Effect of Dissolution Temperature on Purity of LaNi5 Powder Synthesized with the Combustion-Reduction Method

The LaNi5 intermetallic phase has been extensively investigated because of its excellent properties, such as attractive hydrogen storage, medium plateau pressure, and easy activation. LaNi5 phase is generally produced by a complicated method, which involves several steps, i.e. melting, alloying, casting, softening and making them into powder. This study aimed to develop a new LaNi5 synthesis process by modifying the combustion-reduction method. In this method it is very important to produce La2NiO4, because LaNi5 is formed from the process of reducing this phase. The precursor powders La(NO3)3.6H2O and Ni(NO3)2.6H2O were reacted with distilled water as a solvent medium and mixed using magnetic stirring. The synthesis process was carried out at room temperature, 60 °C, 70 °C, and 80 °C for 10 minutes until the solution became transparent green. The solution was then dried for 2 hours at 100 °C to form a transparent green gel. The gel was calcined at a temperature of 500 °C for 2 hours, producing a black powder. The optimal black powder was then reduced using CO gas at 600 °C for 2 hours. The powder samples were characterized using XRD, FTIR, and SEM-EDX. The analysis revealed that synthesis at room temperature was the most optimal method for the reduction process because it produced the most La2NiO4, at 12.135 wt%.

High-speed camera test of newly developed igniter’s charges for artillery rounds

The article presents the results of the high-speed camera test of newly developed igniter’s charges for artillery rounds. The test was performed to take a closer look at the ignition process of mixtures, that is, to check the time-to-ignition of samples, and to assess the presence and quantity of solid igniting particles (if any). Five compositions were tested: Three of them contained the new igniter’s charges developed by the Military Institute of Armament Technology, and the other two contained black powder in different granularity classes as a comparison mixture. This article presents the collated test results.

The GRINDER CONSTRUCTION DESIGN OF A BALL MILL MACHINE FOR THE PROCESS OF HOMOGENIZING BLACK POWDER USING AN AUTOMATIC SYSTEM

Combat technology in the military world has undergone a very rapid development in both close combat and long-range combat. Long-range combat is identical to a rocket weapon where the rocket works because of the presence of an igniter that serves to burn the propellant so that when the propellant burns it will produce pressure that will push the rocket hurtling towards a predetermined target. Igniter is very important in the launch of rockets where the filling of the igniter is black powder that has been difficult to obtain because of the difficult manufacturing process and risk of explosion. This research aims to design a tool that can produce black powder with a large enough capacity and good quality and reduce the risk of explosions to support the manufacture of igniters for rocket launches, especially those owned by Indonesian Army. This research used pure experimental quantitative method with empirical calculations to obtain tools with the desired specifications. The results obtained after the calculation are the volume of octagonal prism tubes 2942.5 cm3, the total volume of steel balls with two size variations is 979.5 cm3, the maximum lendutan that occurs on the shaft of the player is 0.108 mm, so it is said to be safe.

The DESIGN OF A TRANSMISSION SYSTEM ON A BALL MILL MACHINE TO PROCESS HOMOGENIZATION OF BLACK POWDER USING AN AUTOMATIC SYSTEM

In the military world, battle technology has experienced very rapid development, both close-range combat and long-range combat. In long-distance combat the technology that is often used is rocket technology where this rocket technology can paralyze the enemy in large numbers. Black powder is a mixture of potassium nitrate (KNO3), carbon powder (C) and sulfur (S). (Evie Lestariana, LAPAN). The black powder itself functions as an igniter filling material for the propellant combustion process. This research is to design a tool to support the manufacture of black powder in the igniter filling to help the combustion of rockets, especially those owned by the Indonesian Army. This study uses an experimental method using empirical calculations to get a tool with the desired specifications. Before carrying out the calculations, the author collects research data to carry out calculations, the data collected are as follows: 1. Roller shaft rotation: 246 rpm, 2. Roller shaft torque: 4.0697 Nm, 3. Roller shaft diameter: 25 mm, 4. Pulley shaft diameter top: 100mm. The results obtained after carrying out the calculations are the diameter of the driving pulley 98 mm, the belt contact angle against the pulley 174.6º, and the length of the V-belt 453.14 mm, moment of inertia on the gearbox output shaft 1884,8 mm4.

A Physical Chemistry Study of Black Powder Materials by Solution Combustion Synthesis Method

A study on the synthesis of black powder (La2NiO4) material using the solution combustion synthesis method at a variation of synthesis temperature of 60, 70, and 80°C was carried out. It produces a mass of black powder of 2 grams by four times of synthesis process. Then, material characterization was performed on the black powder samples obtained by using X-ray Diffraction (XRD) to determine the phases formed, Scanning Electron Microscopy - Energy Dispersive X-ray Spectroscopy (SEM-EDS) to determine the morphology and analyze the composition elemental on the microscale and Fourier Transform Infra-Red (FTIR) to determine chemical bonds. From the whole black powder sample, XRD analysis showed the phases of Dilantanum Nickel Tetraoxide (La2NiO4), Nickel Oxide (NiO), Lanthanum Oxide (La2O3), and Lanthanum Oxide Ht x-form (La2O3 Ht (x-form)). In addition, it was seen from the visible compositions of the phases that the NiO phase looks more dominant and the variation of the synthesis temperature shows that the La2O3 phase was increasing. This was supported by the EDS analysis, which showed that the EDS spectrum contains elements La, Ni, and O where the element O indicates that oxidation occurs in the elements Ni and La. On the other hand, the SEM analysis results confirm that the black powder sample contains the elements La and Ni, based on the high and low electron images contained in the morphology of the black powder sample. In addition, it was also known that the particles in the black powder sample were micron size and had porous morphology. This occurs due to rapid thermal decomposition events and excessive gas development. In addition, FTIR analysis showed that the O-H bond had been reduced and there are still C-O and C-H bonds indicating the presence of organic elements possessed by glycine.