Effect of spectral overlap and mixing ratio on metal-semiconductor mixed colloid.

Metal-semiconductor hybrid colloid is an emerging paradigm for construction of advanced materials having multiple functionalities. In such colloids, the ratio between the number of metal nanoparticles (NP) to the number of semiconductor quantum dots (QD) plays an important role in controlling the properties of the final hybrid colloid. We study the effect of mixing ratio of Ag NPs to the CdTe QDs on the photoluminscence (PL) properties of the final mixed hybrid colloid. Using steady-state and time-resolved photoluminescence, it has been shown that when exciton and plasmon spectrally overlap in a hybrid, the amplitude of the decay component of PL depends on the excitation energy. Such dependence is not observed in the case of hybrid where exciton and plasmon are spectrally separated. This study contributes to the appropriate selection of the shape of metal NPs in designing a hybrid material that is well suited for optoelectronic device applications.

A Review on X-ray Excited Emission Decay Dynamics in Inorganic Scintillator Materials

Scintillator materials convert high-energy radiation into photons in the ultraviolet to visible light region for radiation detection. In this review, advances in X-ray emission dynamics of inorganic scintillators are presented, including inorganic halides (alkali-metal halides, alkaline-earth halides, rare-earth halides, oxy-halides, rare-earth oxyorthosilicates, halide perovskites), oxides (binary oxides, complex oxides, post-transition metal oxides), sulfides, rare-earth doped scintillators, and organic-inorganic hybrid scintillators. The origin of scintillation is strongly correlated to the host material and dopants. Current models are presented describing the scintillation decay lifetime of inorganic materials, with the emphasis on the short-lived scintillation decay component. The whole charge generation and the de-excitation process are analyzed in general, and an essential role of the decay kinetics is the de-excitation process. We highlighted three decay mechanisms in cross luminescence emission, exitonic emission, and dopant-activated emission, respectively. Factors regulating the origin of different luminescence centers controlling the decay process are discussed.

Compositional turnover in ecto- and endoparasite assemblages of an African bat, Miniopterus natalensis (Chiroptera, Miniopteridae): effects of hierarchical scale and host sex

We studied the compositional turnover in infracommunities and component communities of ecto- and endoparasites infesting a bat, Miniopterus natalensis (Chiroptera, Miniopteridae), across seven sampling sites using the zeta diversity metric (measuring similarity between multiple communities) and calculating zeta decline and retention rate (both scales) and zeta decay (component communities). We asked whether the patterns of zeta diversity differ between (a) infracommunities and component communities; (b) ecto- and endoparasites and (c) subsets of communities infecting male and female bats. The pattern of compositional turnover differed between infracommunities and component communities in endoparasites only. The shape of zeta decline for infracommunities indicated that there were approximately equal probabilities of ecto- and endoparasitic species to occur on/in any bat individual within a site. The shape of zeta decline for component communities suggested the stochasticity of ectoparasite turnover, whereas the turnover of endoparasites was driven by niche-based processes. Compositional turnover in component communities of ectoparasites was more spatially dependent than that of endoparasites. Spatial independence of compositional turnover in endoparasites was due to subcommunities harboured by female bats. We conclude that the patterns of compositional turnover in infracommunities were similar in ecto- and endoparasites, whereas the patterns of turnover in component communities differed between these groups.

Picosecond Lifetime Hot Electrons in TiO2 Nanoparticles for High Catalytic Activity

A large number of studies have examined the origins of high-catalytic activities of nanoparticles, but very few have discussed the lifetime of high-energy electrons in nanoparticles. The lifetime is one of the factors determining electron transfer and thus catalytic activity. Much of the lifetime of electrons reported in the literature is too short for a high transfer-efficiency of photo-excited electrons from a catalyst to the attached molecules. We observed TiO2 nanoparticles using the femtosecond laser two-color pump-probe technique with photoemission electron microscopy having a 40 nm spatial resolution. A lifetime longer than 4 ps was observed together with a fast decay component of 100 fs time constant when excited by a 760 nm laser. The slow decay component was observed only when the electrons in an intermediate state pumped by the fundamental laser pulse were excited by the second harmonic pulse. The electronic structure for the asymmetry of the pump-probe signal and the origin of the two decay components are discussed based on the color center model of the oxygen vacancy.

