In the present study, the Fe-9Cr model alloy was irradiated with 240 keV He2+ at 550°C with a dose of 0.5 dpa at the peak damage region. The depth distribution of bubbles in Fe-9Cr alloy was investigated by transmission electron microscopy (TEM). The experimental results revealed that the spatial distribution of bubbles along the depth is different. In the region with higher helium concentration and irradiation dose, the bubbles inclined to be situated inside the plane of loops, forming a structure of “bubble-loop complex.” However, in regions where the helium concentration and irradiation dose are relatively low, the number of “bubble-loop complexes” significantly decreased. In addition, the Burgers vector of “bubble-loop complexes” was identified as <100> type. Radiation-induced enrichment of Cr atoms at the “bubble-loop complexes” was also quantitatively estimated by energy-dispersive X-ray spectroscopy (EDS) in the scanning TEM mode.
Abstract
A new modified 9 wt% Cr steel has been developed in order to improve the resistance against coke deposition on the internal surface of refinery tube furnaces, in comparison to widely used grades, such as Grade 5 (5 wt% Cr) or Grade 9 (9 wt% Cr). The new grade has an improved composition, based on Cr and Si and further additions of Cu and Ni. This optimal chemical analysis has been specified after extensive laboratory testing on different laboratory and industrial heats. Thermogravimetric analyses have been performed to benchmark various materials (ferritic and austenitic grades) in terms of coking rate. Specimens of these alloys have been exposed to this coking atmosphere in a wide temperature range. The new modified 9Cr steel exhibits an almost 10 times lower coking rates than typical Grade 9 steel. The new 9Cr steel shows allowable stress levels up to 90% higher than Grade 9 at temperatures below 500°C (time independent regime) and up to 7% higher stress levels at temperatures above 500°C (creep regime). The industrial feasibility of production of elbows has been successfully implemented and a welding solution using a commercially available filler material has been established.
Commercial F91 steel was exposed to atmospheric pressure CO2 and laboratory air at 550 °C for exposure times up to 1000 h. In both atmospheres, a Fe-rich duplex oxide scale formed, but with different morphology, oxide phases and growth rates. In CO2, the duplex morphology was observed at the onset of oxidation and it was found that the cooling rate affect the oxide phases formed on the outer scale. In air, the alloy initially formed a protective chromium rich oxide layer, followed by the nucleation and growth of duplex iron-rich oxide nodules at random locations, leading to breakaway oxidation. Alloy carburization was also observed in CO2 but not in air environment.
Ultrafine-grained oxide-dispersion-strengthened 9Cr steel with exceptional strength and thermal stability