization or thermal decomposition of glycol (TEG). In addition, excessive top temperature in the still column allows vaporized glycol to escape from the still column with the water vapor. Excessive contactor operating temperature could be the result of malfunction glycol cooler or high TEG flow rate. This paper will focus on a detailed case study in one of the running TEG systems at a gas-oil separation plant.

Hydrocyclone optimisation to separate oil and water in the separator

The conventional 3-phase separator installed cannot anticipate the increase in fluid flow so that the oil content carried into the produced water from the separator consistently exceeds the upper operating threshold. This study aimed to test the application of a hydrocyclone device to a 3-phase horizontal separator. Hydrocyclones are widely used as auxiliary devices to optimise oil separation by minimising oil carried into the produced water stream. This study made a comparison between installing a hydro cyclone at the inlet with a 3-phase horizontal separator. Applying a hydrocyclone at the inlet of a 3-phase horizontal separator increases the efficiency of the separation process in production. Proper design improvements with Hysys and flow characteristics with CFD can reduce the oil content carried in the produced water stream below 20 mg/l. The results of this study can support de-bottlenecking to increase production to a production target of above 375 kbps. A robust application of engineered hydrocyclones with correct production and operating shrouds has been experienced to optimise the separation process by up to 92%.

TECHNOLOGY OF ISOLATION OF BIOLOGICALLY ACTIVE SUBSTANCES FROM MAKHALI CORN GRAIN

Research has been carried out to obtain oil from corn grown in the Khorezm region. The amount of protein, oil, starch and fiber in the composition of corn grains has been determined. Optimal indicators of the technology for obtaining corn oil by extraction with ethyl alcohol have been determined. The amount of oil in grain and corn germ has been studied. Ethanol seed oil separation is exploring the advantages of the wet process.