LSQ13ddu: a rapidly evolving stripped-envelope supernova with early circumstellar interaction signatures

ABSTRACT This paper describes the rapidly evolving and unusual supernova LSQ13ddu, discovered by the La Silla-QUEST survey. LSQ13ddu displayed a rapid rise of just 4.8 ± 0.9 d to reach a peak brightness of −19.70 ± 0.02 mag in the LSQgr band. Early spectra of LSQ13ddu showed the presence of weak and narrow $\mathrm{ He}\, {\small I}$ features arising from interaction with circumstellar material (CSM). These interaction signatures weakened quickly, with broad features consistent with those seen in stripped-envelope SNe becoming dominant around two weeks after maximum. The narrow $\mathrm{ He}\, {\small I}$ velocities are consistent with the wind velocities of luminous blue variables but its spectra lack the typically seen hydrogen features. The fast and bright early light curve is inconsistent with radioactive 56Ni powering but can be explained through a combination of CSM interaction and an underlying 56Ni decay component that dominates the later time behaviour of LSQ13ddu. Based on the strength of the underlying broad features, LSQ13ddu appears deficient in He compared to standard SNe Ib.

Спектроскопия и кинетика люминесценции ионов Pr-=SUP=-3+-=/SUP=- в K-=SUB=-3-=/SUB=-LuSi-=SUB=-2-=/SUB=-O-=SUB=-7-=/SUB=- : Pr-=SUP=-3+-=/SUP=-

Abstract—The luminescent characteristics of K_3LuSi_2O_7:Pr^3+ (1%), which is a promising optical material for the use as a scintillator, have been studied using a set of techniques. The luminescence spectra of K_3LuSi_2O_7:Pr^3+ (1%) contain two bands in the UV-range with peaks at 284 and 330 nm, which correspond intraconfigurational 5 d → 4 f transitions in the Pr^3+ ions. The radiation in the visible and near IR range (480–850 nm) has been represented by the intraconfigurational 4 f → 4 f transitions. The kinetics of 5 d → 4 f -luminescence contains a build-up stage (τ_rise ∼ 7–12 ns), nonexponential decay stage (τ_1/2 ∼ 60 ns), and a slow component of the μs-range when excited by high-frequency (∼8 MHz) synchrotron radiation of the X-ray range. The fast component of the decay (τ = 54 ns) dominates in the decay kinetics of luminescence along with the build-up stage while the contribution of the μs decay component is less than 0.5% at the excitation by an pulse electron beam (5Hz). The excitation spectra of d – f - and f–f -photoluminescence in the ultraviolet and vacuum ultraviolet range that are measured using synchrotron radiation reveal features that are caused by both intracenter transitions and processes related to the energy transfer from the intrinsic electronic excitations to the impurity center.

Measuring the Ultrafast Spectral Diffusion Dynamics of Colloidal CdSe Nanomaterials

We use ultrafast coherent two-dimensional electronic spectroscopy (2DES) to study the ultrafast spectral diffusion dynamics of colloidal CdSe quantum dots (QDs) and CdSe nanoplatelets (NPLs). The Center Line Slope (CLS) and Nodal Line Slope (NLS) techniques were employed to analyse the 2DES spectra. We show that no spectral diffusion dynamics occurs for the CdSe QDs. On the other hand, spectral diffusion was observed in the CdSe 5 mono-layers NPLs heavy-hole transition. The normalized Frequency Fluctuation Correlation Function (FFCF) of the CdSe NPLs heavy-hole transition was measured to have a major fast decay component at 140 fs.

The effect of PbS nanocrystal additives on the charge transfer state recombination in a bulk heterojunction blend

A persistent limitation of organic semiconductors is their low dielectric constant єr, which limits the performance of bulk heterojunction (BHJ) solar cells. One way to increase єr is to employ high-єr additives, such as PbS nanocrystals (QDs) to BHJ blends. In this work, we use the recombination of the interfacial charge transfer (CT) state as a means to study the effects of PbS nanocrystals on blends of a narrow bandgap copolymer: poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1- b;3,4-b′]dithiophene)-alt-4,7-(2,1,3-benzothiadiazole)] (PCPDTBT), and phenyl-C61-butyric acid methyl ester (PCBM). We show that at low dilution levels (0.25% - 0.75% by weight), there is a decrease in the relative weight of the CT recombination lifetime (longer decay component); suggesting that there is an increase in the local єr of the ternary blend.