Influence of copper addition on corrosion properties and hardness of Al–Cu/Al two-layered-structure composites

An experimental investigation has been observed on hardness, sintered density and corrosion behaviour of two-layered structured Al-xCu/Al sample through powder metallurgical route under hot compaction condition. The samples were prepared with different percentages of Cu content (x: 5 wt. %, 10 wt. % and 15 wt. %) in the aluminium matrix with a constant pressure of 400 MPa with different hot-pressed temperatures (500 °C, 550 °C and 600 °C) at a dwelling time of 3 h. The developed two-layered samples microstructure was analysed using the optical and scanning electron microscope. The highest value of micro-hardness (100.6 HV) was obtained at interface region of 15% of copper at 550 °C. The corrosion rate of Al-Cu/Al two-layered samples at the interface were analyzed through the potentiodynamic polarization test and found that with addition of copper content the susceptibility of corrosion increases. The Electrochemical Impedance Spectroscopy (EIS) test was conducted to know the equivalent circuit model, which provides a minimum chi-square value and that circuit model taken as best-fit circuit model. From the EIS results, it was found that 10 wt. %Cu sample circuit provides minimum chi-square value.

Weathering of Copper Deposits and Copper Mobility: Mineralogy, Geochemical Stratigraphy, and Exploration Implications

Weathering of pyrite and copper sulfide-bearing rocks produces a consistent series of iron- and copper-bearing minerals that reflect vertical and lateral geochemical changes as supergene solutions react with rock and experience loss of oxidizing capacity. Reactive host rocks, comprising feldspars, mafic minerals, chlorite, and carbonates, buffer pH values that limit copper mineral destruction, thus restricting the supergene transport of copper. Generally, rocks that have undergone well-developed hypogene or supergene hydrolysis of aluminosilicates promote copper mobility because they do not react substantially with low-pH supergene solutions generated by oxidation of pyrite and associated copper sulfides. Development of geochemical stratigraphy is characterized by physical and geochemical parameters that determine the maturity of a supergene profile, with cyclical leaching and enrichment periods critical for the production of economically significant copper accumulation. Evidence for multicycle enrichment is recorded by hematite after chalcocite, hanging zones of copper oxides that replace chalcocite, and hematitic capping overlying immature goethitic-pyritic capping. Because pyrite is the most refractory sulfide with respect to chalcocite replacement, geochemically strong supergene enrichment is independent of total copper added to protore and instead is indicated qualitatively by the degree to which chalcocite replaces pyrite. Covellite replacement of chalcopyrite indicates weak copper addition to protore and generally represents the base and lateral extent of supergene enrichment; covellite replacement of chalcocite indicates incipient copper removal by copper-impoverished supergene solutions. Exploration for, and delineation of, mature supergene enrichment profiles benefits from the recognition of paleoweathering cycles and consequent development of mature geochemical stratigraphy.

Stresses affect inbreeding depression in complex ways: disentangling stress-specific genetic effects from effects of initial size in plants

The magnitude of inbreeding depression (ID) varies unpredictably among environments. ID often increases in stressful environments suggesting that these expose more deleterious alleles to selection or increase their effects. More simply, ID could increase under conditions that amplify phenotypic variation (CV²), e.g., by accentuating size hierarchies among plants. These mechanisms are difficult to distinguish when stress increases both ID and phenotypic variation. We grew in- and outbred progeny of Mimulus guttatus under six abiotic stress treatments (control, waterlogging, drought, nutrient deficiency, copper addition, and clipping) with and without competition by the grass Poa palustris. ID differed greatly among stress treatments with δ varying from 7% (control) to 61% (waterlogging) but did not consistently increase with stress intensity. Poa competition increased ID under nutrient deficiency but not other stresses. Analyzing effects of initial size on performance of outbred plants suggests that under some conditions (low N, clipping) competition increased ID by amplifying initial size differences. In other cases (e.g., high ID under waterlogging), particular environments amplified the deleterious genetic effects of inbreeding suggesting differential gene expression. Interestingly, conditions that increased the phenotypic variability of inbred progeny regularly increased ID whereas variability among outbred progeny showed no relationship to ID. Our study reconciles the stress- and phenotypic variability hypotheses by demonstrating how specific conditions (rather than stress per se) act to increase ID. Analyzing CV² separately in inbred and outbred progeny while including effects of initial plant size improve our ability to predict how ID and gene expression vary across environments.